Skip to main content

Synthesis of sodium dodecyl sulfate-supported nanocomposite cation exchanger: removal and recovery of Cu2+ from synthetic, pharmaceutical and alloy samples

Journal of the Iranian Chemical Society volume 12, pages 1677–1686 (2015)Cite this article

Abstract

A new surfactant-based nanocomposite cation exchanger, sodium dodecyl sulfate–Th(IV) tungstate (SDS–TT) was prepared by the sol–gel method. The SDS–TT was characterized by FTIR, XRD, TGA, SEM, EDS and TEM. The distribution studies for various metal ions on SDS–TT were performed in different acidic mediums. On the basis of distribution coefficient values, SDS–TT was found to be selective for Cu2+ metal ion. SDS–TT was successfully used for the quantitative separation of Cu2+ from the synthetic mixture, pharmaceutical formulation and brass sample. The regeneration studies were performed which showed a decrease in the recovery of Cu2+ from 88 to 70 % after seven consecutive cycles.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

References

  1. J. Keary, A.D. Mortimer, in Ion Exchange Developments and Applications, vol. 35, ed. by J.A. Greig (The Royal Society of Chemistry, Cambridge, UK, 1996), pp. 35–42

  2. J. Lee, D.F. Hussey, G.L. Foutch, in Ion Exchange at the Millennium, vol. 61 ed. by J.A. Greig (Imperial College Press, London, 2000) pp. 61–68

  3. A. Clearfield, Inorganic Ion Exchange Materials (CRC Press, Boca Raton, 1982)

    Google Scholar 

  4. Mu. Naushad, Chem. Eng. J. 235, 100 (2014)

    Article  CAS  Google Scholar 

  5. Z.A. ALOthman, Inamuddin, Mu. Naushad, Chem. Eng. J. 171, 456 (2011)

    Article  CAS  Google Scholar 

  6. S.S.M. Hassan, S.A. Marei, I.H. Badr, H.A. Arida, Anal. Chim. Acta 427, 21 (2001)

    Article  CAS  Google Scholar 

  7. S.A. Nabi, S.A. Ganai, M. Naushad, Ads. Sci. Tech. 26, 463 (2009)

    Article  Google Scholar 

  8. G. Sharma, D. Pathania, Mu. Naushad, N.C. Kothiyal. Chem. Eng. J. 251, 413 (2014)

    Article  CAS  Google Scholar 

  9. Z.A. ALOthman, Inamuddin, Mu. Naushad, Chem. Eng. J. 166, 639 (2011)

    Article  CAS  Google Scholar 

  10. Z.A. ALOthman, Inamuddin, Mu. Naushad, Chem. Eng. J. 169, 38 (2011)

    Article  CAS  Google Scholar 

  11. S.A. Nabi, Mu. Naushad, Inamuddin, J. Hazard Mater. 42, 404 (2007)

    Article  Google Scholar 

  12. S.A. Nabi, Mu. Naushad, Chem. Eng. J. 158, 100 (2010)

    Article  CAS  Google Scholar 

  13. O.M. Vatutsina, V.S. Soldatov, V.I. Sokolova, J. Johann, M. Bissen, A. Weisswnbacher, React. Funct. Polym. 67, 184 (2007)

    Article  CAS  Google Scholar 

  14. L. Wang, L. Yang, Y. Li, Y. Zhang, X. Ma, Z. Ye, Chem. Eng. J. 163, 364 (2010)

    Article  CAS  Google Scholar 

  15. L.C. Lin, R.S. Juang, Chem. Eng. J. 132, 205 (2007)

    Article  CAS  Google Scholar 

  16. J. Peric, M. Trgo, N.V. Medvidovic, Water Res. 38, 1893 (2004)

    Article  CAS  Google Scholar 

  17. Mu. Naushad, Inamuddin, T.A. Rangreez, Z.A. ALOthman, J. Electroanal. Chem. 713, 125 (2014)

    Article  CAS  Google Scholar 

  18. Z. Ujang, G.K. Anderson, Water Sci. Technol. 38, 521 (1998)

    Article  CAS  Google Scholar 

  19. A. Dabrowski, Z. Hubicki, P. Podkoscielny, E. Robens, Chemosphere 56, 91 (2004)

    Article  CAS  Google Scholar 

  20. M.R. Awual, M.M. Hasan, A. Shahat, M. Naushad, H. Shiwaku, T. Yaita, Chem. Eng. J. 265, 210 (2015)

    Article  CAS  Google Scholar 

  21. Z.A. ALOthman, M.M. Alam, Mu. Naushad, J. Ind. Eng. Chem. 19, 956 (2013)

    Article  CAS  Google Scholar 

  22. K.G. Varshney, M.Z.A. Rafiquee, A. Somya, M. Drabik, Indian J. Chem. 45A, 1856 (2006)

    CAS  Google Scholar 

  23. K.G. Varshney, M.Z.A. Rafiquee, A. Somya, Coll. Surf A Physiochem. Eng. Asp. 301, 224 (2007)

    Article  CAS  Google Scholar 

  24. N. Iqbal, M. Mobin, M.Z.A. Rafiquee, Chem. Eng. J. 169, 43 (2011)

    Article  CAS  Google Scholar 

  25. K.M. El-Azony, A.M. Ismail, A.A. El-Mohty, J. Radioanal. Nucl. Chem. 289, 381 (2011)

    Article  CAS  Google Scholar 

  26. A. Mohammad, Inamuddin, A. Amin, J. Therm. Anal. Calorim. 107, 127 (2012)

    Article  CAS  Google Scholar 

  27. L.L. Schramm, E.N. Stasiuk, D.G. Marangoni, Annu. Rep. Prog. Chem. Sect. C Phys. Chem. 99, 3 (2003)

    Article  CAS  Google Scholar 

  28. S. Tagashira, S. Kimoto, K. Nozaki, Y. Murakami, Anal. Sci. 25, 723 (2009)

    Article  CAS  Google Scholar 

  29. N. Li, N. Bai, Sep. Purif. Technol. 42, 237 (2005)

    Article  CAS  Google Scholar 

  30. M.M. Rao, A. Ramesh, G.P.C. Rao, K. Seshaiah, J. Hazard Mater. B 129, 123 (2006)

    Article  Google Scholar 

  31. S.A. Nabi, S. Usmani, N. Rahman, Ann. Chim. Sci. Fr. 21, 521 (1996)

    CAS  Google Scholar 

  32. W. Kossel, Ann. Phys. 49, 229 (1916)

    Article  CAS  Google Scholar 

  33. L. Paulling, J. Am. Chem. Soc. 51, 1010 (1929)

    Article  Google Scholar 

  34. F.A. Miller, C.H. Wilkins, Anal. Chem. 24, 1253 (1952)

    Article  CAS  Google Scholar 

  35. S.A. Nabi, M. Naushad, Coll Surf. A Phys. Eng. Asp. 293, 175 (2007)

    Article  CAS  Google Scholar 

  36. C. Dual, Inorganic thermogravimetric analysis (Elsevier, Amsterdam, 1963)

    Google Scholar 

Download references

Acknowledgments

The authors extend their appreciation to the Deanship of Scientific Research at King Saud University for funding the work through the research group project No. RGP-VPP-130.

Author information

Authors and Affiliations

  1. Department of Chemistry, College of Science, Bld#5, King Saud University, Riyadh, Kingdom of Saudi Arabia

    Mu. Naushad, Zeid Abdullah ALOthman, Mohammad Mezbaul Alam & Gaber E. Eldesoky

  2. Actinide Coordination Chemistry Group, Quantum Beam Science Centre, Japan Atomic Energy Agency (SPring-8), Hyogo, 679-5148, Japan

    Md. Rabiul Awual

  3. Department of Chemistry, Purushottam Institute of Engineering and Technology, Rourkela, 770034, Orissa, India

    Mahamudur Islam

Authors
  1. Mu. Naushad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zeid Abdullah ALOthman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mohammad Mezbaul Alam
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Md. Rabiul Awual
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Gaber E. Eldesoky
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Mahamudur Islam
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mu. Naushad.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Naushad, M., ALOthman, Z.A., Alam, M.M. et al. Synthesis of sodium dodecyl sulfate-supported nanocomposite cation exchanger: removal and recovery of Cu2+ from synthetic, pharmaceutical and alloy samples. J IRAN CHEM SOC 12, 1677–1686 (2015). https://doi.org/10.1007/s13738-015-0642-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-015-0642-8

Keywords

  • Sodium dodecyl sulfate
  • Nanocomposite cation exchanger
  • Brass alloy
  • Pharmaceutical formulation
  • Environmental remediation