Skip to main content

Advertisement

Log in

Provisional investigation of biomass pyrolysis in CSTR using Simulink® and Aspen Plus®

  • Original Article
  • Published:
Biomass Conversion and Biorefinery Aims and scope Submit manuscript

Abstract

A Simulink-based model is designed to simulate biomass pyrolysis as a case study. The Simulink model has a separate database for system models, material properties, and thermodynamic models. The data flow has been standardised and straightforward to use with user-supplied data. The simulation results are validated with the results from Aspen Plus. Given that Aspen Plus is licensed software cast-aside, the scope for young researchers to design and analyse the performance of a process. The purpose is not an alternative to Aspen Plus but to serve the ease of accessibility and work. The present case study considers biomass pyrolysis in a bubbling bed reactor. The screw feeder is considered, in practice, to accomplish continuous introduction of feed biomass to the bed. The bubbling bed realises vigorous mixing of solid-phase; a continuous stirred tank reactor (CSTR) model is more suitable to represent the pyrolysis reaction dynamics. The pyrolysis reactions were proposed and applied to model a pyrolysis reactor. This process analysis is based on operating factors such as reaction temperature, residence duration, biomass-wood type, and reactor type. To evaluate the foregoing findings, the results of other researchers’ process analyses are compared. Pyro-char, a by-product of pyro-oil manufacture, aids in retaining moisture and nutrients in forest soils and has been an aspect of environmental importance. Hence, this research focuses on determining the precise reaction for biomass pyrolysis in a CSTR with high oil yield rates, char yields, and biomass conversion.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Li J, Burra KG, Wang Z et al (2021) Effect of alkali and alkaline metals on gas formation behavior and kinetics during pyrolysis of pine wood. Fuel 290:120081. https://doi.org/10.1016/j.fuel.2020.120081

    Article  Google Scholar 

  2. Choi M, kyu, Park HC, Choi HS, (2018) Comprehensive evaluation of various pyrolysis reaction mechanisms for pyrolysis process simulation. Chem Eng Process - Process Intensif 130:19–35. https://doi.org/10.1016/j.cep.2018.05.011

    Article  Google Scholar 

  3. Zhang L, Bao Z, Xia S, et al (2018) Catalytic pyrolysis of biomass and polymer wastes. Catalysts

  4. Palanki S, Kolavennu S (2003) Simulation of control of a CSTR process. Int J Eng Educ 19:

  5. Prokopova Z, Prokop R (2009) Modelling and simulation of chemical industrial reactors. In: ECMS 2009 Proceedings edited by J. Otamendi, A. Bargiela, J. L. Montes, L. M. Doncel Pedrera. ECMS, pp 378–383

  6. Degenstein JC (2016) Fast-pyrolysis of biomass related model compounds : a novel approach to experimental study and modeling

  7. Forchheim D (2013) Optimisation of the reaction parameters in a batch reactor and a CSTR for the recovery of phenol from hydrothermal biomass liquefaction

  8. Morin M, Pécate S, Hémati M (2018) Experimental study and modelling of the kinetic of biomass char gasification in a fluidised bed reactor. Chem Eng Res Des 131:488–505. https://doi.org/10.1016/j.cherd.2017.09.030

    Article  Google Scholar 

  9. Papari S, Hawboldt K (2015) A review on the pyrolysis of woody biomass to bio-oil: Focus on kinetic models. Renew. Sustain. Energy Rev.

  10. Sun X, Atiyeh HK, Zhang H, et al (2019) Enhanced ethanol production from syngas by Clostridium ragsdalei in continuous stirred tank reactor using medium with poultry litter biochar. Appl Energy 236https://doi.org/10.1016/j.apenergy.2018.12.010

  11. Klasson KT, Gupta A, Clausen EC, Gaddy JL (1993) Evaluation of mass-transfer and kinetic parameters for Rhodospirillum rubrum in a continuous stirred tank reactor. Appl Biochem Biotechnol 39 https://doi.org/10.1007/BF02919017

  12. Thaore VB, Gaikar VG (2013) Kinetic model development for steam pyrolysis of dimethylformamide in a tubular reactor. Ind Eng Chem Res 52(31): https://doi.org/10.1021/ie4003238

  13. Wang S, Dai G, Yang H, Luo Z (2017) Lignocellulosic biomass pyrolysis mechanism: a state-of-the-art review. Prog. Energy Combust. Sci.

  14. Vikram S, Rosha P, Kumar S (2021) Recent modeling approaches to biomass pyrolysis: a review. Energy and Fuels

  15. Smith JD, Alembath A, Al-Rubaye H et al (2019) Validation and application of a kinetic model for downdraft biomass gasification simulation. Chem Eng Technol 42:2505–2519

    Article  Google Scholar 

  16. Ji W, Richter F, Gollner MJ, Deng S (2021) Autonomous kinetic modeling of biomass pyrolysis using chemical reaction neural networks. arXiv Prepr arXiv210511397

  17. Tancredi N, Cordero T, Rodríguez-Mirasol J, Rodríguez JJ (1996) CO2 gasification of eucalyptus wood chars. Fuel 75https://doi.org/10.1016/0016-2361(96)82641-X

  18. Varma AK, Thakur LS, Shankar R, Mondal P (2019) Pyrolysis of wood sawdust: effects of process parameters on products yield and characterisation of products. Waste Manag 89:224–235

    Article  Google Scholar 

  19. Swapan Suman SG (2020) Physicochemical performance of wood chips char and wheat husk char for utilisation as an alternate source of energy. Int J Recent Technol Eng 8:. https://doi.org/10.35940/ijrte.c6119.018520

  20. Widiyannita AM, Cahyono RB, Budiman A, et al (2016) Study of pyrolysis of ulin wood residues. In: AIP Conference Proceedings. AIP Publishing LLC, p 50004

  21. Sinha S, Jhalani A, Ravi MR, Ray A (2000) Modelling of pyrolysis in wood: a review. SESI J 10:41–62

    Google Scholar 

  22. Wagenaar BM, Prins W, van Swaaij WPM (1993) Flash pyrolysis kinetics of pine wood. Fuel Process Technol 36https://doi.org/10.1016/0378-3820(93)90039-7

  23. Boot-Handford ME, Virmond E, Florin NH et al (2018) Simple pyrolysis experiments for the preliminary assessment of biomass feedstocks and low-cost tar cracking catalysts for downdraft gasification applications. Biomass Bioenerg 108:398–414

    Article  Google Scholar 

  24. Halim SA, Swithenbank J (2016) Characterisation of Malaysian wood pellets and rubberwood using slow pyrolysis and microwave technology. J Anal Appl Pyrolysis 122:64–75

    Article  Google Scholar 

  25. Guizani C, Jeguirim M, Valin S et al (2017) Biomass chars: the effects of pyrolysis conditions on their morphology, structure, chemical properties and reactivity. Energies 10:796

    Article  Google Scholar 

  26. Santamaria L, Beirow M, Mangold F, et al (2021) Influence of temperature on products from fluidised bed pyrolysis of wood and solid recovered fuel. Fuel 283:118922

  27. Mätzing H, Baris D, Ciuta S, et al (2016) Measurement and modelling of the pyrolysis gas composition of natural wood and waste wood

  28. Lu P, Huang Q, Chi Y, et al (2019) Catalytic cracking of tar derived from the pyrolysis of municipal solid waste fractions over biochar. Proc Combust Insthttps://doi.org/10.1016/j.proci.2018.06.051

  29. Lu P, Huang Q, Bourtsalas ACT et al (2018) Synergistic effects on char and oil produced by the co-pyrolysis of pine wood, polyethylene and polyvinyl chloride. Fuel 230:359–367

    Article  Google Scholar 

  30. Wiley J, Hepburn K, Levenspiel O (1999) Chemical reaction engineering - third edition

  31. MathWorks Simulink for system modeling and simulation

  32. The MathWorks I Block libraries

  33. Poddar S, Sarat Chandra Babu J (2021) Modelling and optimisation of a pyrolysis plant using swine and goat manure as feedstock. Renew Energy 175:253–269. https://doi.org/10.1016/j.renene.2021.04.120

    Article  Google Scholar 

  34. Unlu D, Hilmioglu ND (2020) Application of Aspen Plus to renewable hydrogen production from glycerol by steam reforming. Int J Hydrogen Energy 45 https://doi.org/10.1016/j.ijhydene.2019.02.106

  35. Lu P, Huang Q, (Thanos) Bourtsalas AC, et al (2018) Synergistic effects on char and oil produced by the co-pyrolysis of pine wood, polyethylene and polyvinyl chloride. Fuel 230: https://doi.org/10.1016/j.fuel.2018.05.072

  36. Widiyannita AM, Cahyono RB, Budiman A, et al (2016) Study of pyrolysis of ulin wood residues. In: AIP Conference Proceedings. p 050004

  37. Han D, Yang X, Li R, Wu Y (2019) Environmental impact comparison of typical and resource-efficient biomass fast pyrolysis systems based on LCA and Aspen Plus simulation. J Clean Prod 231https://doi.org/10.1016/j.jclepro.2019.05.094

  38. Mohan D, Pittman CU, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20:848–889. https://doi.org/10.1021/ef0502397

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to thank Dr Sourav Poddar and Dr Sarat Chandra Babu J. for guiding them throughout the research. The authors would like to thank Dr. (Mrs.) P. Kalaichelvi, Head Department of Chemical Engineering, and the Director Prof. (Dr.) Mini Shaji Thomas and the administration of the National Institute of Technology, Tiruchirappalli, Tamil Nadu, for helping us with immense support.

Author information

Authors and Affiliations

Authors

Contributions

Yamini K. did the paper writing in this work. Both Yamini K. and Sandeep Charan K. have performed the analysis required for this work in MATLAB-Simulink and Aspen Plus environments. Yamini K: conceptualisation, data curation, formal analysis, investigation, software utilisation, validation, visualisation, writing. Sandeep Charan K: conceptualisation, data curation, formal analysis, investigation, software utilisation, validation, visualisation, writing. Dr Sourav Poddar: conceptualisation, data curation, formal analysis, investigation, software utilisation, validation, visualisation, writing, review, and editing — original and final manuscript. Prof. (Dr.) J. Sarat Chandra Babu: funding acquisition, project administration, supervision, validation, visualisation, writing — review and editing.

Corresponding authors

Correspondence to Sourav Poddar or Sarat Chandra Babu J..

Ethics declarations

Conflict of interest

The authors declare no competing interests.

Additional information

Publisher's note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Highlights

• The proximate and ultimate analysis required for pyrolysis of biomass is summarised.

• Pioneer to simulate, the rate equations are required for pyrolysis with biomass feedstock in Simulink.

• Reviewed the results from Simulink using Aspen Plus.

• In conclusion, determined the precise reaction for pyrolysis of biomass which can be deployed, reliant on the scope of the research.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (TXT 0 KB)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

K., Y., K., S.C., Poddar, S. et al. Provisional investigation of biomass pyrolysis in CSTR using Simulink® and Aspen Plus®. Biomass Conv. Bioref. 13, 15903–15916 (2023). https://doi.org/10.1007/s13399-022-02311-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13399-022-02311-9

Keywords

Navigation