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Fabrication and characterization of the immobilized Cu(II) and Ni(II) species on silica-coated copper ferrite: as novel magnetically reusable nanocatalysts toward synthesis of biscoumarins

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Abstract

In this study, we have synthesized magnetically nanoparticles (MNPs) of CuFe2O4@SiO2@AAPTMS@Ni(II) and CuFe2O4@SiO2@AAPTMS@Cu(II). The prepared nanocomposite systems were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, Brunauer–Emmett–Teller analysis, vibrating-sample magnetometer and inductively coupled plasma optical emission spectroscopy. Catalytic activity of CuFe2O4@SiO2@AAPTMS@Ni(II) and CuFe2O4@SiO2@AAPTMS@Cu(II) MNPs was also studied toward one-pot the Knoevenagel–Michael reaction of aromatic aldehydes with 4-hydroxycoumarin. All reactions were carried using 40 mg of the nanocatalysts in refluxing H2O within 12‒45 min to afford biscoumarin materials in 84–96% yield. The obtained results exhibited that catalytic activity of the Ni(II)-composite system was higher than the Cu(II)-analogue. Moreover, reusability of the nanocatalysts was examined for five consecutive cycles without the significant loss of the catalytic activity.

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Acknowledgements

The authors gratefully acknowledged the financial support of this work by the research council of Urmia University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Urmia University, Urmia, 5756151818, Iran

    Behzad Zeynizadeh, Maryam Sadeghbari & Nader Noroozi Pesyan

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  1. Behzad Zeynizadeh
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  2. Maryam Sadeghbari
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Correspondence to Behzad Zeynizadeh.

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Zeynizadeh, B., Sadeghbari, M. & Noroozi Pesyan, N. Fabrication and characterization of the immobilized Cu(II) and Ni(II) species on silica-coated copper ferrite: as novel magnetically reusable nanocatalysts toward synthesis of biscoumarins. J IRAN CHEM SOC 17, 73–88 (2020). https://doi.org/10.1007/s13738-019-01750-y

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