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Nano TiO2-supported Preyssler-type heteropolyacid (nanoTiO2/H14[NaP5W30O110]): an efficient and re-usable catalyst for the one-pot synthesis of N-acetyl-2-aryl-1,2-dihydro-(4H)-3,1-benzoxazin-4-ones

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Abstract

An efficient procedure has been developed for one-pot synthesis of N-acyle-2-aryl-1,2-dihydro-(4H)-3,1-benzoxazin-4-ones in the presence of Preyssler-type heteropolyacid acid modified nano-sized TiO2 as catalyst. The reactions proceed smoothly at 25 °C to afford the products in high yields. The catalyst is easily separated and re-used for the next successive reactions without significant loss of its activity.

Graphical Abstract

An efficient procedure has been developed for one-pot synthesis of N-acyle-2-aryl-1,2-dihydro-(4H)-3,1-benzoxazin-4-ones in the presence of Preyssler-type heteropolyacid acid modified nano-sized TiO2 as catalyst. The reactions proceed smoothly at 25 °C to afford the products in high yields. The catalyst is easily separated and re-used for the next successive reactions without significant loss of its activity.

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Acknowledgments

The authors wish to thank the Research Council of Bu-Ali Sina University and also the Ministry of Science, Research and Technology of Islamic Republic of Iran for financial support to carry out this research.

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Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, Zip Code 65178, Hamedan, Iran

    Davood Azarifar, Seyed-Mola Khatami, Mohammad Ali Zolfigol & Davood Sheikh

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  1. Davood Azarifar
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  2. Seyed-Mola Khatami
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  3. Mohammad Ali Zolfigol
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  4. Davood Sheikh
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Correspondence to Davood Azarifar.

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Azarifar, D., Khatami, SM., Zolfigol, M.A. et al. Nano TiO2-supported Preyssler-type heteropolyacid (nanoTiO2/H14[NaP5W30O110]): an efficient and re-usable catalyst for the one-pot synthesis of N-acetyl-2-aryl-1,2-dihydro-(4H)-3,1-benzoxazin-4-ones. J IRAN CHEM SOC 10, 1039–1046 (2013). https://doi.org/10.1007/s13738-013-0242-4

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