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Headspace solid-phase microextraction of menthol using a sol–gel titania-based coating along with multiwalled carbon nanotubes on the surface of stainless steel fiber

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Abstract

Sol–gel coating technology for the preparation of solid-phase microextraction fibers involves a single-step procedure and allows for in situ creation of chemically bonded coatings which are characterized by high thermal and solvent stabilities. A novel titania sol–gel coating was prepared for the first time on a stainless steel fiber and applied for the headspace solid-phase microextraction (HS-SPME) of menthol with gas chromatography and flame ionization detection. Important parameters influencing the efficiency of SPME process, such as extraction time, extraction temperature and ionic strength, were optimized by central composite design. An extraction time of 40 min at 60 °C gave maximum extraction efficiency, when NaCl (10% w/v) was added to the aqueous sample. The analytical characteristics of the proposed method were comparable with other reported fibers. Under optimized conditions, the linearity was between 0.05 and 100 µg mL− 1. The relative standard deviations (RSDs) determined at 0.5 µg mL− 1 concentration level (n = 5) were as follows: intra-day RSD 7.26%; inter-day RSD 10.87%; fiber-to-fiber RSD 9.05%. The relative recoveries determined after spiking a mint distillate sample at three concentration levels from 0.067 to 50.0 µg mL− 1 varied from 86 to 102%. The proposed method was successfully applied for the analysis of menthol in peppermint samples.

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References

  1. A.A.S. de Sousa, P.M.G. Soares, A.N.S. de Almeida, A.R. Maia, E.P. de Souza, A.M.S. Assreuy, J. Ethnopharmacol. 130, 433–436 (2010)

    Article  CAS  PubMed  Google Scholar 

  2. M. Ligor, B. Buszewski, J. Chromatogr. A 847, 161–169 (1999)

    Article  CAS  Google Scholar 

  3. C.D. Neniţescu, Tratat elementar de chimie organică, vol II. Bucureşti (Editura Tehnică, 1958)

  4. E. Capecka, A. Mareczek, M. Leja, Food Chem. 93, 223–226 (2005)

    Article  CAS  Google Scholar 

  5. M. Adam, P. Dobiáš, P. Pavlíková, K. Ventura, Cent. Eur. J. Chem. 7, 303–311 (2009)

    CAS  Google Scholar 

  6. J. Dai, V. Orsat, G.V. Raghavan, V. Yaylayan, J. Food Eng. 96, 540–543 (2010)

    Article  CAS  Google Scholar 

  7. J. Pawliszyn, Solid phase Microextraction: Theory and Practice (John Wiley & Sons, New York, 1997)

    Google Scholar 

  8. S. Maghsoudi, E. Noroozian, Chromatographia 75, 913–921 (2012)

    Article  CAS  Google Scholar 

  9. C. Bicchi, S. Drigo, P. Rubiolo, J. Chromatogr. A 892, 469–485 (2000)

    Article  CAS  PubMed  Google Scholar 

  10. H. Asadollahzadeh, E. Noroozian, S. Maghsoudi, Anal. Chim. Acta 669, 32–38 (2010)

    Article  CAS  PubMed  Google Scholar 

  11. M. Behzadi, M. Mirzaei, M. Daneshpajooh, Anal. Methods 6, 9234–9241 (2014)

    Article  CAS  Google Scholar 

  12. M. Behzadi, E. Noroozian, M. Mirzaei, Talanta 108, 66–73 (2013)

    Article  CAS  PubMed  Google Scholar 

  13. M. Behzadi, E. Noroozian, M. Mirzaei, J. Sep. Sci. 36, 3550–3557 (2013)

    Article  CAS  PubMed  Google Scholar 

  14. M. Behzadi, E. Noroozian, M. Mirzaei, RSC Adv. 4, 50426–50434 (2014)

    Article  CAS  Google Scholar 

  15. A. Mollahosseini, E. Noroozian, Anal. Chim. Acta 638, 169–174 (2009)

    Article  CAS  PubMed  Google Scholar 

  16. H. Bagheri, A. Aghakhani, A. Es-haghi, Chromatographia 66, 779–783 (2007)

    Article  CAS  Google Scholar 

  17. H. Bagheri, Z. Ayazi, A. Aghakhani, Anal. Chim. Acta 683, 212–220 (2011)

    Article  CAS  PubMed  Google Scholar 

  18. X. Li, S. Gong, Z. Zeng, Chromatographia 62, 519–525 (2005)

    Article  CAS  Google Scholar 

  19. X. Li, Z. Zeng, S. Gao, H. Li, J. Chromatogr. A 1023, 15–25 (2004)

    Article  CAS  PubMed  Google Scholar 

  20. X. Li, Z. Zeng, J. Zhou, S. Gong, W. Wang, Y. Chen, J. Chromatogr. A 104, 1–9 (2004)

    Article  CAS  Google Scholar 

  21. M. Liu, Z. Zeng, Y. Lei, H. Li, J. Sep. Sci. 28, 2306–2318 (2005)

    Article  CAS  PubMed  Google Scholar 

  22. M. Azenha, C. Malheiro, A.F. Silva, J. Chromatogr. A 1069, 163–172 (2005)

    Article  CAS  PubMed  Google Scholar 

  23. V.G. Zuin, A.L. Lopes, J.H. Yariwake, F. Augusto, J. Chromatogr. A 1056, 21–26 (2004)

    Article  CAS  PubMed  Google Scholar 

  24. D. Wang, S.L. Chong, A. Malik, Anal. Chem. 69, 4566–4576 (1997)

    Article  CAS  Google Scholar 

  25. K. Alhooshani, T.-Y. Kim, A. Kabir, A. Malik, J. Chromatogr. A 1062, 1–14 (2005)

    Article  CAS  PubMed  Google Scholar 

  26. M. Liu, Y. Liu, Z. Zeng, T. Peng, J. Chromatogr. A 1108, 149–157 (2006)

    Article  CAS  PubMed  Google Scholar 

  27. T.-Y. Kim, K. Alhooshani, A. Kabir, D.P. Fries, A. Malik, J. Chromatogr. A 1047, 165–174 (2004)

    Article  CAS  PubMed  Google Scholar 

  28. S.S. Segro, Y. Cabezas, A. Malik, J. Chromatogr. A 1216, 4329–4338 (2009)

    Article  CAS  PubMed  Google Scholar 

  29. K. Farhadi, R. Tahmasebi, R. Maleki, Talanta 77, 1285–1289 (2009)

    Article  CAS  PubMed  Google Scholar 

  30. R. Maleki, K. Farhadi, R. Tahmasebi, Chromatographia 69, 775–778 (2009)

    Article  CAS  Google Scholar 

  31. R.L. Mason, R.F. Gunst, J.L. Hess, Statistical Design and Analysis of Experiments: with Applications to Engineering and Science (John Wiley & Sons, New York, 2003)

    Book  Google Scholar 

  32. M. Mousavi, E. Noroozian, M. Jalali-Heravi, Anal. Chim. Acta 581, 71–77 (2007)

    Article  CAS  PubMed  Google Scholar 

  33. D.C. Montgomery, G.C. Runger, N.F. Hubele, Engineering Statistics (John Wiley & Sons, New York, 2009)

    Google Scholar 

  34. M. Ahmadi, F. Vahabzadeh, B. Bonakdarpour, E. Mofarrah, M. Mehranian, J. Hazard. Mater. 123, 187–195 (2005)

    Article  CAS  PubMed  Google Scholar 

  35. M. Muthukumar, D. Sargunamani, N. Selvakumar, J.V. Rao, Dyes Pigm. 63, 127–134 (2004)

    Article  CAS  Google Scholar 

  36. Q.K. Beg, V. Sahai, R. Gupta, Process Biochem. 39, 203–209 (2003)

    Article  CAS  Google Scholar 

  37. L. Stobinski, B. Lesiak, L. Kövér, J. Tóth, S. Biniak, G. Trykowski, J. Judek, J. Alloys Compd. 501, 77–84 (2010)

    Article  CAS  Google Scholar 

  38. S.N. Deming, J.A. Palasota, J.M. Palasota, J. Chemom. 5, 181–192 (1991)

    Article  CAS  Google Scholar 

  39. E. Morgan, Chemometrics: Experimental Design (Wiley, London, 1995)

    Google Scholar 

  40. M.J. Nozal, J. Bernal, J. Jimenez, M.J. González, M. Higes, J. Chromatogr. A 954, 207–215 (2002)

    Article  CAS  PubMed  Google Scholar 

  41. M. Spichiger, R.C. Mühlbauer, R. Brenneisen, J. Chromatogr. B 799, 111–117 (2004)

    Article  CAS  Google Scholar 

  42. D.Y.-H. Yeung, T. Lee, G. Grant, M. Ma, E. Kwong, J. Pharm. Biomed. Anal. 30, 1469–1477 (2003)

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, Iran

    Mina Yarazavi, Ebrahim Noroozian & Mehdi Mousavi

Authors
  1. Mina Yarazavi
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  2. Ebrahim Noroozian
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  3. Mehdi Mousavi
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Correspondence to Mina Yarazavi.

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Yarazavi, M., Noroozian, E. & Mousavi, M. Headspace solid-phase microextraction of menthol using a sol–gel titania-based coating along with multiwalled carbon nanotubes on the surface of stainless steel fiber. J IRAN CHEM SOC 15, 2593–2603 (2018). https://doi.org/10.1007/s13738-018-1448-2

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  • DOI: https://doi.org/10.1007/s13738-018-1448-2

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