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Investigation of catalytic activity of vanadyl sulphate immobilized on prepared UiO-66 modified with urea and melamine as allyl alcohol epoxidation catalysts

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Abstract

The modification of UiO-66 with urea and melamine were carried out using ZrCl4, benzene dicarboxylic acid and designated as U-B-Zr and M-B-Zr, followed by immobilization of vanadyl sulphate on U-B-Zr and M-B-Zr as U-B-Zr-VO-and M-B-Zr-VO, respectively. The prepared compounds as catalysts were characterized by XRD, BET, XPS, TGA, SEM, FTIR and CHN techniques. It was found that the prepared catalysts show moderate to high activity towards the epoxidation of some allyl alcohols such as trans-2-hexene-1-ol and 1-octen-3-ol and geraniol with 80%–100% conversions and 100% selectivity towards the formation of the corresponding epoxides. The prepared catalysts were also found to be reusable up four catalytic cycles without any appreciable loss in activity.

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References

  1. G. Ferey, Chem. Soc. Rev. 37, 191–214 (2008)

    Article  CAS  PubMed  Google Scholar 

  2. J.-R. Li, R.J. Kuppler, H.-C. Zhou, Chem. Soc. Rev. 38, 1477–1504 (2009)

    Article  CAS  PubMed  Google Scholar 

  3. Y. Bai, Y. Dou, L.-H. Xie, W. Rutledge, J.-R. Li, H.-C. Zhou, Chem. Soc. Rev. 45, 2327–2367 (2016)

    Article  CAS  PubMed  Google Scholar 

  4. A. Ma, Z. Luo, C. Gu, B. Li, J. Liu, Inorg. Chem. Communi. 77, 68–71 (2017)

    Article  CAS  Google Scholar 

  5. P. Kumar, A. Pournara, K.-H. Kim, V. Bansal, S. Rapti, M.J. Manos, Prog. Mater. Sci. 86, 25–74 (2017)

    Article  CAS  Google Scholar 

  6. A. Kirchon, L. Feng, H.F. Drake, E.A. Josepha, H.-C. Zhou, Chem. Soc. Rev. 47, 8611–8638 (2018)

    Article  CAS  PubMed  Google Scholar 

  7. J.H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K.P. Lillerud, J. Am. Chem. Soc. 130, 13850–13851 (2008)

    Article  PubMed  Google Scholar 

  8. A.M. Ebrahim, T.J. Bandosz, Micropor. Mesopor. Mater. 188, 149–162 (2014)

    Article  CAS  Google Scholar 

  9. H.G.T. Nguyen, N.M. Schweitzer, C.-Y. Chang, T.L. Drake, M.C. So, P.C. Stair, O.K. Farha, J.T. Hupp, S.T. Nguyen, ACS Catal. 4, 2496–2500 (2014)

    Article  CAS  Google Scholar 

  10. H.G.T. Nguyen, L. Mao, A.W. Peters, C.O. Audu, Z.J. Brown, O.K. Farha, J.T. Hupp, S.T. Nguyen, Catal. Sci. Tech. 5, 4444–4451 (2015)

    Article  CAS  Google Scholar 

  11. H. Fei, J. Shin, Y.S. Meng, M. Adelhardt, J. Sutter, K. Meyer, S.M. Cohen, J. Am. Chem. Soc. 136, 4965–4973 (2014)

    Article  CAS  PubMed  Google Scholar 

  12. E. Geravand, F. Farzaneh, M. Ghiasi, J. Mol. Struct. 1198, 126940 (2019)

    Article  CAS  Google Scholar 

  13. R. Gil-San-Millan, E. López-Maya, M. Hall, N.M. Padial, G.W. Peterson, J.B. DeCoste, L.M. Rodríguez-Albelo, J.E. Oltra, E. Barea, J.A.R. Navarro, A.C.S. Appl, Mater. Inter. 9, 23967–23973 (2017)

    Article  CAS  Google Scholar 

  14. P. Van Der Voort, K. Leus, Y.-Y. Liu, M. Vandichel, V. Van Speybroeck, M. Waroquier, S. Biswas, New. J. Chem. 38, 1853–1867 (2014)

    Article  Google Scholar 

  15. E. Geravand, F. Farzaneh, M. Ghiasi. J. Mol. Struct. 1253, 132248 (2022)

    Article  CAS  Google Scholar 

  16. E. Geravand, F. Farzaneh, R. Gil-San-Millan, F.J. Carmona, J.A.R. Navarro, Inorg. Chem. 59, 16160–16167 (2020)

    Article  CAS  PubMed  Google Scholar 

  17. S. Sadeghi, M. Jafarzadeh, A. Reza Abbasi, K. Daasbjerg, New. J. Chem. 41, 12014–12027 (2017)

    Article  CAS  Google Scholar 

  18. Y. Luan, Y. Qi, Z. Jin, X. Peng, H. Gao, G. Wang, RSC Adv. 5, 19273–19278 (2015)

    Article  CAS  Google Scholar 

  19. J.M. Roberts, B.M. Fini, A.A. Sarjeant, O.K. Farha, J.T. Hupp, K.A. Scheidt, J. Am. Chem. Soc. 134, 3334–3337 (2012)

    Article  CAS  PubMed  Google Scholar 

  20. Z. Su, Y.-R. Miao, G. Zhang, J.T. Miller, K.S. Suslick, Chem. Sci. 8, 8004–8011 (2017)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  21. G. Silversmit, D. Depla, H. Poelman, G.B. Marin, R. De Gryse, Sur. Sci. 600, 3512–3517 (2006)

    Article  CAS  Google Scholar 

  22. A. Wang, Y. Zhou, Z. Wang, M. Chen, L. Sun, X. Liu, RSC Adv. 6, 3671–3679 (2016)

    Article  CAS  Google Scholar 

  23. S. Dorbes, C. Pereira, M. Andrade, D. Barros, A. Pereira, S. Rebelo, J. Araujo, J. Pires, A. Carvalho, C. Freire, Micropor. Mesopor. Mater. 160, 67–74 (2012)

    Article  CAS  Google Scholar 

  24. E. Zamanifar, F. Farzaneh, React. Kinet. Mech. Catal. 104, 197–209 (2011)

    Article  CAS  Google Scholar 

  25. L. Hamidipour, F. Farzaneh, Compt. Rendus. Chem. 17, 927–933 (2014)

    Article  CAS  Google Scholar 

  26. L.M. Slaughter, J.P. Collman, T.A. Eberspacher, J.I. Brauman, Inorg. Chem. 43, 5198–5204 (2004)

    Article  CAS  PubMed  Google Scholar 

  27. Z. Azarkamanzad, F. Farzaneh, M. Maghami, J. Simpson, M. Azarkish, Appl. Organomet. Chem. 32, 4168 (2018)

    Article  Google Scholar 

  28. A. Rezaeifard, I. Sheikhshoaie, N. Monadi, M. Alipour, Polyhedron 29, 2703–2709 (2010)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors would appreciate Alzahra University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O. Box 1993893973, Vanak, Tehran, Iran

    Elham Geravand, Safura Talatimehr, Maryam Ghahremani & Faezeh Farzaneh

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  1. Elham Geravand
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  2. Safura Talatimehr
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  3. Maryam Ghahremani
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  4. Faezeh Farzaneh
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Correspondence to Faezeh Farzaneh.

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Geravand, E., Talatimehr, S., Ghahremani, M. et al. Investigation of catalytic activity of vanadyl sulphate immobilized on prepared UiO-66 modified with urea and melamine as allyl alcohol epoxidation catalysts. J IRAN CHEM SOC 19, 4669–4677 (2022). https://doi.org/10.1007/s13738-022-02649-x

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