Abstract
Rice straw, a leftover vegetative part of rice plant, is neither efficiently composted nor used as a feed in India. Moreover, due to the need for quick disposal, operational difficulties in small-scale pulp and paper mills and lack of logistical convenience rice straw doesn’t find other large-scale commercial applications, and therefore is burnt openly in fields causing tremendous air pollution in parts of India. In the present work, a prospective commercially viable small-scale on-field utilization of rice straw was identified for the first time through an environmentally benign process. Refiner mechanical pulping was successfully used for converting rice straw into paperboard and a food-serving bowl. The prepared rice straw paperboard was found equivalent to grade-III Kraft paper as specified in IS 1397:1990, when compared for tensile and burst index. The molded bowl could become an environment friendly alternative for the presently used disposable food-serving containers made of plastics. Three different chemical treatments were attempted to impart water- and grease-resistance to the rice straw paperboard and bowl as demanded by the conceived application. Water absorption was reduced from 387 to 3 g·m−2 as measured by Cobb60 test and grease-resistance was improved from 0 to 10 as measure by Kit test. Moreover, the sizing process didn’t render the bowls harmful to consumers’ health in terms of toxicity. Summarily, the utilization of rice straw pulp for making value-added products holds promise in mitigating air pollution, reducing plastic-based disposables, and in promoting entrepreneurship in rural areas.
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References
Kaur D, Bhardwaj NK, Lohchab RK (2017) Prospects of rice straw as a raw material for paper making. Waste Manag 60:127–139. https://doi.org/10.1016/j.wasman.2016.08.001
Sood J (2015) Not a waste until wasted - Punjab farmers burn straw after harvest. It is time to exploit the potential of this agro-waste. https://www.downtoearth.org.in/coverage/not-a-waste-until-wasted-40051. Accessed 06 Nov 2020
Datta A, Emmanuel MA, Ram NK, Dhingra S (2020) https://www.teriin.org/article/impact-stubble-burning-and-poor-air-quality-india-during-time-covid-19. Accessed 06 Nov 2020
Satyendra T, Singh RN, Shaishav S (2013) Emissions from crop/biomass residue burning risk to atmospheric quality. Int Res J Earth Sci 1:1–5
Haile A, Gebino G, Tesfaye T, Mengie W, Ayele M, Abuhay A, Yilie D (2021) Utilization of non-wood biomass for pulp manufacturing in paper industry: case of Ethiopia. Biomass Conv Bioref. https://doi.org/10.1007/s13399-021-01424-x
Sasaki K, Okamoto M, Shirai T et al (2016) Toward the complete utilization of rice straw : methane fermentation and lignin recovery by a combinational process involving mechanical milling, supporting material and nanofiltration. Bioresour Technol 216:830–837. https://doi.org/10.1016/j.biortech.2016.06.029
Kadam S, Sharma A, Islam S et al (2020) Utilization of rice straw as a source of biomolecules for sustainable multifunctional finishing vis a vis dyeing of wool utilization of rice straw as a source of biomolecules for sustainable multifunctional finishing vis a vis dyeing of wool. J Nat Fibers 17:1508–1518. https://doi.org/10.1080/15440478.2019.1581120
Lou R, Wu SB, Lv GJ, Guo DL (2010) Pyrolytic products from rice straw and enzymatic/mild acidolysis lignin (EMAL). BioResources 5:2184–2194. https://doi.org/10.15376/biores.5.4.2184-2194
Munshi S, Sharma RP (2019) Utilization of rice straw ash as a mineral admixture in construction work. Mater Today Proc 11:637–644. https://doi.org/10.1016/j.matpr.2019.03.021
Jackson MG (1978) Rice straw as livestock feed. In: Ruminant nutrition: selected articles from the World Animal Review. http://www.fao.org/3/X6512E/X6512E07.htm. Accessed 06 Nov 2020
Rodríguez A, Sánchez R, Requejo A, Ferrer A (2010) Feasibility of rice straw as a raw material for the production of soda cellulose pulp. J Clean Prod 18:1084–1091. https://doi.org/10.1016/j.jclepro.2010.03.011
Singh AK, Chandra R (2019) Pollutants released from the pulp paper industry: aquatic toxicity and their health hazards. Aquat Toxicol 211:202–216. https://doi.org/10.1016/j.aquatox.2019.04.007
Pokhrel D, Viraraghavan T (2004) Treatment of pulp and paper mill wastewater — a review. Sci Total Environ 333:37–58. https://doi.org/10.1016/j.scitotenv.2004.05.017
Sain M (2020) Production of bioplastic and sustainable packaging materials from rice straw to eradicate stubble burning (a mini review). Environ Conserv J 21:1–5. https://doi.org/10.36953/ecj.2020.21301
Bildik AE, Hubbe MA, Gürboy KB (2016) Alkyl ketene dimer (AKD) sizing of paper under simplified treatment conditions. TAPPI J 15:545–552
Shen Z, Kwon S, Oh K et al (2019) Facile fabrication of hydrophobic cellulosic paper with good barrier properties via PVA/AKD dispersion coating. Nord Pulp Pap Res J 34:516–524. https://doi.org/10.1515/npprj-2019-0040
Wise LE, Murphy M, Adieco AAD (1946) A chlorite holocellulose, its fractionation and bearing on summative wood analysis and studies on the hemicelluloses. Pap trade J 2:35–40
Rodriguez A, Moral A, Sánchez R et al (2009) Influence of variables in the hydrothermal treatment of rice straw on the composition of the resulting fractions. Bioresour Technol 100:4863–4866. https://doi.org/10.1016/j.biortech.2009.04.030
U.S. Food and Drug Administration (2019) 21CFR176.120. Substances for Use Only as Components of Paper and Paperboard. https://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr=176.120. Accessed 06 Nov 2020
Davachi SM, Bakhtiari S, Pouresmaeel-Selakjani P et al (2018) Investigating the effect of treated rice straw in PLLA/starch composite: mechanical, thermal, rheological, and morphological study. Adv Polym Technol 37:5–16. https://doi.org/10.1002/adv.21634
Jakate DN, Rao V, Swamy VSR et al (1981) Soda-AQ [anthraquinone] pulping of rice straw. TAPPI J Tech Assoc Pulp Pap Ind 6:124–125
Shao S, Wu C, Chen K (2017) Refining, dewatering, and paper properties of soda-anthraquinone (soda/AQ) pulp from rice straw. BioResources 12:4867–4880. https://doi.org/10.15376/biores.12.3.4867-4880
Kaur D, Bhardwaj NK, Lohchab RK (2018) A study on pulping of rice straw and impact of incorporation of chlorine dioxide during bleaching on pulp properties and effluents characteristics. J Clean Prod 170:174–182. https://doi.org/10.1016/j.jclepro.2017.09.111
Rodriguez A, Moral A, Serrano L et al (2008) Rice straw pulp obtained by using various methods. Bioresour Technol 99:2881–2886. https://doi.org/10.1016/j.biortech.2007.06.003
Rodríguez A, Serrano L, Moral A, Jiménez L (2008) Pulping of rice straw with high-boiling point organosolv solvents. Biochem Eng J 42:243–247
Ho CL, Wang EIC, Su YC (2009) Tetrahydrofurfuryl alcohol (THFA) pulping of rice straw. J Wood Chem Technol 29:101–118. https://doi.org/10.1080/02773810902796138
Jahan MS, Lee ZZ, Jin Y (2006) Organic acid pulping of rice straw. I: Cooking. Turkish J Agric For 30:231–239. https://doi.org/10.3906/tar-0505-4
Casey JP (1960) Pulp and paper-Chemistry and Chemical Technology, 2nd edn. Interscience Publishers Inc, New York, p 1027
Jani SM, Rushdan I (2016) Mechanical properties of beating pulp and paper from rice straw. J Trop Agric Fd Sc 44:103–109
Schott S, Chaussy D, Mauret E et al (2003) Valorisation of different agricultural crops in papermaking applications. In: Baudin G, Fellegi J, Gellerstedt G et al (eds) Proceedings of the international conference “Chemical technology of wood, pulp and paper.” Slovak University of Technology, Bratislava, pp 168–170
Nassar MA, Ibrahim S, Attia M, Refaat Y (2017) Improving the performance of local manufactured paperboard. Egypt J Chem 60:435–442. https://doi.org/10.21608/EJCHEM.2017.3595
Potucek F, Rihova M, Gurung B (2013) Chemic-mechanical pulp from rapeseed straw. Cellulose Chem Technol 50:489–496
Varshoei A, Javid E, Rahmaninia M, Rahmany F (2013) The performance of alkylketene dimer (AKD) for the internal sizing of recycled OCC pulp. Lignocellulose 2:316–326
BIS (1999) Kraft paper - Specification Bur. Indian Stand, New Delhi
Chen F, Song X, Liu F, Liu D (2013) Calculation of the reactivity of alkyl ketene dimer with ethanol and the characterization of reaction products. Asian J Chem 25:1182–1186
Lindström T, Larsson PT (2008) Alkyl Ketene Dimer (AKD) sizing – a review. Nord Pulp Pap Res J 23:202–209
SIAM 20 (2005) SIDS Initial assessment profile. UK/ICCA. https://hpvchemicals.oecd.org/ui/handler.axd?id=e74fc6e7-fef5-4661-b424-23de896ce75b#:~:text=Cross%20reading%20from%20a%20newly,experimental%20animal%20and%20human%20studies. Accessed 10 June 2021
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The authors gratefully acknowledge the Ministry of Human Resource Development (MHRD), Govt. of India for financial support.
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Saini, S., Kadam, A.A., Kumar, V. et al. Conversion of rice straw into disposable food-serving bowl via refiner mechanical pulping: an environmentally benign approach to mitigate stubble burning and plastic pollution. Biomass Conv. Bioref. 13, 6797–6806 (2023). https://doi.org/10.1007/s13399-021-01728-y
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DOI: https://doi.org/10.1007/s13399-021-01728-y