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Poly(4-vinylpyridinium tribromide) as metal-free and recoverable oxidizing agent for the selective oxidation of alcohols, and oxidative deprotection of trimethylsily ethers

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Abstract

Poly(4-vinylpyridinium tribromide) was found to be an efficient oxidizing polymer for the chemoselective oxidation of a wide range of alcohols into aldehydes and ketones. In addition it was used for the oxidative deprotection of trimethylsilyl ethers into alcohols or carbonyl compounds depending on the structure of trimethylsilyl ether.

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Acknowledgments

The authors acknowledge Bu-Ali Sina University Research Council (grant number 32-1716), Center of Excellence in Development of Chemical Methods (CEDCM), National Foundation of Elites (BMN), and Ilam University, Ilam, Iran for financial support of this work.

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Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, P.O. Box 6517838683, Hamadan, Iran

    Mohammad Ali Zolfigol & Maryam Hajjami

  2. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Arash Ghorbani-Choghamarani

Authors
  1. Mohammad Ali Zolfigol
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  2. Maryam Hajjami
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  3. Arash Ghorbani-Choghamarani
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Corresponding authors

Correspondence to Mohammad Ali Zolfigol or Arash Ghorbani-Choghamarani.

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Zolfigol, M.A., Hajjami, M. & Ghorbani-Choghamarani, A. Poly(4-vinylpyridinium tribromide) as metal-free and recoverable oxidizing agent for the selective oxidation of alcohols, and oxidative deprotection of trimethylsily ethers. J IRAN CHEM SOC 9, 13–18 (2012). https://doi.org/10.1007/s13738-011-0011-1

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  • DOI: https://doi.org/10.1007/s13738-011-0011-1

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