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A three-dimensional porous and magnetic framework constructed from copper salt and 5-Methyltetrazole: [Cu8(Metz)9](OH)·xH2O

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Abstract

A new compound of [Cu8(Metz)9](OH)·xH2O (x≈3) (1) (Metz = 5-Methyltetrazole) has been prepared and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal is of hexagonal, space group P63/m with a = b = 13.988(1) Å, c = 16.309(2) Å, α = β = 90°, γ = 120°, V = 2 763.5 (4) Å3, Mr = 1327.13, D c = 1.595 g cm−3, Z = 2, F(000) = 1 316, μ = 3.076 mm−1, the final R = 0.0494 and wR = 0.1532 for 1,731 observed reflections (I > 2σ(I)). In this compound, the [(CuII)2(CuI)6(Metz)9]+ cationic clusters are connected together through CuI cations and Metz ligands and result in a three-dimensional framework. Remarkable, three-dimensional intersecting channels exist in it. The variable temperature magnetic investigations indicate that 1 exhibits typical antiferromagnetic behaviors. N2 gas adsorption measurements at 77 K showed that compound 1 possesses permanent porosities.

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Acknowledgments

This work is supported by the NSFC (21361012), the key project of the Natural Science Foundation of Jiangxi Province (20133ACB20010), the Natural Science Foundation of Jiangxi Province (20114BAB203027), Jinggangshan University (JZB110037), and the Project of Graduates’ Innovative of Jiangxi Province.

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Authors and Affiliations

  1. Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an, 343009, Jiangxi, People’s Republic of China

    Dong-Sheng Liu, Ji-Wei Wang, Li-Ming Zhang, Wen-Tong Chen, Jian-Gen Huang & Yan Sui

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  1. Dong-Sheng Liu
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  2. Ji-Wei Wang
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  3. Li-Ming Zhang
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  4. Wen-Tong Chen
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  6. Yan Sui
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Correspondence to Dong-Sheng Liu or Yan Sui.

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Supplementary material: Additional figures, PXRD patterns, IR spectra, TGA and partly magnetic plots, as well as crystal data and structure refinement parameters of complex 1. Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Centre, CCDC No. 943370‏. Copies of this information may be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge, CBZ 1EZ, UK (Fax: +44-1223-336033; email: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk).

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Liu, DS., Wang, JW., Zhang, LM. et al. A three-dimensional porous and magnetic framework constructed from copper salt and 5-Methyltetrazole: [Cu8(Metz)9](OH)·xH2O. J IRAN CHEM SOC 11, 847–852 (2014). https://doi.org/10.1007/s13738-013-0356-8

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  • DOI: https://doi.org/10.1007/s13738-013-0356-8

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