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Alkanol-based supramolecular solvent microextraction of organophosphorus pesticides and their determination using high-performance liquid chromatography

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Abstract

A sensitive method for extraction and determination of three organophosphorus pesticides (chlorpyrifos, diazinon, phosalone) using a supramolecular solvent (SUPRAS) made of inverted hexagonal aggregates of alkanol and high-performance liquid chromatography with ultraviolet detection (HPLC–UV) was developed. The studied factors were alkanol amount, THF percentage (v/v), pH and vortex time. According to the full factorial design results, the effective parameters were alkanol amount, THF percentage (v/v) and pH. Then, a CCF was applied to obtain optimal conditions. The optimized conditions were obtained at 100 mg of alkanol, 5% of THF and pH 3.9. The limits of detection of pesticides were 0.5–1.3 ng/mL. The linearity was 1.6–500.0 ng/mL for different pesticides. Relative standard deviations for intra- and inter-day extraction of pesticides were 3.3–5.0 and 5.1–6.3, respectively, for five measurements. The method was also successfully applied for the determination of the pesticides in fruit juice and tap water samples.

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Authors and Affiliations

  1. Department of Chemistry, University of Mazandran, Niroo Havayii Boulevard, Babolsar, 47416-95447, Iran

    Moazameh Peyrovi & Mohammadreza Hadjmohammadi

Authors
  1. Moazameh Peyrovi
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  2. Mohammadreza Hadjmohammadi
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Correspondence to Mohammadreza Hadjmohammadi.

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Mohammadreza Hadjmohammadi declares that he has no conflict of interest. Moazameh Payrovi declares that she has no conflict of interest.

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Peyrovi, M., Hadjmohammadi, M. Alkanol-based supramolecular solvent microextraction of organophosphorus pesticides and their determination using high-performance liquid chromatography. J IRAN CHEM SOC 14, 995–1004 (2017). https://doi.org/10.1007/s13738-017-1049-5

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  • DOI: https://doi.org/10.1007/s13738-017-1049-5

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