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Journal of the Iranian Chemical Society

, Volume 14, Issue 5, pp 1005–1010 | Cite as

Ullmann homocoupling of aryl iodides catalyzed by gold nanoparticles stabilized on magnetic mesoporous silica

  • Shahnaz Rostamizadeh
  • Hamid Estiri
  • Mohammad Azad
Original Paper

Abstract

We demonstrated a convenient new procedure of the Ullmann homocoupling reaction for the synthesis of symmetrical biaryls via homocoupling of aryl iodides over a recyclable gold catalyst comprising Au nanoparticles supported on functional magnetic mesoporous silica (α-Fe2O3)-MCM-41-HS-Au. The catalyst was easily separated by an external magnet, and the recovered catalyst was reused in six successive reaction cycles without any significant loss of activity. So, using this catalyst is affordable. Also, the reaction time is much shorter than a few previously reported work.

Graphical Abstract

Keywords

Ullmann homocoupling reaction Symmetrical biaryls Magnetic nanocatalyst Gold nanoparticles 

Notes

Acknowledgements

We gratefully acknowledge the partial support of this work to K. N. Toosi University of Technology.

Supplementary material

13738_2017_1050_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2370 kb)

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Copyright information

© Iranian Chemical Society 2017

Authors and Affiliations

  • Shahnaz Rostamizadeh
    • 1
  • Hamid Estiri
    • 1
  • Mohammad Azad
    • 1
  1. 1.Department of ChemistryK. N. Toosi University of TechnologyTehranIran

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