Abstract
Four Cu(II) and Co(II) complexes with N-containing heterocycles as ligands were reported firstly. In a simple method, the reaction of 2-benzenediacetonitrile and pyridine-2-carboxaldehyde 2-quinolylhydrazone with Cu(OAc)2·H2O afforded the copper(II) complexes I–II, and addition of 2-(2-pyridyl)-1-(2-thiazolylazo)-2-naphthol with CoCl2·6H2O and 2-(2-pyridyl)benzimidazole with Co(OAc)2·4H2O furnished two mononuclear cobalt complexes III–IV. The structures of complexes I–IV were determined by elemental analysis, X-ray diffraction, NMR spectroscopy and IR spectroscopy.
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C. Pettinari, A. Tabacaru, S. Galli, Coord. Chem. Rev. 307, 1 (2016)
F. Lazreg, F. Nahra, C.S.J. Cazin, Coord. Chem. Rev. 293–294, 48 (2015)
J.M. Hu, R. Guo, Y.G. Liu, G.H. Cui, Inorg. Chim. Acta 450, 418 (2016)
H. Kheira, P.F. Li, J.X. Xu, J. Mol. Catal. A 391, 168 (2014)
I. Banerjee, J. Marek, R. Herchel, M. Ali, Polyhedron 29, 1201 (2010)
H.A. Azab, L. Banci, M. Borsari, C. Luchinat, M. Sola, M.S. Viezzolit, Inorg. Chem. 31, 4649 (1992)
J. Zhang, J. Li, Y. Zang, Y. Shu, T. Zhang, L. Yang, P. Power, Z. Anorg, Allg. Chem. 636, 1147 (2010)
P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1999)
M. Mirzaei, H. Eshtiagh-Hosseini, Z. Karrabi, B. Notash, A. Bauzá, A. Frontera, M. Habibi, M. Ardalani, M. Shamsipur, J. Mol. Struct. 1079, 78 (2015)
B. Hu, C.Y. Su, D. Fenske, O. Fuhr, Inorg. Chim. Acta 419, 118 (2014)
M.K. Gangwar, A. Chkalita, P. Ghosh, Chem. Sci. 126, 1557 (2016)
C. Somnath, R. Subhasis, C. Soumi, B. Kishalay, R. Joan, M. Montserrat, K. Barindra, Polyhedron 89, 39 (2015)
L. Mei, W. Lei, J.-C. Zhang, Acta Cryst. E70, m27 (2014)
Z.-E. Lin, J. Zhang, S.-T. Zheng, G.-Y. Yang, Z. Anorg, Allg. Chem. 631, 155 (2005)
C.S. Hawes, C.M. Fitchett, P.E. Kruger, Supramol. Chem. 24, 553 (2012)
M.M. Omar, G.G. Mohamed, Spectrochim. Acta Part A 61, 929–936 (2005)
N.G. White, S. Brooker, Supermol. Chem. 25, 806 (2013)
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This work was supported by Hefei University of Technology.
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Luo, M., Guo, C.C., Li, Y.Z. et al. Syntheses and crystal structure of copper (II) and cobalt (II) complexes containing N-heterocyclic compounds. J IRAN CHEM SOC 15, 415–420 (2018). https://doi.org/10.1007/s13738-017-1242-6
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DOI: https://doi.org/10.1007/s13738-017-1242-6