Efficient synthesis of 4H-pyran derivatives using a polymeric catalyst based on PVP

Journal of the Iranian Chemical Society volume 12, pages2105–2113(2015)Cite this article

Abstract

A one-pot efficient method for the synthesis of 4H-pyran derivatives has been developed through a multi-component reaction of aldehydes, malononitrile, and 1,3-cyclic diketones using poly(vinylpyrrolidonium) hydrogen sulfate ([PVPH]HSO4) as a heterogeneous and reusable catalyst. The synthesized polymeric catalyst has fully been characterized by Fourier transform infrared spectra, X-ray diffraction, scanning electron microscopy, thermal gravimetric analysis, Hammett acidity (H0), and pH analysis, which expose of the polymeric catalyst. This procedure has the advantages of operational simplicity, mild conditions, easy work-up, short reaction times, high yields of the products, and reusability of the catalyst.

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Acknowledgments

The authors are Grateful to the Research Council of the University of Guilan for partial support of this study.

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Affiliations

  1. Department of Chemistry, College of Science, University of Guilan, 41335, Rasht, Islamic Republic of Iran

    Farhad Shirini, Masoumeh Abedini, Susan Zarrabzadeh & Mohadeseh Seddighi

Authors
  1. Farhad Shirini
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  2. Masoumeh Abedini
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  3. Susan Zarrabzadeh
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  4. Mohadeseh Seddighi
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Correspondence to Farhad Shirini.

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Shirini, F., Abedini, M., Zarrabzadeh, S. et al. Efficient synthesis of 4H-pyran derivatives using a polymeric catalyst based on PVP. J IRAN CHEM SOC 12, 2105–2113 (2015). https://doi.org/10.1007/s13738-015-0687-8

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Keywords

  • Poly(vinylpyrrolidone)
  • Poly(vinylpyrrolidonium) hydrogen sulfate ([PVPH]HSO4)
  • 2-Amino-4H-pyran derivatives
  • Multi-component reactions