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Porous ZSM-5 zeolite catalyst modified with sulfonic acid functional groups for hydrolysis of biomass

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Abstract

A porous sulfonated ZSM-5 zeolite has been successfully synthesized by grafting sulfonic acid groups on the surface and/or the pores. Structural properties of the mesoporous HSO3-ZSM-5 zeolite are characterized by XRD, IR, SEM, BET, and NH3-TPD. Catalytic performance of the sulfonated ZSM-5 in biomass hydrolysis, an important process for production of useful sugar for chemical industry, is investigated. Possessing strong acid groups HSO3, the as-obtained catalyst shows high catalytic activity and high efficiency in the hydrolysis of cellulosic pulp and corncob. Moreover, this catalyst can be reused impressively for several times with no significant loss in catalytic activity.

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Acknowledgements

This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant Number 104.03-2015.15.

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Authors and Affiliations

  1. School of Chemical Engineering, Hanoi University of Science and Technology, No. 1, Dai Co Viet Street, Hanoi, Vietnam

    Phan Huy Hoang, Nguyen Hoang Chung & Le Quang Dien

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  1. Phan Huy Hoang
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  2. Nguyen Hoang Chung
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  3. Le Quang Dien
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Correspondence to Phan Huy Hoang.

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Hoang, P.H., Chung, N.H. & Dien, L.Q. Porous ZSM-5 zeolite catalyst modified with sulfonic acid functional groups for hydrolysis of biomass. J IRAN CHEM SOC 16, 2203–2210 (2019). https://doi.org/10.1007/s13738-019-01692-5

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  • DOI: https://doi.org/10.1007/s13738-019-01692-5

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