Skip to main content
SpringerLink
Log in

Response surface methodology for modelling and determination of catechin in Pistachio green hull using surfactant-based dispersive liquid–liquid microextraction followed by UV–Vis spectrophotometry

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

A rapid and simple approach for the preconcentration and determination of catechin from pistachio green hull samples has been proposed by surfactant-assisted dispersive liquid–liquid microextraction followed by UV–Vis spectrophotometry (SADLLME/UV–Vis). This method involved the formation of a catechin complex with cetylpyridinium chloride (CPC) as cationic surfactant, and subsequently, DLLME was applied to extract the catechin–CPC complex into chloroform. Different parameters affected the extraction efficiency were optimized by central composite design (CCD) and response surface methodology (RSM). In optimum condition, the calibration curve was linear in the range of 0.4–5 µg mL− 1 of catechin with correlation coefficient of 0.9982. The relative standard deviation based on five replicated analyses of 1 µg mL− 1 catechin was 1.85%. The proposed method was successfully applied for preconcentration and determination of trace amounts of catechin in pistachio hull samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. A. Agouni, A.H. Lagrue-Lak-Hal, H.A. Mostefai, A. Tesse, P. Mulder, P. Rouet, F. Desmoulin, C. Heymes, M.C. Martinez, R. Andriantsitohain, PLoS One. 4, 1 (2009)

    Article  CAS  Google Scholar 

  2. B. Shukitt-Hale, A. Carey, L. Simon, D.A. Mark, J.A. Joseph, Nutrition. 22, 295 (2006)

    Article  CAS  PubMed  Google Scholar 

  3. A. Basu, E.A. Lucas, Nutr. Rev. 65, 361 (2007)

    Article  PubMed  Google Scholar 

  4. C.Y. Chen, P.E. Milbury, K. Lapsley, J.B. Blumberg, J. Nutr. 135, 1366 (2005)

    Article  CAS  PubMed  Google Scholar 

  5. K.J. Anderson, S.S. Teuber, A. Gobeille, P. Cremin, A.L. Waterhouse, F.M. Steinberg, J. Nutr. 131, 2837 (2001)

    Article  CAS  PubMed  Google Scholar 

  6. P. Velayutham, A. Babu, D.D. Liu, Curr. Med. Chem. 15, 1840 (2008)

    Article  PubMed Central  Google Scholar 

  7. A.H. Goli, M. Barzegar, M.A. Sahari, Food Chem. 92, 521 (2005)

    Article  CAS  Google Scholar 

  8. A. Rajaei, M. Barzegar, A.M. Mobarez, M.A. Sahari, Z.H. Esfahani, Food Chem. Toxicol. 48, 107 (2010)

    Article  CAS  PubMed  Google Scholar 

  9. D. Barreca, G. Lagana, U. Leuzzi, A. Smeriglio, D. Trombetta, E. Bellocco, Food Chem. 196, 493 (2016)

    Article  CAS  PubMed  Google Scholar 

  10. F. Garavand, A. Madadlou, S. Moini, Int. J. Food Prop. 20, 19 (2017)

    Article  CAS  Google Scholar 

  11. E. Bellocco, D. Barreca, G. Lagana, A. Calderaro, Z.El Lekhlifi, S. Chebaibi, A. Smeriglio, D. Trombetta, J. Funct. Foods. 27, 376 (2016)

    Article  CAS  Google Scholar 

  12. M.H. Grace, D. Esposito, M.A. Timmers, J. Xiong, G. Yousef, S. Komarnytsky, M.A. Lila, Food Chem. 210, 85 (2016)

    Article  CAS  PubMed  Google Scholar 

  13. E. de Rijke, P. Out, W.M. Niessen, F. Ariese, C. Gooijer, U.A. Brinkman, J. Chromatogr A. 1112, 31 (2006)

    Article  CAS  PubMed  Google Scholar 

  14. X.L. Hu, J.Y. You, C.L. Bao, H. Zhang, X. Meng, T. Xiao, K. Zhang, Y. Wang, H. Wang, H. Zhang, A. Yu, Anal. Chim. Acta 610, 217 (2008)

    Article  CAS  PubMed  Google Scholar 

  15. A. Meda, C.E. Lamien, M. Romito, J. Millogo, O.G. Nacoulma, Food Chem. 91, 571 (2005)

    Article  CAS  Google Scholar 

  16. L.A. Lemos da Silva, B. Ramos Pezzini, L. Soares, Pharmacogn Mag 11, 96 (2015)

    Article  CAS  Google Scholar 

  17. M. Rezaee, Y. Assadi, M.R.M. Hosseini, E. Aghaee, F. Ahmadi, S. Berijani, J. Chromatogr. A. 1116, 1 (2006)

    Article  CAS  PubMed  Google Scholar 

  18. M. Rahmani, M. Kaykhaii, E. Ghasemi, M. Tahernejad, J. Chromatogr. Sci. 53, 1210 (2016)

    Article  CAS  Google Scholar 

  19. M. Polo, M. Llompart, C. Garcia-Jares, R. Cela, J. Chromatogr. A. 1072, 63 (2005)

    Article  CAS  PubMed  Google Scholar 

  20. C.L. Roriz, L. Barros, M.A. Prieto, P. Morales, I.C.F.R. Ferreira, Food Chem. 229, 223 (2017)

    Article  CAS  PubMed  Google Scholar 

  21. A. Asfaram, M. Ghaedi, S. Agarwal, I. Tyagi, V.K. Gupta, RSC Adv. 5, 18438 (2015)

    Article  CAS  Google Scholar 

  22. G.B. Celli, A. Ghanem, M.S.L. Brooks, Ultrason. Sonochem. 27, 449 (2015)

    Article  CAS  PubMed  Google Scholar 

  23. M.A. Bezerra, R.E. Santelli, E.P. Oliveira, L.S. Villar, L.A. Escaleira, Talanta. 76, 965 (2008)

    Article  CAS  PubMed  Google Scholar 

  24. A. Tomaino, M. Martorana, T. Arcoraci, D. Monteleone, C. Giovinazzo, A. Saija, Biochimie 92, 1115 (2010)

    Article  CAS  PubMed  Google Scholar 

  25. S.D. Brown, S.T. Sum, F. Despagne, Anal. Chem. 68, 21 (1996)

    Article  CAS  Google Scholar 

  26. P. Gemperline, Practical Guide to Chemometrics, 2nd edn. (CRC Press, Taylor & Francis Group, Boca Raton, Springer, 2006), p. 552

    Book  Google Scholar 

  27. D.D. Stephan, J. Werner, R.P. Yeater, Essential regression and experimental design for chemists and engineers, MS Excel Add-in Software Package (1998–2001)

  28. L.V. Candioti, J.C. Robles, V.E. Mantovani, H.C. Goicoechea, Talanta. 69, 140 (2006)

    Article  CAS  PubMed  Google Scholar 

  29. R.G. Brereton, Chemometrics, data analysis for the laboratory and chemical plant (John Wiley & Sons Ltd, Springer, England, 2003), p. 504

    Google Scholar 

  30. K. Shrivas, N.K. Jaiswal, Food Chem. 141, 2263 (2013)

    Article  CAS  PubMed  Google Scholar 

  31. L.M. Magalhaes, M.I.G.S. Almeida, L. Barreiros, S. Reis, A.S. Marcela, Food Anal. Methods 5, 530 (2012)

    Article  Google Scholar 

  32. D. Marinova, F. Ribarova, M. Atanassova, J. Univ. Chem. Technol. Metallurgy 40, 255 (2005)

    CAS  Google Scholar 

  33. Y. Jaiswal, P. Tatke, S. Gabhe, A. Vaidya, Pol. J. Food Nutr. Sci. 63, 49 (2013)

    CAS  Google Scholar 

  34. W.E. Bronner, G.R. Beecher, J. Chromatogr A. 805, 137 (1998)

    Article  CAS  PubMed  Google Scholar 

  35. N. Chaieb, M. Lopez-Mesas, J. Luis Gonzalez, M. Marsb, M. Valiente, Phytochem. Anal. 26, 346 (2015)

    Article  CAS  PubMed  Google Scholar 

  36. P. Vinas, N. Campillo, N. Martinez-Castillo, M. Hernandez-Cordoba, J. Chromatogr A. 1216, 1279 (2009)

    Article  CAS  PubMed  Google Scholar 

  37. P. Yang, H. Li, H. Wang, F. Han, S. Jing, C. Yuan, A. Guo, Y. Zhang, Z. Xu, Food Anal. Methods 10, 2383 (2017)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran

    Sima Ahmadi & Mohammad Taghi Hamed Mosavian

  2. Department of Chemistry, University of Torbat-e jam, Torbat-e jam, Iran

    Somayeh Heydari

Authors
  1. Sima Ahmadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohammad Taghi Hamed Mosavian
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Somayeh Heydari
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Somayeh Heydari.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahmadi, S., Hamed Mosavian, M.T. & Heydari, S. Response surface methodology for modelling and determination of catechin in Pistachio green hull using surfactant-based dispersive liquid–liquid microextraction followed by UV–Vis spectrophotometry. J IRAN CHEM SOC 15, 2605–2614 (2018). https://doi.org/10.1007/s13738-018-1449-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-018-1449-1

Keywords

Search

Navigation