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Heterogeneous oxidation of alcohols with hydrogen peroxide catalyzed by polyoxometalate metal–organic framework

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Abstract

HSiW-MOF, PMo-MOF, HPMo-MOF and PW-MOF were synthesized and characterized by elemental analysis, UV–Vis, FT-IR, cyclic voltammetry and XRD. These compounds were used as catalyst for the selective oxidation of alcohols by hydrogen peroxide. Within them, PW-MOF showed a higher catalytic activity compared to other catalysts in a similar reaction condition. Therefore, PW-MOF catalyst system was successfully used for the selective oxidation of the benzylic, linear and secondary alcohols to the corresponding aldehydes and ketones. Also, allylic alcohols were converted to the corresponding aldehydes with high conversion and significant selectivity. Moreover, PW-MOF was stable to leaching, behaved as true heterogeneous catalysts, easily recovered by filtration, and reused four times with the preserve of the catalytic performance.

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Acknowledgments

The authors of this study acknowledge gratefully the support of the research by the Islamic Azad University of Shahrekord branch.

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Authors and Affiliations

  1. Medicinal Plants Research Center, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran

    Ali Kazemi Babahydari

  2. College of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, Tehran, Iran

    Reza Fareghi-Alamdari

  3. Chemical Nanoscience Laboratory, School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK

    Shahrbanou Moradpour Hafshejani

  4. Department of Chemistry, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran

    Shahrbanou Moradpour Hafshejani & Mostafa Riahi Farsani

  5. Department of Chemistry, University of Isfahan, Isfahan, 81746-73441, Iran

    Hadi Amiri Rudbari

Authors
  1. Ali Kazemi Babahydari
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  2. Reza Fareghi-Alamdari
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  3. Shahrbanou Moradpour Hafshejani
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  4. Hadi Amiri Rudbari
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  5. Mostafa Riahi Farsani
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Correspondence to Shahrbanou Moradpour Hafshejani or Mostafa Riahi Farsani.

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Babahydari, A.K., Fareghi-Alamdari, R., Hafshejani, S.M. et al. Heterogeneous oxidation of alcohols with hydrogen peroxide catalyzed by polyoxometalate metal–organic framework. J IRAN CHEM SOC 13, 1463–1470 (2016). https://doi.org/10.1007/s13738-016-0861-7

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  • DOI: https://doi.org/10.1007/s13738-016-0861-7

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