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Two Cobalt(II) Supramolecular architectures based on 1,5-naphthalenedisulfonate: Syntheses, Structures and Photoluminescence

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Abstract

Two new supramolecular architectures, [Co(dafo)2(H2O)2]·1,5-nds 1 and [Co(phen)2(H2O)(1,5-nds)] 2 (1,5-nds = 1,5-naphthalenedisulfonate; dafo = 4,5-diazafluoren-9-one; phen = 1,10-phenanthroline), were synthesized and characterized by element analysis, IR, XRD, TG-DSC and single-crystal X-ray diffraction. Compounds 1 and 2 exhibit 2D and 3D supramolecular structures via O–H∙∙∙O hydrogen bond interactions and π–π interactions, respectively. The compound 1 represents the first example of the Co(II)-1,5-nds-dafo system, in which the [Co(dafo)2(H2O)2]2+ chains and the counter anions 1,5-nds appear alternately. In addition, luminescent properties of 1 and 2 were discussed. The emission band at 422 nm of 1 is attributed to intraligand transitions. 2 shows two emission bands centered at 420 nm which may be originated from the intraligand emission from the phen ligand and at 459 nm assigned to the combined interaction of intraligand π* → π transitions of the phen ligand and ligand-to-metal charge-transfer (LMCT) transitions (λ ex = 254 nm).

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Acknowledgments

This work was supported by the Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials (No. JSKC11098).

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Authors and Affiliations

  1. Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huaian, 223300, People’s Republic of China

    Cao Li, Hui-Chao Zhao, Yu-Lan Zhu, Yu-He Kan & Kui-Rong Ma

  2. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Cao Li, Hui-Chao Zhao, Yu-Lan Zhu & Xiu-Mei Pan

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  1. Cao Li
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  2. Hui-Chao Zhao
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  3. Yu-Lan Zhu
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  4. Yu-He Kan
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Correspondence to Yu-Lan Zhu.

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Li, C., Zhao, HC., Zhu, YL. et al. Two Cobalt(II) Supramolecular architectures based on 1,5-naphthalenedisulfonate: Syntheses, Structures and Photoluminescence. J IRAN CHEM SOC 12, 1227–1233 (2015). https://doi.org/10.1007/s13738-015-0586-z

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