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Highly efficient and recyclable acetylation of phenols and alcohols by nickel zirconium phosphate under solvent-free conditions

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Abstract

Nickel zirconium phosphate nanoparticles have been used as an efficient catalyst for the acetylation of a wide range of alcohols and phenols with acetic anhydride in good to excellent yields under solvent‐free conditions. The steric and electronic properties of the different substrates had a significant influence on the reaction conditions required to achieve the acetylation. The catalyst used in the current study was characterized by inductively coupled plasma optical emission spectroscopy, X‐ray diffraction, N2 adsorption–desorption, scanning electron microscopy, and transmission electron microscopy. This nanocatalyst could also be recovered and reused at least six times without any discernible decrease in its catalytic activity.

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Acknowledgments

We gratefully acknowledge the funding support received for this project from the Isfahan University of Technology (IUT), IR Iran.

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Authors and Affiliations

  1. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, 84156, Isfahan, Islamic Republic of Iran

    Abdol Reza Hajipour, Hirbod Karimi & Afshin Kohi

  2. Department of Neuroscience, University of Wisconsin, Medical School, Madison, WI, 53706-1532, USA

    Abdol Reza Hajipour

  3. Young Researchers and Elite Club, Shahreza Branch, Islamic Azad University, Shahreza, Iran

    Hirbod Karimi

Authors
  1. Abdol Reza Hajipour
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Correspondence to Abdol Reza Hajipour.

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Hajipour, A.R., Karimi, H. & Kohi, A. Highly efficient and recyclable acetylation of phenols and alcohols by nickel zirconium phosphate under solvent-free conditions. J IRAN CHEM SOC 13, 55–64 (2016). https://doi.org/10.1007/s13738-015-0711-z

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  • DOI: https://doi.org/10.1007/s13738-015-0711-z

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