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Efficient synthesis of 3,4-dihydropyrano[3,2-c]chromenes catalyzed by Ni(II)-functionalized Li+-Montmorillonite in a one-pot fashion under solvent-free conditions

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Abstract

A family of 3,4-dihydropyrano[3,2-c]chromenes were synthesized from 4-hydroxycoumarin and malononitrile via a one-pot reaction under solvent-free conditions at 100 °C catalyzed by Ni@Imine-Li+-MMT. This methodology tolerates most of the substrates and has the merits of lower loading of the catalyst, absence of solvents, excellent yields and reusability of the catalyst. A reasonable mechanism is also proposed. This catalytic system can be reused for at least five times with a negligible loss of activity. The prepared catalyst was characterized by using FTIR, TGA, SEM, TEM, uv-DRS, EDX and XRD.

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Acknowledgements

Partial support of this study by the Research Council of University of Guilan is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, University of Guilan, University Campus 2, P. O. Box: 41335-1914, Rasht, Iran

    Hashem Azizi, Alireza Khorshidi & Khalil Tabatabaeian

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  1. Hashem Azizi
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  2. Alireza Khorshidi
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  3. Khalil Tabatabaeian
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Correspondence to Alireza Khorshidi.

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Azizi, H., Khorshidi, A. & Tabatabaeian, K. Efficient synthesis of 3,4-dihydropyrano[3,2-c]chromenes catalyzed by Ni(II)-functionalized Li+-Montmorillonite in a one-pot fashion under solvent-free conditions. J IRAN CHEM SOC 15, 1023–1032 (2018). https://doi.org/10.1007/s13738-018-1299-x

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