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Reactivity of cyclohexene using ordered mesoporous materials based on calcined CoFeAl hydrotalcite-supported CoMo catalysts

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Abstract

Co2+, Fe3+ and Al3+ tertiary hydrotalcite-type solids were synthesized, calcined and impregnated with Mo (15 wt% MoO3) and Co (3Mo:Co) in order to get different catalytic precursors: CoMo/CoFeAl. As-synthesized hydrotalcites and their catalytic precursors were characterized by different physicochemical techniques, such as: X-ray fluorescence, N2 adsorption–desorption isotherms (BET specific surface area, BJH pore volume and diameter), Fourier transform infrared spectroscopy, X-ray diffraction and temperature-programmed desorption of carbon dioxide. These CoMo/CoFeAl catalytic precursors were previously pre-sulfided with CS2 and tested in the cyclohexene hydrogenation reaction. Results indicated that these sulfide catalysts showed very low activity in comparison with the conventional CoMo/Al2O3 catalyst used as reference, possibly to their high basicity. These catalysts could have the advantage of retaining the octane number of gasoline, by low hydrogenation of olefins.

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References

  1. M. Toba, Y. Miki, T. Matsui, M. Harada, Y. Yoshimara, Appl. Catal. B Environ. 70, 542 (2007)

    Article  CAS  Google Scholar 

  2. L. Chao, Z. Zhiming, H. Yongli, C. Zhenmin, Y. Weikang, Chin. J. Chem. Eng. 22, 383 (2014)

    Article  Google Scholar 

  3. T.R. Ling, B.Z. Wan, H.P. Lin, C.Y. Mou, Ind. Eng. Chem. Res. 48, 1797 (2009)

    Article  CAS  Google Scholar 

  4. S. Garg, K. Soni, M. Kumar, T. Bhaskar, J.K. Gupta, K.S. Rama Rao, G. Murali Dhar, Catal. Today 198, 263 (2012)

    Article  CAS  Google Scholar 

  5. F. Cavani, F. Trifiro, A. Vacari, Catal. Today 11, 173 (1991)

    Article  CAS  Google Scholar 

  6. B.F. Sels, D.E. De Vos, P.A. Jacobs, Catal. Rev. 43, 443 (2001)

    Article  CAS  Google Scholar 

  7. P. Kustrowski, A. Rafalska-Lasopcha, D. Maida, D. Tomaszewska, R. Dziemba, Solid State Ion. 141–142, 237 (2001)

    Article  Google Scholar 

  8. M. Gabrovska, R. Edreva-Kardjieva, K. Tenchev, P. Tzvetkov, A. Spojakina, L. Petrov, Appl. Catal. A Gen. 399, 242 (2011)

    Article  CAS  Google Scholar 

  9. M. Jafari, S.A. Hassanzadeh-Tabrizi, Powder Technol. 266, 236 (2014)

    Article  CAS  Google Scholar 

  10. F.Y.A. El Kady, S.A. Shaban, A.O. Abo El Naga, Transit. Met. Chem. 36, 237 (2011)

    Article  Google Scholar 

  11. T.L. Coelho, Y.E. Licea, L.A. Palacio, A.C. Faro Jr., Catal. Today 250, 38 (2015)

    Article  CAS  Google Scholar 

  12. C.F. Linares, M. Vasquez, R. Castillo, P. Bretto, R. Solano, A. Rincon, Fuel Process. Technol. 132, 105 (2015)

    Article  CAS  Google Scholar 

  13. T. Wang, J. Li, Y. Su, C. Wang, Y. Gao, L. Chou, W. Yao, J. Energy Chem. 24, 432 (2015)

    Article  Google Scholar 

  14. P. Castaño, T.A. Zepeda, B. Pawelec, M. Makkee, J.L.G. Fierro, J. Catal. 267, 30 (2009)

    Article  Google Scholar 

  15. G.S. Pakirson, Surf. Sci. Rep. 71, 272 (2016)

    Article  Google Scholar 

  16. D. Mey, S. Brunet, C. Canaff, F. Maugé, C. Bouchy, F. Diehl, J. Catal. 227, 436 (2004)

    Article  CAS  Google Scholar 

  17. M. Badawi, L. Vivier, G. Pérot, D. Duprez, J. Mol. Catal. A Chem. 293, 53 (2008)

    Article  CAS  Google Scholar 

  18. A. Di Fronzo, C. Pirola, A. Comazzi, F. Galli, C.L. Bianchi, A. Di Michele, R. Vivani, M. Nocchetti, M. Bastianini, D.C. Boffato, Fuel 119, 62 (2014)

    Article  Google Scholar 

  19. N. Blanch-Raga, A.E. Palomares, J. Martinez-Triguero, M. Puche, G. Feller, P. Bosch, Appl. Catal. B Environ. 160–161, 129 (2014)

    Article  Google Scholar 

  20. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquérol, T. Siemieniewska, Pure Appl. Chem. 50–4, 603 (1985)

    Article  Google Scholar 

  21. S. Tripathy, D.S. Saini, D. Bhattacharya, J. Asian Ceram. Soc. 4, 149 (2016)

    Article  Google Scholar 

  22. H. Farag, H. Al-Megren, J. Colloid Interface Sci. 332, 425 (2009)

    Article  CAS  Google Scholar 

  23. P. Yuan, J. Liu, Y. Li, Y. Fan, G. Shi, H. Liu, X. Bao, Chem. Eng. Sci. 111, 381 (2014)

    Article  CAS  Google Scholar 

  24. Y. Villasana, F. Ruscio-Vanalesti, C. Pfaff, F. Mendez, M.A. Luis-Luis, J. Brito, Fuel 110, 259 (2013)

    Article  CAS  Google Scholar 

  25. J.C. Rodriguez, A.J. Marchi, A. Borgna, E. Romeo, A. Monzon, Stud. Surf. Sci. Catal. 139, 37 (2001)

    Article  CAS  Google Scholar 

  26. S.L. Amaya, G. Alonso-Nuñez, J. Cruz-Reyes, S. Fuentes, A. Echeverria, Fuel 139, 575 (2015)

    Article  CAS  Google Scholar 

  27. C. Bartholomew, Appl. Catal. A Gen. 212, 17 (2001)

    Article  CAS  Google Scholar 

  28. Y. Chen, L. Wang, Y. Zhang, T. Liu, X. Liu, Z. Jiang, C. Li, Appl. Catal. A Gen. 474, 69 (2014)

    Article  CAS  Google Scholar 

  29. B.R. Yeo, G.J.F. Pudge, K.G. Bugler, A.V. Rushby, S. Kondrat, J. Bartley, S. Golunski, S. Taylor, E. Gibson, P.P. Wells, C. Brookes, M. Bowker, G.J. Hutchings, Surf. Sci. 648, 163 (2016)

    Article  CAS  Google Scholar 

  30. L.Q. Qwabe, H.B. Friedrich, S. Singh, J. Mol. Catal. A Chem. 404–405, 167 (2015)

    Article  Google Scholar 

  31. T.A. Zepeda, B. Pawelec, J.L.G. Fierro, T. Halachev, J. Catal. 242, 254 (2006)

    Article  CAS  Google Scholar 

  32. K. Wang, J. Ma, Z. Yao, W. Zhang, S. Komarneni, Ceram. Int. 42, 15981 (2016)

    Article  CAS  Google Scholar 

  33. C. Barbosa, P.M. Dias, A.M. Ferreria, V.R.L. Constantino, Appl. Clay Sci. 28, 147 (2005)

    Article  CAS  Google Scholar 

  34. S. Zhao, H. Yi, X. Tang, D. Kang, H. Wang, K. Li, K. Duan, Appl. Clay Sci. 56, 84 (2004)

    Article  CAS  Google Scholar 

  35. H.S. Ahmed, M.F. Menoufy, Chem. Eng. Technol. 32, 873 (2009)

    Article  CAS  Google Scholar 

  36. T. Wang, J. Li, Y. Su, C. Wang, Y. Gao, L. Chou, W. Yao, J. Energy Chem. 24, 432 (2015)

    Article  Google Scholar 

  37. Z. Huang, W. Bensch, L. Kienle, S. Fuentes, G. Alonso, C. Ornelas, Catal. Lett. 122, 57 (2008)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are grateful to the Program of Cooperative of Post grade (PCP) France-Venezuela (No. Project: 2013000444) and National Funding of Science and Technology-Venezuela (PAE-FONACIT No. 2011000797) for funding the research carried out in this work.

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Authors and Affiliations

  1. Institute of Chemistry of Poitiers: Materials and Natural Resources (IC2MP), UMR, 7285 CNRS, University of Poitiers, Poitiers, France

    Edwin Oviedo, Philippe Ayrault, Sylvette Brunet & Carlos F. Linares

  2. Unit of Synthesis of Materials and Transition Metals (SIMMET), Experimental Faculty of Science and Technology, Department of Chemistry, University of Carabobo, Naguanagua, Venezuela

    Edwin Oviedo & Carlos F. Linares

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  1. Edwin Oviedo
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  2. Philippe Ayrault
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  3. Sylvette Brunet
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  4. Carlos F. Linares
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Correspondence to Carlos F. Linares.

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Oviedo, E., Ayrault, P., Brunet, S. et al. Reactivity of cyclohexene using ordered mesoporous materials based on calcined CoFeAl hydrotalcite-supported CoMo catalysts. J IRAN CHEM SOC 15, 1235–1242 (2018). https://doi.org/10.1007/s13738-018-1321-3

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  • DOI: https://doi.org/10.1007/s13738-018-1321-3

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