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Efficient enrichment and trace determination of hazardous compound of 2,4-dinitrophenol in environmental water samples using 2-aminothiophenol magnetic nanoadsorbent

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Abstract

Aromatic compounds, such as 2,4-dinitrophenol (2,4-DNP), are one of the significant sources of environmental pollutants that are toxic compounds and have noxious effects on the environment and human health. In this project, 2-aminothiophenol magnetic nanoadsorbent (γ-Fe2O3@2-ATP) was synthesized and characterized. The prepared γ-Fe2O3@2-ATP was evaluated as a selective and efficient magnetic nanoadsorbent in the magnetic dispersive micro-solid phase extraction (MD–μ-SPE) method for the preconcentration and determination of trace amount of 2,4-DNP in the water samples spectrophotometrically. The significant variables, including the pH, amounts of sorbent, adsorption time, and desorption time, were optimized by experimental design method. Under optimized conditions, the linear range, limit of detection, and the relative standard deviation (%R.S.D) for the 2,4-DNP were 10–400, 2.73 ng mL−1, and 2.44% (n = 4), respectively. The method was successfully applied for the determination of 2,4-DNP in three different environmental water samples. It was validated via the analysis of the selected real samples by the high-performance liquid chromatography-ultraviolet detection method. Excellent recoveries for 2,4-DNP determination were obtained in spiked real samples.

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References

  1. M. Villar-Navarro, M. Ramos-Payán, J.L. Pérez-Bernal, R. Fernández-Torres, M. Callejón-Mochón, M.A. Bello-López, Talanta 99, 55 (2012). https://doi.org/10.1016/j.talanta.2012.05.020

    Article  CAS  PubMed  Google Scholar 

  2. V.V. Kadam, S.D. Shanmugam, J.P. Ettiyappan, R.M. Balakrishnan, Environ. Sci. Pollut. Res. 28, 12119 (2021). https://doi.org/10.1007/s11356-020-10833-w

    Article  CAS  Google Scholar 

  3. A. Penalver, E. Pocurull, F. Borrull, R.M. Marce, J. Chromatogr. A 953, 79 (2002). https://doi.org/10.1016/S0021-9673(02)00113-9

    Article  CAS  PubMed  Google Scholar 

  4. L. Zhu, L. Zhu, H.K. Lee, J. Chromatogr. A 924, 407 (2001). https://doi.org/10.1016/S0021-9673(01)00906-2

    Article  CAS  PubMed  Google Scholar 

  5. T. Jing, H. Xia, J. Niu, Y. Zhou, Q. Dai, Q. Hao, Y. Zhou, S. Mei, Biosens. Bioelectron. 26, 4450 (2011). https://doi.org/10.1016/j.bios.2011.05.001

    Article  CAS  PubMed  Google Scholar 

  6. W. Luo, L. Zhu, C. Yu, H. Tang, H. Yu, X. Li, X. Zhang, Anal. Chim. Acta 618, 147 (2008). https://doi.org/10.1016/j.aca.2008.04.051

    Article  CAS  PubMed  Google Scholar 

  7. E. Dehghanifard, A. Jonidi Jafari, R. Rezaei Kalantary, A.H. Mahvi, M.A. Faramarzi, A. Esrafili, Iran. J. Environ. Health Sci. Eng. 10, 1 (2013). https://doi.org/10.1186/1735-2746-10-25

    Article  CAS  Google Scholar 

  8. K. Srinivasan, T. Stalin, K. Sivakumar, Spectrochim. Acta A. Mol. Biomol Spectrosc. 94, 89 (2012). https://doi.org/10.1016/j.saa.2012.03.066

    Article  CAS  PubMed  Google Scholar 

  9. J. Michałowicz, W. Duda, Pol. J. Environ. Stud. 16, 347 (2007)

    Google Scholar 

  10. J. Jiang, Z. Yuan, W. Huang, J. Wang, Toxicol. Ind. Health 27, 323 (2011). https://doi.org/10.1177/0748233710387004

    Article  CAS  Google Scholar 

  11. L. Phillips, M.A. Singer, Neurol. 80, 773 (2013). https://doi.org/10.1212/WNL.0b013e3182825367

    Article  Google Scholar 

  12. F. Xu, W.N. Guan, G.Y. Yao, Y.F. Guan, J. Chromatogr. A 1186, 183 (2008). https://doi.org/10.1016/j.chroma.2007.08.063

    Article  CAS  PubMed  Google Scholar 

  13. A. Preiss, A. Bauer, H.M. Berstermann, S. Gerling, R. Haas, A. Joos, A. Lehmann, L. Schmalz, K. Steinbach, J. Chromatogr. A 1216, 4968 (2009). https://doi.org/10.1016/j.chroma.2009.04.055

    Article  CAS  PubMed  Google Scholar 

  14. M. Saraji, M. Marzban, Anal. Bioanal. Chem. 396, 2685 (2010). https://doi.org/10.1007/s00216-010-3496-z

    Article  CAS  PubMed  Google Scholar 

  15. D. Hofmann, F. Hartmann, H. Herrmann, Anal. Bioanal. Chem. 391, 161 (2008). https://doi.org/10.1007/s00216-008-1939-6

    Article  CAS  PubMed  Google Scholar 

  16. M.D.M. Abadi, N. Ashraf, M. Chamsaz, F. Shemirani, Talanta 99, 1 (2012). https://doi.org/10.1016/j.talanta.2012.05.027

    Article  CAS  Google Scholar 

  17. V. Andruch, L. Kocúrová, I.S. Balogh, J. Škrlíková, Microchem. J. 102, 1 (2012). https://doi.org/10.1016/j.microc.2011.10.006

    Article  CAS  Google Scholar 

  18. H. Abdolmohammad-Zadeh, E. Rahimpour, Anal. Chim. Acta 881, 54 (2015). https://doi.org/10.1016/j.aca.2015.04.035

    Article  CAS  PubMed  Google Scholar 

  19. A. Chisvert, S. Cárdenas, R. Lucena, TrAC-Trends anal. Chem. 112, 226 (2019). https://doi.org/10.1016/j.trac.2018.12.005

    Article  CAS  Google Scholar 

  20. S.C. Fu, S.H. Tzing, H.C. Chen, Y.C. Wang, W.H. Ding, Anal. Bioanal. Chem. 402, 2209 (2012). https://doi.org/10.1007/s00216-011-5681-0

    Article  CAS  PubMed  Google Scholar 

  21. N. Yahaya, T. Mitome, N. Nishiyama, M.M. Sanagi, W.A.W. Ibrahim, H. Nur, J. Pharm. Innov. 8, 240 (2013). https://doi.org/10.1007/s12247-013-9164-z

    Article  Google Scholar 

  22. P. Baile, L. Vidal, A. Canals, Talanta 220, 121 (2020). https://doi.org/10.1016/j.talanta.2020.121394

    Article  CAS  Google Scholar 

  23. R. Khani, S. Sobhani, T. Yari, Microchem. J. 146, 471 (2019). https://doi.org/10.1016/j.microc.2019.01.038

    Article  CAS  Google Scholar 

  24. S. Sobhani, Z. Vahidi, Z. Zeraatkar, S. Khodadadi, RSC Adv. 5, 36552 (2015). https://doi.org/10.1039/C5RA03334A

    Article  CAS  Google Scholar 

  25. S. Sobhani, Z. Zeraatkar, Appl. Organomet. Chem. 30, 12 (2016). https://doi.org/10.1002/aoc.3392

    Article  CAS  Google Scholar 

  26. S. Pirsa, E. Banafshechin, S. Amiri, A. Rahimirad, J. Ghafarzadeh, J. Iran. Chem. Soc. 18, 1167 (2021). https://doi.org/10.1007/s13738-020-02100-z

    Article  CAS  Google Scholar 

  27. M. Jiang, Z. Zheng, Environ. Sci. Pollut. Res. 25, 23276 (2018). https://doi.org/10.1007/s11356-018-2009-z

    Article  CAS  Google Scholar 

  28. R. Khani, M. Ghalibafan, A. Farrokhi, Environ. Sci. Pollut. Res. 27, 26305 (2020). https://doi.org/10.1007/s11356-020-09033-3

    Article  CAS  Google Scholar 

  29. R. Khani, S. Sobhani, M.H. Beyki, S. Miri, Ecotoxicol. Environ. Saf. 150, 54 (2018). https://doi.org/10.1016/j.ecoenv.2017.12.018

    Article  CAS  PubMed  Google Scholar 

  30. M. Fang, F. Lei, J. Zhou, Y.N. Wu, Z.Y. Gong, Chin. Chem. Lett. 25, 1492 (2014). https://doi.org/10.1016/j.cclet.2014.06.015

    Article  CAS  Google Scholar 

  31. T. Boontongto, K. Siriwong, R. Burakham, Chromatographia 81, 735 (2018). https://doi.org/10.1007/s10337-018-3498-0

    Article  CAS  Google Scholar 

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Acknowledgements

The financial support from the University of Birjand, is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Birjand, Birjand, 97179-414, Iran

    Farzaneh Chahardehi, Rouhollah Khani & Sara Sobhani

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  1. Farzaneh Chahardehi
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  2. Rouhollah Khani
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  3. Sara Sobhani
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Correspondence to Rouhollah Khani.

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Chahardehi, F., Khani, R. & Sobhani, S. Efficient enrichment and trace determination of hazardous compound of 2,4-dinitrophenol in environmental water samples using 2-aminothiophenol magnetic nanoadsorbent. J IRAN CHEM SOC 20, 3033–3042 (2023). https://doi.org/10.1007/s13738-023-02895-7

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