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Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization

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Abstract

Pt loaded on a series of MIL-53(Al) metal−organic framework, FDU˗12 mesoporous silica and FDU˗12 composites with HZSM-5 zeolite and TiO2 has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed. These new catalysts have high conversion and selectivity to isomerized products (i-C7). The best i-C7 selectivity (65.4%) was observed for Pt/MIL-53(Al) at T=200 °C. These catalysts have a low selectivity to undesired products such as aromatic and cracking products.

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Authors and Affiliations

  1. Department of Physical and Computational Chemistry, Faculty of Chemistry Science and Petroleum, Shahid Beheshti University, Tehran, 1983963113, Iran

    Z. Ghaderi & M. H. Peyrovi

  2. Department of Applied Chemistry, Kosar University of Bojnord, North Khorasan, Iran

    N. Parsafard

Authors
  1. Z. Ghaderi
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  2. M. H. Peyrovi
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  3. N. Parsafard
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Correspondence to N. Parsafard.

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Ghaderi, Z., Peyrovi, M.H. & Parsafard, N. Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization. J IRAN CHEM SOC 19, 4679–4685 (2022). https://doi.org/10.1007/s13738-022-02630-8

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  • DOI: https://doi.org/10.1007/s13738-022-02630-8

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