Journal of the Iranian Chemical Society

, Volume 11, Issue 4, pp 985–991 | Cite as

Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N2O2 Schiff base ligands

  • Soraia Meghdadi
  • Mehdi Amirnasr
  • Maryam Bagheri
  • Fatemeh Ahmadi Najafabadi
  • Kurt Mereiter
  • Kurt Joß Schenk
  • Fahimeh Ziaee
Original Paper

Abstract

Nickel(II) and copper(II) complexes of two unsymmetrical tetradentate Schiff base ligands [Ni(Me-salabza)] (1), [Cu(Me-salabza)] (2) and [Ni(salabza)] (3), {H2salabza = N,N′-bis[(salicylidene)-2-aminobenzylamine] and H2Me-salabza = N,N′-bis[(methylsalicylidene)-2-aminobenzylamine]}, have been synthesized and characterized by elemental analysis and spectroscopic methods. The crystal structures of 2 and 3 complexes have been determined by single crystal X-ray diffraction. Both copper(II) and nickel(II) ions adopt a distorted square planar geometry in [Cu(Me-salabza)] and [Ni(salabza)] complexes. The cyclic voltammetric studies of these complexes in dichloromethane indicate the electronic effects of the methyl groups on redox potential.

Keywords

Unsymmetrical N2O2 Schiff base Ni(II) and Cu(II) complexes Crystal structure Cyclic voltammetry 

Supplementary material

13738_2013_365_MOESM1_ESM.docx (1.4 mb)
Supplementary material 1 Crystallographic data for 2 and 3 have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications, CCDC reference numbers 876390 and 876389. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: (+44) 1223-336-033; or Email: deposit@ccdc.cam.ac.uk)

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Copyright information

© Iranian Chemical Society 2013

Authors and Affiliations

  • Soraia Meghdadi
    • 1
  • Mehdi Amirnasr
    • 1
  • Maryam Bagheri
    • 1
  • Fatemeh Ahmadi Najafabadi
    • 1
  • Kurt Mereiter
    • 2
  • Kurt Joß Schenk
    • 3
  • Fahimeh Ziaee
    • 1
  1. 1.Department of ChemistryIsfahan University of TechnologyIsfahanIran
  2. 2.Faculty of ChemistryVienna University of TechnologyViennaAustria
  3. 3.Laboratoire de CristallographieÉcole Polytechnique Fédérale de LausanneLausanneSwitzerland

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