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Pd(II) anchored to modified Fe3O4 nanoparticles as a new magnetically recoverable catalyst for epoxidation of styrene

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Abstract

A new support for Pd(II) was synthesized via the functionalization of Fe3O4 nanoparticles with N-(2-aminoethyl)acetamide. PdCl2 was anchored to the support for obtaining a heterogeneous magnetically recoverable catalyst for Pd(II). High yield and excellent selectivity were obtained for the green epoxidation of styrene derivatives using H2O2 as a green oxidant in H2O as the solvent at 100 °C. Also, the recovered catalyst is applicable for four times without significant decrease in yield.

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Acknowledgments

We gratefully acknowledge financial support from the Research Council of Urmia University.

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Authors and Affiliations

  1. Department of Nanochemistry, Nanotechnology Research Centre, Urmia University, G. C., P. O. Box 165-5715944931, Urmia, Iran

    Sajjad Keshipour & Nastaran Kalam Khalteh

Authors
  1. Sajjad Keshipour
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  2. Nastaran Kalam Khalteh
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Correspondence to Sajjad Keshipour.

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Keshipour, S., Khalteh, N.K. Pd(II) anchored to modified Fe3O4 nanoparticles as a new magnetically recoverable catalyst for epoxidation of styrene. J IRAN CHEM SOC 13, 1977–1982 (2016). https://doi.org/10.1007/s13738-016-0914-y

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  • DOI: https://doi.org/10.1007/s13738-016-0914-y

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