Skip to main content
SpringerLink
Log in

Preparation of a highly selective Mo(VI) optical sensor by immobilization of quercetin on a transparent agarose membrane

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

Development of a highly selective optical sensor for determining Mo(VI) in water samples has been reported. The optical sensor was prepared through immobilizing quercetin as a proper ionophore on a transparent agarose film. Spectrophotometric investigations on the complex formation between quercetin and Ni2+, Ca2+, Cu2+, Fe2+, Cr3+, Fe3+, pb2+, and Co2+ metal ions in buffer solution showed a considerably higher stability constant for the Mo(VI) ion complex indicating its high selectivity for this metal ion. The contact of the sensing membrane with Mo(VI) ions at pH 2.7 led to a change in color from pale to dark yellow. The effects of ionophore concentration, pH, reaction time, and ionic strength were assessed. There was a linear relationship between the Mo(VI) concentrations and membrane absorbance at 430 nm within a range of 7.93 × 10−6 to 2 × 10−4 mol L−1with an R2 value of 0.993. There was no considerable interference from the concentration of some possibly interfering ions (100 times) to determine Mo(VI). Using the optical sensor, Mo(VI) ion was successfully determined in spiked sea and river water specimens.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. M.-H. Wu, J.-L. Lin, J. Wang, Z. Cui, Z. Cui, Biomed. Microdevice 11, 265 (2009)

    Article  Google Scholar 

  2. P. Hashemi, M. Hosseini, K. Zargoosh, K. Alizadeh, Sens. Actuators, B Chem. 153, 24 (2011)

    Article  CAS  Google Scholar 

  3. A.P. Veedu, P. Deivasigamani, Microporous Mesoporous Mater. 343, 112139 (2022)

    Article  Google Scholar 

  4. R. Heydari, M. Hosseini, A. Amraei, A. Mohammadzadeh, Mater. Sci. Eng., C 61, 333 (2016)

    Article  CAS  Google Scholar 

  5. G. Jindal, P. Vashisht, N. Kaur, Results in Chemistry 4, 100551 (2022)

    Article  CAS  Google Scholar 

  6. B. Kaczmarczyk, A. Kisiel, P. Piątek, K. Maksymiuk, A. Michalska, Talanta 227, 122147 (2021)

    Article  CAS  PubMed  Google Scholar 

  7. Z. Dikmen, O. Turhan, M. Yaman, V. Bütün, J. Photochem. Photobiol. A 419, 113456 (2021)

    Article  CAS  Google Scholar 

  8. S.K. Sahoo, G.-D. Kim, H.-J. Choi, J. Photochem. Photobiol. C 27, 30 (2016)

    Article  CAS  Google Scholar 

  9. H.M. Tay, P. Beer, Org. Biomol. Chem. 19, 4652 (2021)

    Article  CAS  PubMed  Google Scholar 

  10. K. Alizadeh, B. Rezaei, E. Khazaeli, J. Photochem. Photobiol. A: Chem. 417, 113371 (2021).

    Article  CAS  Google Scholar 

  11. M. Hosseini, R. Heydari, M. Alimoradi, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 128, 864 (2014)

    Article  CAS  Google Scholar 

  12. S. Khodadoust, N.C. Kouri, M.S. Talebiyanpoor, J. Deris, A.A. Pebdani, Mater. Sci. Eng. C 57, 304 (2015)

    Article  CAS  Google Scholar 

  13. T. Carofiglio, C. Fregonese, G.J. Mohr, F. Rastrelli, U. Tonellato, Tetrahedron 62, 1502 (2006)

    Article  CAS  Google Scholar 

  14. K. Alizadeh, R. Parooi, P. Hashemi, B. Rezaei, M.R. Ganjali, J. Hazard. Mater. 186, 1794 (2011)

    Article  CAS  PubMed  Google Scholar 

  15. M.M. Abolghasemi, M. Sobhi, M. Piryaei, Sens. Actuators B Chem. 224, 391 (2016)

    Article  CAS  Google Scholar 

  16. P. Hashemi, R.A. Zarjani, Sens. Actuators B Chem. 135, 112 (2008)

    Article  CAS  Google Scholar 

  17. M. Safdarian, P. Hashemi, M. Adeli, Anal. Chim. Acta 774, 44 (2013)

    Article  CAS  PubMed  Google Scholar 

  18. M.M. Sanagi, S.H. Loh, W.A.W. Ibrahim, M.N. Hasan, J. Chromatogr. A 1262, 43 (2012)

    Article  CAS  PubMed  Google Scholar 

  19. H. Tabani, K. Khodaei, P. Varanusupakul, M. Alexovič, Microchem. J. 153, 104520 (2020)

    Article  CAS  Google Scholar 

  20. A. Erdamar, M.F. Aksahin, Biomed. Signal Process. Control 56, 101672 (2020)

    Article  Google Scholar 

  21. M. Khodadadi Yazdi, A. Taghizadeh, M. Taghizadeh, F. J. Stadler, M. Farokhi, F. Mottaghitalab, P. Zarrintaj, J. D. Ramsey, F. Seidi, M. R. Saeb, M. Mozafari, J. Controlled Release 326,523 (2020).

  22. H. Tabani, M. Alexovič, J. Sabo, M. Ramos Payán, Talanta 224, 121892 (2021).

    Article  CAS  PubMed  Google Scholar 

  23. S.M. Majidi, M.R. Hadjmohammadi, Talanta 222, 121649 (2021)

    Article  CAS  PubMed  Google Scholar 

  24. P. Hashemi, M.M. Abolghasemi, Sens. Actuators B Chem. 115, 49 (2006)

    Article  CAS  Google Scholar 

  25. P. Hashemi, R.A. Zarjani, M.M. Abolghasemi, Å. Olin, Sens. Actuators B Chem. 121, 396 (2007)

    Article  CAS  Google Scholar 

  26. A. Ghiasvand, S. Shadabi, E. Mohagheghzadeh, P. Hashemi, Talanta 66, 912 (2005)

    Article  CAS  PubMed  Google Scholar 

  27. R. Dass, J. K. Kapoor, S. Gambhir, J. Chem. 2013 (2013).

  28. R. Singh, R. Dwivedi, S. Sharma, J. Indian Chem. Soc. 81, 454 (2004)

    CAS  Google Scholar 

  29. S. Sun, W. Chen, W. Cao, F. Zhang, J. Song, C. Tian, J. Mol. Struct. (Thoechem) 860, 40 (2008)

    Article  CAS  Google Scholar 

  30. R. Ravichandran, M. Rajendran, D. Devapiriam, Food Chem. 146, 472 (2014)

    Article  CAS  PubMed  Google Scholar 

  31. P. Hashemi, M.M. Abolghasemi, K. Alizadeh, R.A. Zarjani, Sens. Actuators B Chem. 129, 332 (2008)

    Article  CAS  Google Scholar 

  32. M.S.G.K.G.H. Rounaghi, M. Chamsaz, Sens. Actuators B Chem. 256, 968 (2018)

    Article  Google Scholar 

  33. I. Matsumoto, Y. Mizuno, N. Seno, J. Biochem. 85, 1091 (1979)

    Article  CAS  PubMed  Google Scholar 

  34. E. Anticó, M. Lerchi, B. Rusterholz, N. Achermann, M. Badertscher, M. Valiente, E. Pretsch, Anal. Chim. Acta 388, 327 (1999)

    Article  Google Scholar 

  35. D. Kara, C. Karadaş, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 147, 158 (2015)

    Article  CAS  Google Scholar 

  36. A.B. Monji, E. Zolfonoun, S.J. Ahmadi, Toxicol. Environ. Chem. 91, 1229 (2009)

    Article  CAS  Google Scholar 

  37. A. Tunçeli, A. Rehber Türker, Microchim. Acta 144 (2004) 69.

    Article  Google Scholar 

  38. J. R. d. Carvalho, E. L. Reis, C. Reis, O. I. Damasceno, A. A. Neves, A. A. Matias, J. Braz. Chem. Soc. 31, 716 (2020).

    Google Scholar 

  39. D. Snigur, A. Chebotarev, V. Dubovyiy, D. Barbalat, K. Bevziuk, Microchem. J. 142, 273 (2018)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, Lorestan University, Khorramabad, Iran

    Elham Bazgir, Payman Hashemi & Fariba Nazari Serenjeh

  2. Department of Chemistry, Doroud Branch, Islamic Azad University, Doroud, Iran

    Akram Rahimi

Authors
  1. Elham Bazgir
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Payman Hashemi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Akram Rahimi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fariba Nazari Serenjeh
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

EB contributed to conceptualization, formal analysis, methodology, investigation, and writing—original draft. PH contributed to supervision, project administration, investigation, review & editing. AR contributed to validation, writing—review & editing. FNS contributed to conceptualization, investigation, and methodology.

Corresponding author

Correspondence to Payman Hashemi.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bazgir, E., Hashemi, P., Rahimi, A. et al. Preparation of a highly selective Mo(VI) optical sensor by immobilization of quercetin on a transparent agarose membrane. J IRAN CHEM SOC 20, 2739–2746 (2023). https://doi.org/10.1007/s13738-023-02870-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-023-02870-2

Keywords

Search

Navigation