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Effects of Dielectric Curing Temperature on the Interfacial Reliability of Cu/Ti/PBO for FOWLP Applications

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Abstract

In this study, the effect of curing temperatures of low-temperature curable polybenzoxazole (PBO) dielectrics on the interfacial adhesion energies between the Cu redistribution layer and PBO dielectric used in advanced fan-out packaging was systematically investigated using a four-point bending test. The results revealed that the interfacial adhesion energy increased when the PBO curing temperature increased from 175 to 200 °C, whereas it decreased when the curing temperature increased from 200 to 225 °C. The increase in the interfacial adhesion energy with an increase in the PBO curing temperature from 175 to 200 °C is attributed to the polymerization of PBO. However, the decrease in the interfacial adhesion energy as the curing temperature increases to 225 °C results from thermal stress.

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References

  1. Kuo, K. H., Chiang, C.Y., Chen, K. H., Lin, T.-E., Chen, S., and Chien, F. L.: The board level reliability performance and process challenges of ultra-thin WLP (Package Height < 250 μm). In: Proceedings of the 2020 IEEE 70th Electronic Components and Technology Conference, Orlando, FL, pp. 2118–2123 (2020)

  2. Lim, T. G., David, S. W. H., Chai, T. C., and Surya, B.: 3D FOWLP integration. In: Proceedings of the 2020 IEEE 70th Electronic Components and Technology Conference, Orlando, FL, pp. 1728–1735 (2020)

  3. Takano, K., Yamada, T., Menjo, T., and Takyu, S.: High expansion tape for fan-out WLP applying a novel stress-strain curve measuring method. In: Proceedings of the 2020 IEEE 70th Electronic Components and Technology Conference, Orlando, FL, pp. 1057–1063 (2020)

  4. Nishido, K., Onozeki, H., Suzuki, N., and Nonaka, T.: Study of the die potion accuracy in the fabrication process of a die first type FO-PLP. In: Proceedings of the 2018 IEEE 20th Electronics Packaging Technology Conference, Singapore (2018)

  5. Andriani, Y., Wang, X., Liu, S., Chen, Z., and Zhang, X.: Thermomechanical and viscoelastic properties of dielectric materials used in fan-out wafer-level packaging. In: Proceedings of the 2018 IEEE 20th Electronics Packaging Technology Conference, Singapore (2018)

  6. Lee, Y.-G., McInerney, M., Joo, Y.-C., Choi, I.-S., Kim, S.E.: Copper bonding technology in heterogeneous integration. Electron. Mater. Lett. 19, 1–25 (2023)

    Google Scholar 

  7. Park, H., Seo, H., Kim, S.E.: Characteristics of copper nitride nanolayer used in 3D Cu bonding interconnects. Electron. Mater. Lett. 17, 392–398 (2021)

    Article  CAS  Google Scholar 

  8. Fang, J. -K., Fong, C. -M., Chen, J. -C., Chang, H. -H., Lu, W. -L., Yang, P., Tu, H. -J, and Huang, M. -L.: A high performance package with fine-pitch RDL quality management. In: Proceedings of the 2021 IEEE 71st Electronic Components and Technology Conference, San Diego, USA, pp. 78–83 (2021)

  9. Enomoto, T., Abe, S., Matsukawa, D., Nakamura, T., Yamazaki, N., Saito, N., Ohe, M., and Motobe, T.: Recent progress in low temperature curable photosensitive dielectric. In: Proceedings of the 2017 International Conference on Electronics Packaging, Yamagata, Japan, pp. 498–501 (2017)

  10. Fujiwara, T., Shoji, Y., Masuda, Y., Hashimoto, K., Koyama, Y., Isobe, K., Araki, H., Okuda, R., and Tomikawa, M.: Higher reliability for low-temperature curable positive-tone photo-definable dielectric materials. In: Proceedings of the 2017 IEEE 19th Electronics Packaging Technology Conference, Singapore, pp. 1–4 (2017)

  11. Singh, B., Smet, V., Lee, J., Menezes, G., Kobayashi, M., Raj, P. M., Sundaram, V., Roggeman, B., Ray, U., Radojcjc, R., and Tummala, R.: First demonstration of drop-test reliability of ultra-thin glass BGA packages directly assembled on boards for smartphone applications. In: Proceedings of the 2015 IEEE 65th Electronic Components and Technology Conference, San Diego, USA, pp. 1566–1573 (2015)

  12. Rubner, R.: Innovation via photosensitive polyimide and poly(benzoxazole) percursors-a review by inventor. J. Photopolm. Sci. Technol. 17, 685 (2004)

    Article  CAS  Google Scholar 

  13. Anzai, N., Fujita, M., and Fujii, A.: Drop test and TCT reliability of buffer coating material for WLCSP. In: Proceedings of the 2014 IEEE 64th Electronic Components and Technology Conference, Orlando, USA, pp. 829–835 (2014)

  14. Yoshida, M., Hirata, T., Fujita, M., Anzai, N., Tamura, N.: High-modulus negative photosensitive polyimide for I-line. J. Photopolym. Sci. Technol. 27, 207 (2014)

    Article  Google Scholar 

  15. Liu, Z., Ding, G., Luo, J., Lu, W., Zhao, X., Cheng, P., Wang, W.: Improved performances of AlN/polyimide hybrid film and its application in redistribution layer. Electron. Mater. Lett. 12, 679–684 (2016)

    Article  CAS  Google Scholar 

  16. Amagai, M., and Ohsumi, M.: The effect of polyimide surface morphology and chemistry on package cracking induced by interfacial delamination. In: Proceedings of the 1994 IEEE International Reliability Physics Symposium, pp. 101–107. San Jose, USA (1994)

  17. Cho, J.H., Kong, D.I., Park, C.E., Jin, M.Y.: Effect of curing temperature on the adhesion strength of polyamideimide/copper joints. J. Adhes. Sci. Technol. 12, 507 (1998)

    Article  CAS  Google Scholar 

  18. Baik, D., Lee, W., Park, Y.: Interfacial characterization of polybenzoxazole/copper system. Mol. Cryst. Liq. Cryst. 424, 265 (2004)

    Article  CAS  Google Scholar 

  19. Kim, S., Kim, Y., Moon, A., Lee, S., Kim. S. E., and Kim, S.: Surface planarization of polymeric interlayer dielectrics for FOWLP applications. In: Proceedings of the 2018 IEEE 20th Electronics Packaging Technology Conference, pp. 882–885. Singapore (2018)

  20. Russell, S.W., Rafalski, S.A., Spreitzer, R.L., Li, J., Moimpour, M., Moghadam, F., Alford, T.L.: Enhanced adhesion of copper to dielectrics via titanium and chromium additions and sacrificial reactions. Thin Solid Films 262, 154 (1995)

    Article  CAS  Google Scholar 

  21. Dauskardt, R.H., Lane, M., Ma, Q., Krishna, N.: Adhesion and debonding of multi-layer thin film structures. Eng. Frac. Mech. 61, 1 (1998)

    Article  Google Scholar 

  22. Charalambides, P.G., Lund, J., Evans, A.G., McMeeking, R.M.: A Test specimen for determining the fracture resistance of bimaterial interfaces. J. Appl. Mech. 56, 77 (1989)

    Article  Google Scholar 

  23. Oliver, W.C., Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7, 1564 (1992)

    Article  CAS  Google Scholar 

  24. Stoney, G.G.: The tension of metallic films deposited by electrolysis. Proc. R. Soc. Lond. Ser. A82, 172 (1909)

    Google Scholar 

  25. Wang, H., Liu, S., Chung, T.-S., Chen, H., Jean, Y.C., Pramoda, K.P.: The evolution of poly(hydroxyamide amic acid) to poly(benzoxazole) via stepwise thermal cyclization: structural changes and gas transport properties. Polymer 52, 5127 (2011)

    Article  CAS  Google Scholar 

  26. Christ, B.V.: Handbook of Monochromatic XPS Spectra, Polymers and Polymers Damaged by X-rays. Wiley, West Sussex (England) (2000)

    Google Scholar 

  27. Berlich, A., Flemmig, B., Wittstock, G.: Formation of polymer-modified electrodes from 2-mercaptobenzoxazole in aqueous solution. J. Solid State Electrochem. 6, 29 (2001)

    Article  CAS  Google Scholar 

  28. Shang, J., Hao, J., Deng, Q., Hang, T., and Li, M.: Interface adhesion study of cu interconnection and low-k organic materials. In: Proceedings of the 2016 IEEE 27th International Conference on Electronic Packaging Technology, pp. 686–689. Wuhan, China (2016)

  29. Kim, Y.-C., Kang, S.K., Ahn, H.J., Kim, K.-H., Kwon, D.: Calibration of contact depth for evaluating residual stress using instrumented indentation testing. Trans. KPVP 7, 41 (2011)

    Google Scholar 

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Acknowledgements

This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MEST) (Nos. 2022R1A2C1092453 and RS-2023-00239657) and the Public-private joint investment semiconductor R&D program(K-CHIPS) to foster high-quality human resources) (“RS-2023-00234159”, Routing design guided development of 3D scaling BEOL interconnect technology) funded By the Ministry of Trade, Industry & Energy (MOTIE, Korea) (1415187652). The authors would like to thank Dr. D. Kim at the Korea Institute of Materials Science for the test sample preparation.

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Kim, G., Son, K., Kim, YC. et al. Effects of Dielectric Curing Temperature on the Interfacial Reliability of Cu/Ti/PBO for FOWLP Applications. Electron. Mater. Lett. 20, 393–401 (2024). https://doi.org/10.1007/s13391-024-00485-0

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  • DOI: https://doi.org/10.1007/s13391-024-00485-0

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