Abstract
Energy derived from biomass is, nowadays, one of the most attractive options to mitigate fossil fuel use. In this study, an organically fertilized poplar plot was employed. The goals of this work were, in the first place, to analyze the thermal behavior of the samples considering three thermal processes: combustion, gasification, and pyrolysis to, finally, try to determine the influence of the poplar clone and the subscriber type about this parameter. For these purposes, thermogravimetric analysis (TGA) together with kinetic parameters and thermal indexes was used. In the same way, fuel properties were determined. Hence, having average higher heating value around 20 MJ/kg and other accurate properties, poplar samples were considered as a fuel with optimal properties. TGA profiles were different for the thermal processes compared. Four different emission stages appeared for both combustion and gasification (moisture, hemicellulose, cellulose, and lignin). However, pyrolysis profiles showed a different pattern. Thermal index results were higher for the combustion than for the rest of the processes.
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References
Basu P (2018) Biomass gasification, pyrolysis, and torrefaction: practical design and theory. Academic press
Shafiee S, Topal E (2009) When will fossil fuel reserves be diminished? Energy Policy 37:181–189. https://doi.org/10.1016/j.enpol.2008.08.016
Khalil EE (2012) The role of solar and other renewable energy sources on the strategic energy planning: Africa’s status & views. ASHRAE Trans 118:64
Bhattacharya SC, Salam PA, Pham HL, Ravindranath NH (2003) Sustainable biomass production for energy in selected Asian countries. Biomass Bioenergy 25:471–482. https://doi.org/10.1016/S0961-9534(03)00085-0
Chinnici G, D’Amico M, Rizzo M, Pecorino B (2015) Analysis of biomass availability for energy use in Sicily. Renew Sust Energ Rev 52:1025–1030. https://doi.org/10.1016/j.rser.2015.07.174
Koppejan J, Van Loo S (2012) Biomass fuel supply and pre-treatment. The Handbook of Biomass Combustion and Co-firing, In
Georgescu M, Lobell DB, Field CB (2011) Direct climate effects of perennial bioenergy crops in the United States. Proc Natl Acad Sci U S A 108:4307–4312. https://doi.org/10.1073/pnas.1008779108
Hill J, Nelson E, Tilman D, Polasky S, Tiffany D (2006) Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. Proc Natl Acad Sci U S A 103:11206–11210. https://doi.org/10.1073/pnas.0604600103
Narayan R (2006) Rationale, drivers, standards, and technology for biobased materials. Renew Resour renew energy—a glob Chall 1208863900:
Teske S, Muth J, Sawyer S et al (2012) Energy [r] evolution-a sustainable world energy outlook. Greenpeace International, EREC and GWEC
Silva TCF, Santos RB, Jameel H, Colodette JL, Lucia LA (2012) Quantitative molecular structure–pyrolytic energy correlation for hardwood lignins. Energy Fuel 26:1315–1322. https://doi.org/10.1021/ef2014869
Karampinis E, Vamvuka D, Sfakiotakis S, Grammelis P, Itskos G, Kakaras E (2012) Comparative study of combustion properties of five energy crops and Greek lignite. Energy Fuel 26:869–878. https://doi.org/10.1021/ef2014088
Nordborg M, Berndes G, Dimitriou I, Henriksson A, Mola-Yudego B, Rosenqvist H (2018) Energy analysis of willow production for bioenergy in Sweden. Renew Sust Energ Rev 93:473–482. https://doi.org/10.1016/j.rser.2018.05.045
Al Afas N, Marron N, Van Dongen S et al (2008) Dynamics of biomass production in a poplar coppice culture over three rotations (11 years). For Ecol Manag 255:1883–1891
Mantineo M, D’Agosta GM, Copani V, Patanè C, Cosentino SL (2009) Biomass yield and energy balance of three perennial crops for energy use in the semi-arid Mediterranean environment. F Crop Res 114:204–213. https://doi.org/10.1016/J.FCR.2009.07.020
Dimitriou I, Rosenqvist H (2011) Sewage sludge and wastewater fertilisation of short rotation coppice (SRC) for increased bioenergy production—biological and economic potential. Biomass Bioenergy 35:835–842. https://doi.org/10.1016/j.biombioe.2010.11.010
Marron N (2015) Agronomic and environmental effects of land application of residues in short-rotation tree plantations: a literature review. Biomass Bioenergy 81:378–400. https://doi.org/10.1016/j.biombioe.2015.07.025
Lafleur B, Thiffault E, Paré D, Camiré C, Bernier-Cardou M, Masse S (2012) Effects of hog manure application on the nutrition and growth of hybrid poplar (Populus spp.) and on soil solution chemistry in short-rotation woody crops. Agric Ecosyst Environ 155:95–104. https://doi.org/10.1016/j.agee.2012.04.002
Paniagua S, Escudero L, Escapa C, Coimbra RN, Otero M, Calvo LF (2016) Effect of waste organic amendments on Populus sp biomass production and thermal characteristics. Renew Energy 94:166–174. https://doi.org/10.1016/j.renene.2016.03.019
Paniagua S, Escudero L, Coimbra RN, Escapa C, Otero M, Calvo LF (2018) Effect of applying organic amendments on the pyrolytic behavior of a poplar energy crop. Waste Biomass Valorization 9:1435–1449. https://doi.org/10.1007/s12649-017-9885-1
Wang C, Wang F, Yang Q, Liang R (2009) Thermogravimetric studies of the behavior of wheat straw with added coal during combustion. Biomass Bioenergy 33:50–56. https://doi.org/10.1016/J.BIOMBIOE.2008.04.013
Gani A, Naruse I (2007) Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass. Renew Energy 32:649–661. https://doi.org/10.1016/j.renene.2006.02.017
Lv D, Xu M, Liu X, Zhan Z, Li Z, Yao H (2010) Effect of cellulose, lignin, alkali and alkaline earth metallic species on biomass pyrolysis and gasification. Fuel Process Technol 91:903–909. https://doi.org/10.1016/j.fuproc.2009.09.014
Sharp J (2017) Reaction kinetics in differential thermal analysis, vol II, chapter 28, 47-77, 1972, Ed. R C Mackenzie, Academic Press, London
Friedman HL (1964) Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. In: journal of polymer science: polymer symposia. Wiley online library, pp 183–195
Flynn JH, Wall LA (1966) A quick, direct method for the determination of activation energy from thermogravimetric data. J Polym Sci Part C Polym Lett 4:323–328
Ozawa T (1965) A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn 38:1881–1886
Akahira T, Sunose T (1971) Method of determining activation deterioration constant of electrical insulating materials. Res Rep Chiba Inst Technol (Sci Technol) 16:22–31
Burnham AK, Dinh LN (2007) A comparison of isoconversional and model-fitting approaches to kinetic parameter estimation and application predictions. J Therm Anal Calorim 89:479–490
Budrugeac P (2002) Differential non-linear isoconversional procedure for evaluating the activation energy of non-isothermal reactions. J Therm Anal Calorim 68:131–139
Paniagua S, Escudero L, Escapa C, Coimbra RN, Otero M, Calvo LF (2016) Effect of waste organic amendments on Populus sp biomass production and thermal characteristics. Renew Energy 94:166–174. https://doi.org/10.1016/j.renene.2016.03.019
Aenor (2018) UNE-EN ISO 18135:2018 . Biocombustibles sólidos. Muestreo
Evans A, Strezov V, Evans TJ (2010) Sustainability considerations for electricity generation from biomass. Renew Sust Energ Rev 14:1419–1427. https://doi.org/10.1016/j.rser.2010.01.010
Li XT, Grace JR, Lim CJ, Watkinson AP, Chen HP, Kim JR (2004) Biomass gasification in a circulating fluidized bed. Biomass Bioenergy 26:171–193
Liu R, Morrell JJ, Yan L (2018) Thermogravimetric analysis studies of thermally-treated glycerol impregnated poplar wood. BioResources 13:1563–1575
Özsin G, Pütün AE (2017) Insights into pyrolysis and co-pyrolysis of biomass and polystyrene: thermochemical behaviors, kinetics and evolved gas analysis. Energy Convers Manag 149:675–685 https://doi.org/10.1016/J.ENCONMAN.2017.07.059
Soria-Verdugo A, Goos E, García-Hernando N (2015) Effect of the number of TGA curves employed on the biomass pyrolysis kinetics results obtained using the distributed activation energy model. Fuel Process Technol 134:360–371. https://doi.org/10.1016/J.FUPROC.2015.02.018
Coats AW, Redfern JP (1963) Thermogravimetric analysis. A Review Analyst 88:906–924
Thengane SK, Gupta A, Mahajani SM (2019) Co-gasification of high ash biomass and high ash coal in downdraft gasifier. Bioresour Technol 273:159–168. https://doi.org/10.1016/J.BIORTECH.2018.11.007
Chen S, Meng A, Long Y, Zhou H, Li Q, Zhang Y (2015) TGA pyrolysis and gasification of combustible municipal solid waste. J Energy Inst 88:332–343. https://doi.org/10.1016/J.JOEI.2014.07.007
Kumar A, Jones DD, Hanna MA (2009) Thermochemical biomass gasification: a review of the current status of the technology. Energies 2:556–581
Cagnon B, Py X, Guillot A, Stoeckli F, Chambat G (2009) Contributions of hemicellulose, cellulose and lignin to the mass and the porous properties of chars and steam activated carbons from various lignocellulosic precursors. Bioresour Technol 100:292–298. https://doi.org/10.1016/j.biortech.2008.06.009
Yang H, Yan R, Chin T, Liang DT, Chen H, Zheng C (2004) Thermogravimetric analysis− Fourier transform infrared analysis of palm oil waste pyrolysis. Energy Fuel 18:1814–1821
Parthasarathy P, Narayanan KS, Arockiam L (2013) Study on kinetic parameters of different biomass samples using thermo-gravimetric analysis. Biomass Bioenergy 58:58–66
Xiang Y, Xiang Y, Wang L (2016) Thermal decomposition kinetic of hybrid poplar sawdust as biomass to biofuel. J Environ Chem Eng 4:3303–3308
Paniagua S, Calvo LF, Escapa C, Coimbra RN, Otero M, García AI (2017) Chlorella sorokiniana thermogravimetric analysis and combustion characteristic indexes estimation. J Therm Anal Calorim 131:3139–3149. https://doi.org/10.1007/s10973-017-6734-1
Basu P (2010) Biomass characteristics. Biomass Gasif Pyrolysis:27–63. https://doi.org/10.1016/B978-0-12-374988-8.00002-7
Liu Y, Cao X, Duan X, Wang Y, Che D (2018) Thermal analysis on combustion characteristics of predried dyeing sludge. Appl Therm Eng 140:158–165. https://doi.org/10.1016/J.APPLTHERMALENG.2018.05.055
Zhao P, Ge S, Yoshikawa K (2013) An orthogonal experimental study on solid fuel production from sewage sludge by employing steam explosion. Appl Energy 112:1213–1221. https://doi.org/10.1016/J.APENERGY.2013.02.026
Junlin X (1998) Catalyzed combustion study of study of anthracite in cement kiln. J Chin Ceram Soc 26:792–795
Lamerre J, Schwarz K-U, Langhof M et al (2015) Productivity of poplar short rotation coppice in an alley-cropping agroforestry system. Agrofor Syst:1–10. https://doi.org/10.1007/s10457-015-9825-7
Swamy SL, Mishra A, Puri S (2006) Comparison of growth, biomass and nutrient distribution in five promising clones of Populus deltoides under an agrisilviculture system. Bioresour Technol 97:57–68. https://doi.org/10.1016/j.biortech.2005.02.032
García R, Pizarro C, Lavín AG, Bueno JL (2012) Characterization of Spanish biomass wastes for energy use. Bioresour Technol 103:249–258
Puig-Arnavat M, Bruno JC, Coronas A (2010) Review and analysis of biomass gasification models. Renew Sust Energ Rev 14:2841–2851
Park Y-H, Kim J, Kim S-S, Park Y-K (2009) Pyrolysis characteristics and kinetics of oak trees using thermogravimetric analyzer and micro-tubing reactor. Bioresour Technol 100:400–405. https://doi.org/10.1016/j.biortech.2008.06.040
Gil MV, Casal D, Pevida C, Pis JJ, Rubiera F (2010) Thermal behaviour and kinetics of coal/biomass blends during co-combustion. Bioresour Technol 101:5601–5608. https://doi.org/10.1016/j.biortech.2010.02.008
Jenkins BM, Baxter LL, Miles TR, Miles TR (1998) Combustion properties of biomass. Fuel Process Technol 54:17–46. https://doi.org/10.1016/S0378-3820(97)00059-3
Miranda MT, Arranz JI, Rojas S, Montero I (2009) Energetic characterization of densified residues from Pyrenean oak forest. Fuel 88:2106–2112. https://doi.org/10.1016/J.FUEL.2009.05.015
Tortosa Masiá AA, Buhre BJP, Gupta RP, Wall TF (2007) Characterising ash of biomass and waste. Fuel Process Technol 88:1071–1081. https://doi.org/10.1016/J.FUPROC.2007.06.011
Niksa S (2019) Predicting ultimate soot yields from any coal. Proc Combust Inst 37:2757–2764. https://doi.org/10.1016/J.PROCI.2018.06.061
Jayaraman K, Kok MV, Gokalp I (2017) Thermogravimetric and mass spectrometric (TG-MS) analysis and kinetics of coal-biomass blends. Renew Energy 101:293–300. https://doi.org/10.1016/J.RENENE.2016.08.072
Chelgani SC, Hower JC, Jorjani E, Mesroghli S, Bagherieh AH (2008) Prediction of coal grindability based on petrography, proximate and ultimate analysis using multiple regression and artificial neural network models. Fuel Process Technol 89:13–20. https://doi.org/10.1016/J.FUPROC.2007.06.004
Niu D, Song Z, Xiao X (2017) Electric power substitution for coal in China: status quo and SWOT analysis. Renew Sust Energ Rev 70:610–622. https://doi.org/10.1016/j.rser.2016.12.092
Saidur R, Abdelaziz EA, Demirbas A, Hossain MS, Mekhilef S (2011) A review on biomass as a fuel for boilers. Renew Sust Energ Rev 15:2262–2289. https://doi.org/10.1016/j.rser.2011.02.015
Tillman D (2000) Biomass cofiring: the technology, the experience, the combustion consequences. Biomass Bioenergy 19:365–384. https://doi.org/10.1016/S0961-9534(00)00049-0
Lee Y, Park J, Ryu C, Gang KS, Yang W, Park YK, Jung J, Hyun S (2013) Comparison of biochar properties from biomass residues produced by slow pyrolysis at 500 °C. Bioresour Technol 148:196–201. https://doi.org/10.1016/J.BIORTECH.2013.08.135
Saeed MA, Anez NF, Andrews GE, Phylaktou HN, Gibbs BM (2017) Steam exploded pine wood burning properties with particle size dependence. Fuel 194:527–532. https://doi.org/10.1016/J.FUEL.2017.01.028
García R, Pizarro C, Lavín AG, Bueno JL (2014) Spanish biofuels heating value estimation. Part II: Proximate analysis data. Fuel 117:1139–1147. https://doi.org/10.1016/J.FUEL.2013.08.049
Guerrero M, Ruiz MP, Alzueta MU, Bilbao R, Millera A (2005) Pyrolysis of eucalyptus at different heating rates: studies of char characterization and oxidative reactivity. J Anal Appl Pyrolysis 74:307–314. https://doi.org/10.1016/J.JAAP.2004.12.008
Bouraoui Z, Jeguirim M, Guizani C, Limousy L, Dupont C, Gadiou R (2015) Thermogravimetric study on the influence of structural, textural and chemical properties of biomass chars on CO2 gasification reactivity. Energy 88:703–710. https://doi.org/10.1016/j.energy.2015.05.100
Paniagua S, Escudero L, Coimbra RN, Escapa C, Otero M, Calvo LF (2017) Effect of applying organic amendments on the pyrolytic behavior of a poplar energy crop. Waste and Biomass Valorization 9:1435–1449. https://doi.org/10.1007/s12649-017-9885-1
Parshetti GK, Quek A, Betha R, Balasubramanian R (2014) TGA–FTIR investigation of co-combustion characteristics of blends of hydrothermally carbonized oil palm biomass (EFB) and coal. Fuel Process Technol 118:228–234
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Authors would like to thank funding given by the Junta de Castilla y León (Project LE129A11).
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Paniagua, S., Prado-Guerra, A., García, A.I. et al. Bioenergy derived from an organically fertilized poplar plot: overall TGA and index estimation study for combustion, gasification, and pyrolysis processes. Biomass Conv. Bioref. 9, 749–760 (2019). https://doi.org/10.1007/s13399-019-00392-7
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DOI: https://doi.org/10.1007/s13399-019-00392-7