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Imprinted Azorubine electrochemical sensor based upon composition of MnO2 and 1-naphthylamine on graphite nanopowder

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Abstract

A new sensitive and selective molecularly imprinted electrochemical sensor was developed for Azorubine determination. This sensor was based on molecularly imprinted polymer composed of poly(1-naphthylamine), triphenylamine (as cross-linkers) and dispersed MnO2 nanorod particles on graphite nanopowders. The structure of the prepared nanocomposite was characterized by X-ray powder diffraction, energy-dispersive X-ray spectroscopy, field emission scanning electron microscopy, transmission electron microscopy and Fourier transform infrared spectroscopy. Calibration curve of the imprinted sensor was linear in the concentration range 1–12 mg L− 1 with a detection limit of 0.57 mg L− 1. The application of the sensor was checked by the determination of Azorubine in a water sample.

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Acknowledgements

The authors are gratefully indebted to Dr. Leila Dolatyari (Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, Iran) for an interesting discussion.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, 45371-38791, Islamic Republic of Iran

    Somayyeh Piri, Farideh Piri & Mohammad Reza Yaftian

  2. Department of Environmental Science, Faculty of Science, University of Zanjan, Zanjan, 45371-38791, Islamic Republic of Iran

    Abbasali Zamani

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  1. Somayyeh Piri
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  2. Farideh Piri
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  3. Mohammad Reza Yaftian
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  4. Abbasali Zamani
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Correspondence to Mohammad Reza Yaftian.

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Piri, S., Piri, F., Yaftian, M.R. et al. Imprinted Azorubine electrochemical sensor based upon composition of MnO2 and 1-naphthylamine on graphite nanopowder. J IRAN CHEM SOC 15, 2713–2720 (2018). https://doi.org/10.1007/s13738-018-1459-z

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  • DOI: https://doi.org/10.1007/s13738-018-1459-z

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