Abstract
This investigation evaluates the effectiveness of UV-365 nm/S2O8 2− process in degrading polyvinyl alcohol in aqueous solutions. The effects of pH, Na2S2O8 dosage, and temperature on the degradation efficiency of polyvinyl alcohol were studied. Under acidic conditions, the degradation efficiency of polyvinyl alcohol exceeded that under alkaline conditions. Additionally, a higher Na2S2O8 dosage and a higher temperature were associated with a higher degradation efficiency of polyvinyl alcohol. The degradation rates of polyvinyl alcohol followed a pseudo-first-order kinetic model. Moreover, the observed degradation rate coefficient increased from 0.0078 to 0.4081 min−1 when the temperature was increased from 10 to 55 °C. Also, the activation energy estimated using the observed degradation rate coefficients and the Arrhenius equation was 64 kJ/mol. At UV-365 nm, pH 3, an Na2S2O8 dosage of 0.06 g/L, a temperature of 55 °C, and an initial polyvinyl alcohol concentration of 20 mg/L, around 100 % of polyvinyl alcohol was degraded, indicating that UV-365 nm/S2O8 2− process has great potential in degrading polyvinyl alcohol in aqueous solutions.
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References
Behera SK, Kim JH, Guo XJ, Park HS (2008) Adsorption equilibrium and kinetics of polyvinyl alcohol from aqueous solution on powdered activated carbon. J Hazard Mater 153(3):1207–1214
Chou WL, Wang CT, Huang KY (2010) Investigation of process parameters for the removal of polyvinyl alcohol from aqueous solution by iron electrocoagulation. Desalination 251(1–3):12–19
Criquet J, Leitner NKV (2009) Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis. Chemosphere 77(2):194–200
Finley JH (1961) Spectrophotometric determination of polyvinyl alcohol in paper coatings. Anal Chem 33(13):1925–1927
Giroto JA, Guardani R, Teixeira ACSC, Nascimento CAO (2006) Study on the photo-Fenton degradation of polyvinyl alcohol in aqueous solution. Chem Eng Process 45(7):523–532
Goslich R, Dillert R, Bahnemann D (1997) Solar water treatment principles and reactors. Water Sci Technol 35(4):137–148
Hayon E, McGarvey JJ (1967) Flash photolysis in the vacuum ultraviolet region of SO4 2−, CO3 2− and OH− ions in aqueous solutions. J Phys Chem 71(5):1472–1477
Hori H, Yamamoto A, Hayakawa E, Taniyasu S, Yamashita N, Kutsuna S, Kiatagawa H, Arakawa R (2005) Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant. Environ Sci Technol 39(7):2383–2388
Hori H, Yamamoto A, Koike K, Kutsuna S, Osaka I, Arakawa R (2007) Persulfate-induced photochemical decomposition of a fluorotelomer unsaturated carboxylic acid in water. Water Res 41(13):2962–2968
Hsu LJ, Lee LT, Lin CC (2011) Adsorption and photocatalytic degradation of polyvinyl alcohol in aqueous solutions using P-25 TiO2. Chem Eng J 173(3):698–705
Huang KC, Couttenye RA, Hoag GE (2002) Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE). Chemosphere 49(4):413–420
Huie RE, Clifton CL, Neta P (1991) Electron transfer reaction rates and equilibria of the carbonate and sulfate radical anions. Radiat Phys Chem 38(5):477–481
Kang SF, Liao CH, Chen MC (2002) Pre-oxidation and coagulation of textile wastewater by the Fenton process. Chemosphere 46(6):923–928
Lau TK, Chu W, Graham NJD (2007) The aqueous degradation of butylated hydroxyanisole by UV/S2O8 2−: study of reaction mechanisms via dimerization and mineralization. Environ Sci Technol 41(2):613–619
Li SX, Wei D, Mak NK, Cai ZW, Xu XR, Li HB, Jiang Y (2009) Degradation of diphenylamine by persulfate: performance optimization, kinetics and mechanism. J Hazard Mater 164(1):26–31
Liang CJ, Wang ZS, Bruell CJ (2007) Influence of pH on persulfate oxidation of TCE at ambient temperatures. Chemosphere 66(1):106–113
Lin YT, Liang CJ, Chen JH (2011) Feasibility study of ultraviolet activated persulfate oxidation of phenol. Chemosphere 82(8):1168–1172
Sahoo MK, Sinha B, Marbaniang M, Naik DB (2011) Degradation and mineralization of Calcon using UV365/H2O2 technique: influence of pH. Desalination 280(1–3):266–272
Salari D, Niaei A, Aber S, Rasoulifard MH (2009) The photooxidative destruction of C.I. basic yellow 2 using UV/S2O8 2− process in a rectangular continuous photoreactor. J Hazard Mater 166(1):61–66
Solaro R, Corti A, Chillini E (2000) Biodegradation of poly(vinyl alcohol) with different molecular weights and degree of hydrolysis. Polym Adv Technol 11(8–12):873–878
Tokiwa Y, Kawabata G, Jarerat A (2001) A modified method for isolating poly(vinyl alcohol)-degrading bacteria and study of their degradation patterns. Biotechnol Lett 23(23):1937–1941
Won YS, Baek SO, Tavakoli J (2001) Wet oxidation of aqueous polyvinyl alcohol solution. Ind Eng Chem Res 40(1):60–66
Xu SC, Zhou H, Wei X, Jun L (1989) The pH dependence and effects of the oxidative products of some aromatic compounds in ozonation under UV irradiation. Ozone Sci Eng 11(3):281–296
Yu XY, Bao ZC, Barker JR (2004) Free radical reactions involving Cl·, Cl2 ·−, and SO4 ·− in the 248 nm photolysis of aqueous solutions containing S2O8 2− and Cl−. J Phys Chem A 108(2):295–308
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The authors would like to thank the National Science Council of the Republic of China, Taiwan, for financially supporting this research under Contract No. NSC 100-2815-C-182-019-E.
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Lin, CC., Lee, LT. & Hsu, LJ. Degradation of polyvinyl alcohol in aqueous solutions using UV-365 nm/S2O8 2− process. Int. J. Environ. Sci. Technol. 11, 831–838 (2014). https://doi.org/10.1007/s13762-013-0280-6
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DOI: https://doi.org/10.1007/s13762-013-0280-6