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Magnetic iron oxide nanoparticles/K2S: a simple and scale-up method for the direct synthesis of symmetrical disulfides from aryl halides

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Abstract

A simple, one-pot, efficient and novel protocol has been developed for direct synthesis of symmetrical organic disulfides by domino reaction of aryl halides and K2S in the presence of magnetic Fe3O4 nanoparticles as a readily available, highly efficient and recyclable catalyst. A variety of diaryl disulfides can be obtained in good-to-excellent yields up to 98%.

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Acknowledgements

We acknowledge the financial support of Ilam University Research Council.

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Authors and Affiliations

  1. Department of Chemistry, Basic of Sciences Faculty, Ilam University, PO Box 69315-516, Ilam, Iran

    Mohammad Soleiman-Beigi, Keivan Mohammadi & Fariba Mohammadi

Authors
  1. Mohammad Soleiman-Beigi
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  2. Keivan Mohammadi
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  3. Fariba Mohammadi
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Corresponding author

Correspondence to Mohammad Soleiman-Beigi.

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Soleiman-Beigi, M., Mohammadi, K. & Mohammadi, F. Magnetic iron oxide nanoparticles/K2S: a simple and scale-up method for the direct synthesis of symmetrical disulfides from aryl halides. J IRAN CHEM SOC 15, 1545–1550 (2018). https://doi.org/10.1007/s13738-018-1352-9

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