Skip to main content
SpringerLink
Log in

Determination of triazole fungicides in environmental water by magnetic solid-phase extraction coupled with UHPLC-MS/MS

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

A simple, rapid and environmentally friendly method was developed for the determination of triazole fungicides (TFs) in environmental water by magnetic solid-phase extraction coupled with UHPLC-MS/MS. The target analytes were quantitatively adsorbed on magnetic multi-wall carbon nanotubes (M-MWCNTs), and then magnetically isolated. After desorption with acetone, the spiked samples were analyzed by UHPLC-MS/MS under optimized conditions, which demonstrated good linearity between 0.04 and 500.0 µg L−1 with the correlation coefficient of 0.9992–0.9998, the limits of detection of 0.011–0.067 µg L−1 and the limits of quantification of 0.037–0.224 µg L−1.The accuracy of the proposed method was evaluated by measuring the recovery of the spiked samples, which ranged from 91.2 to 108.4% with the relative standard deviations from 1.0 to 7.5% for the spiked samples. The proposed method has been successfully applied to the determination of the target compounds in real environmental water samples. The results demonstrate that the developed method has great potential for the determination of TFs in water.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. P.B. Miniyar, A.A. Mahajan, S.N. Mokale, M.U. Shah, A.S. Kumar, G.U. Chaturbhuj, Arab. J. Chem. 10, 295 (2017)

    Article  CAS  Google Scholar 

  2. C.Y. Tian, J. Xu, F.S. Dong, X.G. Liu, X.H. Wu, Y.Q. Zheng, Chin. J. Pestic. Sci. 18, 141 (2016)

    CAS  Google Scholar 

  3. J.H. Zhou, J.Y. Zhang, F.X. Li, J. Liu, J. Hazard. Mater. 308, 294 (2016)

    Article  CAS  PubMed  Google Scholar 

  4. M.A. Farajzadeh, S. Sheykhizadeh, P. Khorram, Food. Anal. Method 7, 1229 (2014)

    Article  Google Scholar 

  5. Y.H. Zhang, Y. Zhang, Q.Y. Zhao, W.J. Chen, B.N. Jiao, Food. Anal. Method 9, 596 (2016)

    Article  Google Scholar 

  6. Q.H.C. Wang, C.X. Wu, Z. Wu, Wang, J. Hazard. Mater. 185, 71 (2011)

    Article  CAS  PubMed  Google Scholar 

  7. R. Bordagaray, E. Garcia-Arrona, Millán, Food. Anal. Method 7, 1195 (2014)

    Article  Google Scholar 

  8. H. Su, Y.L. Lin, Z. Wang, Y.L.E. Wong, X.F. Chen, T.W.D. Chan, J. Chromatogr. A 1141, 117 (2007)

    Article  CAS  Google Scholar 

  9. J. Li, F.S. Dong, J. Xu, X.G. Liu, Y.B. Lia, W.L. Shan, Y.Q. Zheng, Anal. Chim. Acta 702, 127 (2011)

    Article  CAS  PubMed  Google Scholar 

  10. Y.B. Li, F.S. Dong, X.G. Liu, J. Xu, J. Li, Z.Q. Kong, X. Chen, X.Y. Liang, Y.Q. Zheng, J. Chromatogr. A 1224, 51 (2012)

    Article  CAS  PubMed  Google Scholar 

  11. R. Konášová, J.J. Dytrtová, V. Kašička, J. Chromatogr. A 1408, 243 (2015)

    Article  CAS  PubMed  Google Scholar 

  12. T. Tang, K. Qian, T.Y. Shi, F. Wang, J.Q. Li, Y.S. Cao, Anal. Chim. Acta 680, 26 (2010)

    Article  CAS  PubMed  Google Scholar 

  13. Y.L. Wu, R.X. Chen, Y. Zhu, J. Zhao, T. Yang, J. Chromatogr. B 989, 11 (2015)

    Article  CAS  Google Scholar 

  14. N. Wang, M. Su, S.X. Liang, H.W. Sun Food. Chem. 199, 1 (2016)

    Article  CAS  PubMed  Google Scholar 

  15. M. N. Jalbani, Soylak, Ecotoxicol. Environ. Saf. 102, 174 (2014)

    Article  CAS  PubMed  Google Scholar 

  16. S.Q. Zhu, B.B. Chen, M. He, T. Huang, B. Hu, Talanta 171, 213 (2017)

    Article  CAS  PubMed  Google Scholar 

  17. P. Sun, Y.L. Gao, C. Xu, Y.F. Lian, Food. Addit. Contam. A 34, 12 (2017)

    Article  CAS  Google Scholar 

  18. N.A. El Essawy, S.M. Ali, H.A. Farag, A. H. Konsowa, M. Elnouby, H. A. Hamad, Ecotoxicol. Environ Saf. 145, 57 (2017)

    Article  CAS  PubMed  Google Scholar 

  19. S.S. Zunngu, L.M. Madikizela, L. Chimuka, P.S. Mdluli, C.R. Chimie, C. R. Chim. 20, 585 (2017)

    Article  CAS  Google Scholar 

  20. L.C. Xu, J.M. Pan, J.D. Dai, X.X. Li, H. Hang, Z.J. Cao, Y.S. Yan, J. Hazard. Mater. 48, 233–234 (2012)

    Google Scholar 

  21. J.P. Kumar, P.V.R.K. Ramacharyulu, G.K. Prasad, B. Singh, Appl. Clay. Sci. 116–117, 263 (2015)

    Article  CAS  Google Scholar 

  22. H.R. Amiri, F.M. Saadati-Moshtaghin, A. Zonoz, Targhoo, J. Chromatogr. A 1483, 64 (2017)

    Article  CAS  PubMed  Google Scholar 

  23. R.R. Shan, L.G. Yan, K. Yang, Y.F. Hao, B. Du, J. Hazard. Mater. 299, 42 (2015)

    Article  CAS  PubMed  Google Scholar 

  24. H. Su. Y.L. Lin. Z.H. Wang. Y.L.E. Wong, T.W.D. Chan, J. Chromatogr. A 1466, 21 (2016)

    Article  CAS  PubMed  Google Scholar 

  25. F. Pena-Pereira, R.M.B.O. Duarte, T. Trindade, A.C. Duarte, J. Chromatogr. A 1299, 25 (2013)

    Article  CAS  PubMed  Google Scholar 

  26. M. Ahmadi, T. Madrakian, A. Afkhami, Anal. Chim. Acta 852, 250 (2014)

    Article  CAS  PubMed  Google Scholar 

  27. A.Y. Jee, M. Lee, Curr. Appl. Phys. 9, 144 (2009)

    Article  Google Scholar 

  28. L.R. Kong, X.F. Lu, W.J. Zhang, J. Solid. State. Chem. 181, 628 (2008)

    Article  CAS  Google Scholar 

  29. J.Y. Xue, H.C. Li, F.M. Liu, W.Q. Jiang, F. Hou, Food. Chem. 196, 867 (2016)

    Article  CAS  PubMed  Google Scholar 

  30. ÉA. Souza-Silva, V. Lopez-Avila, J. Pawliszyn,J. Chromatogr. A 1313, 139 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by Analytical Centre of Heilongjiang Bayi Agricultural University.

Author information

Authors and Affiliations

  1. Key Laboratory of Functional Inorganic Material Chemistry, School of Chemistry and Materials Science, Ministry of Education, Heilongjiang University, Harbin, 150080, China

    Peng Sun & Yongfu Lian

  2. Heilongjiang Bayi Agricultural University, Daqing, 163319, China

    Peng Sun & Yuling Gao

Authors
  1. Peng Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuling Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongfu Lian
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yongfu Lian.

Ethics declarations

Conflict of interest

The authors declare that there are no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sun, P., Gao, Y. & Lian, Y. Determination of triazole fungicides in environmental water by magnetic solid-phase extraction coupled with UHPLC-MS/MS. J IRAN CHEM SOC 16, 1483–1489 (2019). https://doi.org/10.1007/s13738-019-01614-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-019-01614-5

Keywords

Search

Navigation