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Synthesis and characterization of Ti–Al/Al2O3 nanocomposite and its application as heterogeneous catalyst in the green synthesis of 2-amino-4H-chromens

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Abstract

Ti–Al/Al2O3 nanocomposite catalyzed green and efficient synthesis of 2-amino-4H-chromen-5(6H)-ones via three-component condensation reaction of different aromatic aldehyde, malononitrile and dimedone in aqueous media. The reaction was preceded to completion within 30–90 min in 80–96 % yield at ambient temperature. The Ti–Al/Al2O3 nanocomposite was prepared by milling for 4 h and combustion synthesis at 800 °C in the air atmosphere. The catalyst was well characterized by X-ray diffraction, laser particle sizer and transmission electron microscopy. Its average particle size was found to be around 27 nm. Reusability of the system was assured carrying out multiple runs using the recycled catalyst.

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Acknowledgments

The authors thank the Graduate University of Advanced Technology, for partial financial support of this investigation.

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Authors and Affiliations

  1. Institute of Material Sciences and Engineering, Graduate University of Advanced Technology, 76315-117, Kerman, Iran

    Elaheh Mosaddegh, Asadollah Hassankhani & Mostafa Alizadeh

  2. Department of Chemistry, Faculty of Science, Islamic Azad University, Kerman Branch, Kerman, Iran

    Farzaneh Poshtiban & Dadkhoda Ghazanfari

Authors
  1. Elaheh Mosaddegh
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  2. Farzaneh Poshtiban
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  3. Asadollah Hassankhani
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  4. Mostafa Alizadeh
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  5. Dadkhoda Ghazanfari
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Correspondence to Elaheh Mosaddegh.

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Mosaddegh, E., Poshtiban, F., Hassankhani, A. et al. Synthesis and characterization of Ti–Al/Al2O3 nanocomposite and its application as heterogeneous catalyst in the green synthesis of 2-amino-4H-chromens. J IRAN CHEM SOC 11, 639–643 (2014). https://doi.org/10.1007/s13738-013-0334-1

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