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Iranian Polymer Journal

, Volume 27, Issue 4, pp 253–261 | Cite as

A low-cost and environment friendly chitosan/aluminum hydroxide bead adsorbent for fluoride removal from aqueous solutions

  • Haifeng Hu
  • Liu Yang
  • Zhen Lin
  • Yulai Zhao
  • Xiancai Jiang
  • Linxi Hou
Original Research

Abstract

A novel low-cost adsorbent named chitosan/Al(OH)3·(CS/Al(OH)3) bead was successfully prepared by employing AlCl3·6H2O aqueous solution as the solvent for CS. The CS/Al(OH)3 beads were used for fluoride removal from water. The beads were synthesized using the chitosan and aluminum chloride with the mass ratio of 2:1 as the precursor and in situ generation of aluminum hydroxide sorbents in sodium hydroxide solution. Then, the beads were washed with distilled water to neutral and freeze dried. The sorbents were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX), Fourier transform infrared spectrometry (FTIR), and X-ray diffractometry (XRD), respectively. Batch adsorption experiments were conducted to evaluate the parameters that affected the defluoridation capacity. The influencing parameters including pH, co-existing ions in water and initial temperature of the adsorption process were studied. The influence of temperature confirmed that the adsorption was spontaneous and endothermic. The adsorption isotherm of fluoride followed Langmuir isotherm model and the sorption kinetics was more suitable for pseudo-second-order kinetic model. The defluoridation capacity of chitosan/Al(OH)3 calculated using Langmuir model was 23.06 mg/g (293 K, pH 4). The experimental results showed that the CS/Al(OH)3 bead adsorbent is promising for the fluoride adsorption.

Keywords

Chitosan Fluoride Sorption Aluminum hydroxide Defluoridation capacity 

Notes

Acknowledgements

This work was supported by the Project of Education Department of Fujian Province (No. JA15080) and National Natural Science Foundation of China (No. 21676057).

References

  1. 1.
    WHO (2006) Guidelines for drinking-water quality (First Addendum to 3rd edn). http://www.who.int/water_sanitation_health/dwq/gdwq0506.pdf
  2. 2.
    Lu NC, Liu JC (2010) Removal of phosphate and fluoride from waste water by a hybrid precipitation-microfiltration process. Sep Purif Technol 74:329–335CrossRefGoogle Scholar
  3. 3.
    Ndiaye PI, Moulin P, Dominguez L, Millet JC, Charbit F (2005) Removal of fluoride from electronic industrial effluent by RO membrane separation. Desalination 173:25–32CrossRefGoogle Scholar
  4. 4.
    Hu CY, Lo SL, Kuan WH, Lee YD (2008) Treatment of high fluoride-content wastewater by continuous electrocoagulation-flotation system with bipolar aluminum electrodes. Sep Purif Technol 60:1–5CrossRefGoogle Scholar
  5. 5.
    Chakrabortty S, Roy M, Pal P (2013) Removal of fluoride from contaminated groundwater by cross flow nanofiltration: transport modeling and economic evaluation. Desalination 313:115–124CrossRefGoogle Scholar
  6. 6.
    Ruan Z, Tian Y, Ruan J (2017) Synthesis of hydroxyapatite/multi-walled carbon nanotubes for the removal of fluoride ions from solution. Appl Surf Sci 412:578–590CrossRefGoogle Scholar
  7. 7.
    Viswanathan N, Sairam Sundaram C, Meenakshi S (2009) Removal of fluoride from aqueous solution using protonated CS beads. J Hazard Mater 161:443–450CrossRefGoogle Scholar
  8. 8.
    Zhang C, Li Y, Wang TJ (2017) Synthesis and properties of a magnetic core–shell composite nano-adsorbent for fluoride removal from drinking water. Appl Surf Sci 425:272–281CrossRefGoogle Scholar
  9. 9.
    Chen KH, Ling YZ, Cao C, Li XY, Chen X, Wang XY (2016) Chitosan derivatives/reduced graphene oxide/alginate beads for small-molecule drug delivery. Mat Sci Eng C Mater 69:1222–1228CrossRefGoogle Scholar
  10. 10.
    Li XY, Han Y, Ling YZ, Wang XY, Sun RC (2015) Assembly of layered silicate loaded quaternized chitosan-reduced graphene oxide composites as efficient absorbents for double-stranded DNA. ACS Sustain Chem Eng 3:1846–1852CrossRefGoogle Scholar
  11. 11.
    Luo JW, Han GC, Xie MJ, Cai ZR, Wang XY (2015) Quaternized chitosan/montmorillonite nanocomposite resin and its adsorption behavior. Iran Polym J 24:531–539CrossRefGoogle Scholar
  12. 12.
    Liu B, Luo J, Wang X, Lu J, Deng H, Sun R (2013) Alginate/quaternized carboxymethyl chitosan/clay nanocomposite microspheres: preparation and drug-controlled release behavior. J Biomat Sci Polym E 24:589–605CrossRefGoogle Scholar
  13. 13.
    Pandey S, Ramontja J (2016) Rapid, facile microwave-assisted synthesis of xanthan gum grafted polyaniline for chemical sensor. Int J Biol Macromol 89:89–98CrossRefGoogle Scholar
  14. 14.
    Pandey S, Ramontja J (2016) Sodium alginate stabilized silver nanoparticles–silica nanohybrid and their antibacterial characteristics. Int J Biol Macromol 93:712–723CrossRefGoogle Scholar
  15. 15.
    Camacho LM, Torres A, Saha D, Deng SG (2010) Adsorption equilibrium and kinetics of fluoride on sol–gel-derived activated alumina adsorbents. J Colloid Interface Sci 349:307–313CrossRefGoogle Scholar
  16. 16.
    Maliyekkal SM, Shukla S, Philip L, Nambi IM (2008) Enhanced fluoride removal from drinking water by magnesia-amended activated alumina granules. Chem Eng J 140:183–192CrossRefGoogle Scholar
  17. 17.
    Daifullah AAM, Yakout SM, Elreefy SA (2007) Adsorption of fluoride in aqueous solutions using KMnO4-modified activated carbon derived from steam pyrolysis of rice straw. J Hazard Mater 147:633–643CrossRefGoogle Scholar
  18. 18.
    Li YH, Zhang P, Du QJ, Peng XJ, Liu TH, Wang ZH (2011) Adsorption of fluoride from aqueous solution by graphene. J Colloid Interface Sci 363:348–354CrossRefGoogle Scholar
  19. 19.
    Tchomgui-Kamga E, Ngameni E, Darchen A (2010) Evaluation of removal efficiency of fluoride from aqueous solution using new charcoals that contain calcium compounds. J Colloid Interface Sci 346:494–499CrossRefGoogle Scholar
  20. 20.
    Ramdani A, Taleb S, Benghalem A, Ghaffour N (2010) Removal of excess fluoride ions from Saharan brackish water by adsorption on natural materials. Desalination 250:408–413CrossRefGoogle Scholar
  21. 21.
    Jagtapa S, Yenkie MK, Das S, Rayalu S (2011) Synthesis and characterization of lanthanum impregnated CS flakes for fluoride removal in water. Desalination 273:267–275CrossRefGoogle Scholar
  22. 22.
    Das NN, Konar J, Mohanta MK, Upadhaya AK (2010) Synthesis, characterization and adsorptive properties of hydrotalcite-like compounds derived from titanium rich bauxite. Reac Kinet Mech Cat 99:167–176Google Scholar
  23. 23.
    Onyango MS, KojimaY Aoyic O, Bernardo EC, Matsuda H (2004) Adsorption equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalent-cation-exchanged zeolite F-9. J Colloid Interface Sci 279:341–350CrossRefGoogle Scholar
  24. 24.
    Sun YB, Fang QH, Dong JP, Cheng XW, Xu JQ (2011) Removal of fluoride from drinking water by natural stilbite zeolite modified with Fe(III). Desalination 277:121–127CrossRefGoogle Scholar
  25. 25.
    Zhou QS, Lin XY, Lin B, Luo XG (2014) Fluoride adsorption from aqueous solution by aluminum alginate particles prepared via electrostatic spinning device. Chem Eng J 256:306–315CrossRefGoogle Scholar
  26. 26.
    Singh V, Kumari PL, Tiwari A, Pandey S (2010) Alumina-supported microwave synthesis of Cassia marginata seed gum-graft-polyacrylamide. J Appl Polym Sci 117:3630–3638Google Scholar
  27. 27.
    Singh V, Singh SK, Pandey S, Sanghi R (2011) Synthesis and characterization of guar gum templated hybrid nano silica. Int J Biol Macromol 49:233–240CrossRefGoogle Scholar
  28. 28.
    Singh V, Singh SK, Pandey S, Kumar P (2011) Synthesis and characterization of guar gum templated hybrid nano silica. J Non-Cryst Solids 357:194–201CrossRefGoogle Scholar
  29. 29.
    Pourjavadi A, Tehrani ZM, Salimi H (2015) Hydrogel nanocomposite based on chitosan-g -acrylic acid and modified nanosilica with high adsorption capacity for heavy metal ion removal. Iran Polym J 24:725–734CrossRefGoogle Scholar
  30. 30.
    Mallakpour S, Khadem E (2017) Chitosan reinforced with modified CaCO3 nanoparticles to enhance thermal, hydrophobicity properties and removal of Cu(II) and Cd(II) ions. J Polym Res 24:86CrossRefGoogle Scholar
  31. 31.
    Parhizgar F, Alishahi A, Varasteh H (2017) Removing sodium dodecyl benzene sulfonate (SDBS) from aqueous solutions using chitosan. J Polym Environ 25:836–843CrossRefGoogle Scholar
  32. 32.
    Dash M, Chiellini F, Ottenbrite RM, Chiellini E (2011) CS-A versatile semi-synthetic polymer in biomedical applications. Prog Polym Sci 36:981–1014CrossRefGoogle Scholar
  33. 33.
    Yang K, Zhang X, Chao C, Zhang B, Liu JD (2014) In-situ preparation of NaA zeolite/CS porous hybrid beads for removal of ammonium from aqueous solution. Carbohydr Polym 107:103–109CrossRefGoogle Scholar
  34. 34.
    Ramos RL, Ovalle-Turrubiartes J, Sanchez-Castillo MA (1999) Adsorption of fluoride from aqueous solution on aluminum-impregnated carbon. Carbon 37:609–617CrossRefGoogle Scholar
  35. 35.
    Ganvir V, Das K (2011) Removal of fluoride from drinking water using aluminum hydroxide coated rice husk ash. J Hazard Mater 185:1287–1294CrossRefGoogle Scholar
  36. 36.
    Biswas K, Saha SK, Ghosh U (2007) Adsorption of fluoride from aqueous solution by a synthetic iron(III)–aluminum(III) mixed oxide. J Ind Eng Chem 46:5346–5356CrossRefGoogle Scholar
  37. 37.
    Tchomgui-Kamga E, AlonzoV Nanseu-Njiki CP, Audebrand N, Ngameni E, Darchen A (2010) Preparation and characterization of charcoals that contain dispersed aluminum oxide as adsorbents for removal of fluoride from drinking water. Carbon 48:333–343CrossRefGoogle Scholar
  38. 38.
    Jiang XC, Zhao YL, Hou LX (2016) The effect of glycerol on properties of chitosan/poly(vinyl alcohol) films with AlCl3·6H2O aqueous solution as the solvent for chitosan. Carbohydr Polym 135:191–198CrossRefGoogle Scholar
  39. 39.
    Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1402CrossRefGoogle Scholar
  40. 40.
    Freundlich HMF (1906) Über die adsorption in lösungen, zeitschrift für physikalische chemie. J Am Chem Soc 62:121–125Google Scholar
  41. 41.
    Periasamy K, Namasivayam C (1994) Process development for removal and recovery of cadmium from wastewater by a low cost adsorbent: adsorption rates and equilibrium studies. Ind Eng Chem Res 33:317–320CrossRefGoogle Scholar
  42. 42.
    Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Bio 34:451–465CrossRefGoogle Scholar
  43. 43.
    Zhu HY, Fu YQ, Jiang R, Yao J, Xiao L, Zeng GM (2012) Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: preparation, characterization and application for adsorption of dye from aqueous solution. Bioresour Technol 105:24–30CrossRefGoogle Scholar
  44. 44.
    Ibrahim DM, Abu-Ayana YM (2008) Preparation and characterization of ultrafine alumina via sol–gel polymeric route. Mater Chem Phys 11:326–330CrossRefGoogle Scholar
  45. 45.
    Hughes J, Ramsden DK, Symes KC (1990) The flocculation of bacteria using cationic synthetic flocculants and chitosan. Biotechnol Tech 4:55–60CrossRefGoogle Scholar
  46. 46.
    Jiang XC, Zhang XF, Ye DZ, Zhang X, Dai H (2012) Modification of poly(vinyl alcohol) films by the addition of magnesium chloride hexahydrate. Polym Eng Sci 52:1565–1570CrossRefGoogle Scholar
  47. 47.
    Elwakeela KZ, Guibal E (2015) Arsenic(V) sorption using chitosan/Cu(OH)2 and chitosan/CuO composite sorbents. Carbohydr Polym 134:190–204CrossRefGoogle Scholar
  48. 48.
    Li W, Cao CY, Wu LY, Ge MF, Song WG (2011) Superb fluoride and arsenic removal performance of highly ordered mesoporous aluminas. J Hazard Mater 198:143–150CrossRefGoogle Scholar
  49. 49.
    López Valdivieso A, Reyes Bahena JL, Song S, Herrera Urbina R (2006) Temperature effect on the zeta potential and fluoride adsorption at the α-Al2O3/aqueous solution interface. J Colloid Interface Sci 298:1–5CrossRefGoogle Scholar
  50. 50.
    Wang SG, Ma Y, Shi Y, Gong WX (2009) Defluoridation performance and mechanism of nano-scale aluminum oxide hydroxide in aqueous solution. J Chem Technol Biot 84:1043–1050CrossRefGoogle Scholar
  51. 51.
    Prabhu SM, Meenakshi S (2015) Adendrimer-like hyper branched chitosan beads toward fluoride adsorption from water. Int J Biol Macromol 78:280–286CrossRefGoogle Scholar

Copyright information

© Iran Polymer and Petrochemical Institute 2018

Authors and Affiliations

  • Haifeng Hu
    • 1
  • Liu Yang
    • 2
  • Zhen Lin
    • 1
  • Yulai Zhao
    • 1
  • Xiancai Jiang
    • 1
  • Linxi Hou
    • 1
  1. 1.School of Chemical EngineeringFuzhou UniversityFuzhouPeople’s Republic of China
  2. 2.School of Petroleum EngineeringChina University of PetroleumQingdaoPeople’s Republic of China

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