Abstract
In this work, we report the synthesis, characterization, crystal structure, and thermal and antibacterial studies of a new nano-sized copper(I) thiosemicarbazone complex prepared by an ultrasonic bath assisted synthesis in an acetonitrile solution. Characterization of the complex and its ligand (EHB-tsc = 3-ethoxy-4-hydroxybenzaldehyde-thiosemicarbazone) was performed using elemental analysis, FT-IR, 1H and 13C-NMR, UV–Vis spectroscopy, thermal gravimetry, and single-crystal X-ray diffraction. In addition, the complex was characterized by X-ray powder diffraction and scanning electron microscopy.
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Acknowledgements
We are grateful to the Payame Noor University and Golestan University for the financial support of this work. Structure analysis was supported by the project 18-10504S of the Czech Science Foundation using instruments of the ASTRA lab established within the Operation program Prague Competitiveness e project CZ.2.16/3.1.00/2451.
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Khalaji, A.D., Shahsavani, E., Dusek, M. et al. Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study. J IRAN CHEM SOC 16, 1179–1187 (2019). https://doi.org/10.1007/s13738-019-01592-8
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DOI: https://doi.org/10.1007/s13738-019-01592-8