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Preparation of Cu (II) imprinted polymer electrode and its application for potentiometric and voltammetric determination of Cu (II)

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Abstract

The Cu (II) imprinted polymer glassy carbon electrode (GCE/Cu-IP) was prepared by electropolymerization of pyrrole at GCE in the presence of methyl red as a dopant and then imprinting by Cu2+ ions. This electrode was applied for potentiometric and voltammetric detection of Cu2+ ion. The potentiometric response of the electrode was linear within the Cu2+ concentration range of 3.9 × 10−6 to 5.0 × 10−2 M with a near-Nernstian slope of 29.0 mV decade−1 and a detection limit of 5.0 × 10−7 M. The electrode was also used for preconcentration anodic stripping voltammetry and results exhibited that peak currents for the incorporated copper species were dependent on the metal ion concentration in the range of 1.0 × 10−8 to 1.0 × 10−3 M and detection limit was 6.5 × 10−9 M. Also the selectivity of the prepared electrode was investigated. The imprinted polymer electrode was used for the successful assay of copper in two standard reference material samples.

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References

  1. M.J. Yonone-Lioy, P.J. Lioy, J Expo Sci Environ Epidemiol 16, 397 (2006)

    Article  Google Scholar 

  2. E. Merian, Metals and their compounds in the environment (VCH, Weinheim, 1991)

    Google Scholar 

  3. G.E. Lagos, L.C. Maggi, D. Peters, F. Reveco, Sci Total Environ 239, 49 (1999)

    Article  CAS  Google Scholar 

  4. L.A. Escudero, S. Cerutti, R.A. Olsina, J.A. Salonia, J.A. Gasquez, J Hazard Mater 183, 218 (2010)

    Article  CAS  Google Scholar 

  5. I. Durukan, C.A. Sahin, S. Bektas, Microchem J 98, 215 (2011)

    Article  CAS  Google Scholar 

  6. M.T. Fernandez-Arguelles, W.J. Jin, J.M. Costa-Fernandez, R. Pereiro, A. Sanz-Medel, Anal Chim Acta 549, 20 (2005)

    Article  Google Scholar 

  7. S.E. Ghazy, R.M. El-Shazly, M.S. El-Shahawi, G.A.A. Al-Hazmi, A.A. El-Asmy, J Iran Chem Soc 3, 140 (2006)

    Article  CAS  Google Scholar 

  8. M. Mazloum-Ardakani, M.A. Sheikh-Mohseni, M. Abdollahi-Alibeik, A. Benvidi, Analyst 137, 1950 (2012)

    Article  CAS  Google Scholar 

  9. M. Mazloum-Ardakani, H. Beitollahi, M.A. Sheikh-Mohseni, H. Naeimi, J Iran Chem Soc 9, 27 (2012)

    Article  CAS  Google Scholar 

  10. B. Habibi, H. Phezhhan, M.H. Pournaghi-Azar, J Iran Chem Soc 7, S103 (2010)

    Article  CAS  Google Scholar 

  11. M. Mazloum-Ardakani, M.A. Sheikh-Mohseni, B.B.F. Mirjalili, L. Zamani, J Electroanal Chem 686, 12 (2012)

    Article  CAS  Google Scholar 

  12. A.R. Zanganeh, M.K. Amini, Sens Actuators B 135, 358 (2008)

    Article  CAS  Google Scholar 

  13. B. Adhikari, S. Majumdar, Prog Polym Sci 29, 699 (2004)

    Article  CAS  Google Scholar 

  14. Y. Osada, D.E. Rossi, Polymer sensors and actuators (Springer, Berlin, 2000)

    Book  Google Scholar 

  15. S. Nambiar, J.T.W. Yeow, Biosens Bioelectron 26, 1825 (2011)

    Article  CAS  Google Scholar 

  16. M. Mazloum-Ardakani, M.A. Sheikh-Mohseni, A. Benvidi, Electroanalysis 23, 2822 (2011)

    Article  CAS  Google Scholar 

  17. M.A. Rahman, M.S. Won, Y.B. Shim, Anal Chem 75, 1123 (2003)

    Article  CAS  Google Scholar 

  18. S. Zhao, G. Zhang, L. Fu, L. Liu, X. Fang, F. Yang, Electroanalysis 23, 355 (2011)

    Article  CAS  Google Scholar 

  19. A. Ramanavicius, A. Ramanaviciene, A. Malinauskas, Electrochim Acta 51, 6025 (2006)

    Article  CAS  Google Scholar 

  20. A. Ramanaviciene, A. Ramanavicius, Crit Rev Anal Chem 32, 245 (2002)

    Article  CAS  Google Scholar 

  21. D. Kriz, O. Ramstrom, K. Mosbach, Anal Chem 69, 345A (1997)

    Article  CAS  Google Scholar 

  22. K. Haupt, Analyst 126, 746 (2001)

    Article  Google Scholar 

  23. M.R. Nateghi, A. Bagheri, A. Massoumi, M.H. Kazemeini, Synth Metals 96, 209 (1998)

    Article  CAS  Google Scholar 

  24. K.K. Shiu, O.-Y. Chan, J Electroanal Chem 388, 45 (1995)

    Article  Google Scholar 

  25. A. Ersoz, V.G. Gavalas, L.G. Bachas, Anal Bioanal Chem 372, 786 (2002)

    Article  Google Scholar 

  26. M. Mazloum-Ardakani, M.K. Amini, M. Dehghan, E. Kordi, M.A. Sheikh-Mohseni, J Serb Chem Soc 77, 899 (2012)

    Article  CAS  Google Scholar 

  27. Y. Umezawa, K. Umezawa, H. Sato, Pure Appl Chem 67, 507 (1995)

    Article  Google Scholar 

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Acknowledgments

The authors would like to thank Payam Noor University Research Council (center of Ardakan), Yazd University Research Council, IUT Research Council and Excellence in Sensors for financial support of this research.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Yazd University, Yazd, Islamic Republic of Iran

    Mohammad Mazloum-Ardakani

  2. Department of Chemistry, University of Isfahan, Isfahan, Islamic Republic of Iran

    Mohammad Kazem Amini

  3. Department of Chemistry, Ardakan Center, Payam Noor University, Ardakan, Islamic Republic of Iran

    Marzieh Dehghan & Elham Kordi

  4. Faculty of Education Center of Miandoab, Urmia University, Urmia, Islamic Republic of Iran

    Mohammad Ali Sheikh-Mohseni

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  1. Mohammad Mazloum-Ardakani
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  2. Mohammad Kazem Amini
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  5. Mohammad Ali Sheikh-Mohseni
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Correspondence to Mohammad Mazloum-Ardakani.

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Mazloum-Ardakani, M., Amini, M.K., Dehghan, M. et al. Preparation of Cu (II) imprinted polymer electrode and its application for potentiometric and voltammetric determination of Cu (II). J IRAN CHEM SOC 11, 257–262 (2014). https://doi.org/10.1007/s13738-013-0295-4

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  • DOI: https://doi.org/10.1007/s13738-013-0295-4

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