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Hydrogen adsorption of some new Mercury(II)-benzotriazole dithiocarbamate mixed ligand complexes: kinetic studies

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Abstract

Preparation of series of new Mercury (II) mixed ligand complexes of benzotriazol dithiocarbamate (DTC) [Hg(DTC)2] and phosphine or amine ligands of the type [Hg(DTC)2(diphosphine)] (2–5), [(Hg(DTC)2(diamine)](6,7), [Hg(DTC)2(SPPh3)2] (8) and [Hg(DTC)2(PPh3)2] (9) has been done. This preparation has yielded good amount of these complexes. These complexes were fully characterized by elemental analysis, conductivity measurements and spectroscopic data (FTIR, 1H, 31P-{1H} NMR. Three as–prepared complexes were used for hydrogen storage at a pressure range of 0–100 bar at 77 K. The results prove that the complex [Hg(DTC)2(dppf)] has the ability to store 3.7 wt.% at 77 K under 90 bar and the storage was started under only 20 bar (0.22 wt.%). The kinetic studies on the hydrogen storage in this complex were conducted and the results prove that the storage was conducted in 60 s only and the adsorption is fitted to the second pseudo order with R2 = 0.99.

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Acknowledgements

The authors are grateful to Tikrit University for its support.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Tikrit University, Tikrit, Iraq

    Emaad M. A. Al-Janabi, Subhi A. Al-Jibori, Ahmed S. Faihan & Ahmed S. Al-Janabi

  2. Department of Nursing, Al-Hadi University College, Baghdad, Iraq

    Mustafa A. Alheety

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Al-Janabi, E.M.A., Alheety, M.A., Al-Jibori, S.A. et al. Hydrogen adsorption of some new Mercury(II)-benzotriazole dithiocarbamate mixed ligand complexes: kinetic studies. J IRAN CHEM SOC 20, 1781–1790 (2023). https://doi.org/10.1007/s13738-023-02796-9

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