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Comparative study of polyimides containing different flexible linkages

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Abstract

Two series of polyimides were synthesized based on different aromatic dianhydrides containing various flexible linkages and two aromatic diamines containing ether and nitrile groups. The structure of the polymers was confirmed by FTIR and 1H NMR spectroscopy. The correlation between some physical properties, such as solubility, thermal stability and glass transition temperature, and conformational rigidity parameters, such as Kuhn segment, characteristic ratio and rigidity parameter p, was studied.

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Acknowledgments

The research leading to these results has received funding from the European Union’s Seventh Framework Program (FP7/2007–2013) under grant agreement no. 264115, STREAM.

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda, 41A, 700487, Iasi, Romania

    Irina Bacosca, Elena Hamciuc & Maria Bruma

  2. Nesmeyanov Institute of Element-Organic Compounds, Vavilov Street 28, Moscow, 119991, Russia

    Inga A. Ronova

Authors
  1. Irina Bacosca
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  2. Elena Hamciuc
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  3. Maria Bruma
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  4. Inga A. Ronova
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Correspondence to Irina Bacosca.

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Bacosca, I., Hamciuc, E., Bruma, M. et al. Comparative study of polyimides containing different flexible linkages. J IRAN CHEM SOC 9, 901–910 (2012). https://doi.org/10.1007/s13738-012-0107-2

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  • DOI: https://doi.org/10.1007/s13738-012-0107-2

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