Abstract
Electrocoagulation was demonstrated for the effective removal of organic dyes, waxes, and sodium silicate from batik wastewater. For the first time, the reuse of an electrocoagulated batik sludge (EBS) by converting it into an adsorbent for Acid Red 18 (AR18) dye removal is reported. The EBS sample was dried in an oven to produce the raw EBS (REBS) adsorbent, which was then calcined to remove its organic constituents to give calcined EBS (CEBS) adsorbent. Nitrogen adsorption–desorption isotherm, scanning electron microscope-energy-dispersive X-ray (SEM–EDX), and Fourier transformed infrared (FTIR) analyses were applicable to reveal the adsorbents’ physical and chemical characteristics. Effect of different preparation methods (REBS and CEBS), initial solution pH (3–9), adsorbent dosage (0.1–0.4 g/200 mL), initial concentrations (25–100 mg/L), and temperature (30–50 °C) on the adsorption of AR18 dye as well as regeneration and leaching study of the adsorbent were elucidated. The isotherm results indicated that the experimental data were best fitted to the Langmuir model with maximum adsorption capacity, qmax of 51.62 mg/g. Meanwhile, the adsorption of AR18 dye onto REBS mainly occurred through chemisorption as the kinetic data were best described by the pseudo-second-order model. REBS appeared to be a potential adsorbent for the removal of AR18 dye due to its simple preparation method, good adsorption capacity, and reusability performance.
Similar content being viewed by others
References
Dawood, S.; Sen, T.K.: Review on dye removal from its aqueous solution into alternative cost effective and non-conventional adsorbents. J Chem. Proc. Eng. 1(104), 1–11 (2014). https://doi.org/10.17303/jce.2014.105
Yaneva, Z.L.; Georgieva, N.V.: Insights into Congo red adsorption on agro-industrial materials: spectral, equilibrium, kinetic, thermodynamic, dynamic and desorption studies—a review. Int. Rev. Chem. Eng. 4, 127–146 (2012)
Iqbal, M.; Ahmad, M.Z.; Bhatti, I.A.; Qureshi, K.; Khan, A.: Cytotoxicity reduction of wastewater treated by advanced oxidation process. Chem. Int. 1(1), 53–59 (2015). https://doi.org/10.31221/osf.io/g6qw5
Zhang, W.; Lai, L.; Mei, P.; Li, Y.; Liu, Y.: Enhanced removal efficiency of acid red 18 from aqueous solution using wheat bran modified by multiple quaternary ammonium salts. Chem. Phy. Lett. 710, 193–201 (2018). https://doi.org/10.1016/j.cplett.2018.09.009
Zhang, C.; Yu, Y.; Wei, H.; Li, K.: In situ growth of cube-like AgCl on montmorillonite as an efficient photocatalyst for dye (Acid Red 18) degradation. Appl. Surf. Sci. 456, 577–585 (2018). https://doi.org/10.1016/j.apsusc.2018.06.009
Dias, N.C.; Bassin, J.P.; Sant, G.L.; Dezotti, M.: Ozonation of the dye Reactive Red 239 and biodegradation of ozonation products in a moving-bed biofilm reactor: revealing reaction products and degradation pathways. Int. Biodeter. Biodegr. 144, 104742 (2019). https://doi.org/10.1016/j.ibiod.2019.104742
Malakootian, M.; Moridi, A.: Efficiency of electro-Fenton process in removing Acid Red 18 dye from aqueous solutions. Proc. Saf. Environ. Prot. 1, 138–147 (2017). https://doi.org/10.1016/j.psep.2017.06.008
Bulgariu, L.; Escudero, L.B.; Bello, O.S.; Iqbal, M.; Nisar, J.; Adegoke, K.A.; Alakhras, F.; Kornaros, M.; Anastopoulos, I.: The utilization of leaf-based adsorbents for dyes removal: a review. J. Molec. Liq. 276, 728–747 (2019). https://doi.org/10.1016/j.molliq.2018.12.001
Sonai, G.G.; de Souza, S.M.G.U.; de Oliveira, D.; de Souza, A.A.U.: The application of textile sludge adsorbents for the removal of Reactive Red 2 dye. J. Environ. Manag. 168, 149–156 (2016). https://doi.org/10.1016/j.jenvman.2015.12.003
Kausar, A.; Iqbal, M.; Javed, A.; Aftab, K.; Nazli, Z.; Bhatti, H.N.; Nouren, S.: Dyes adsorption using clay and modified clay: a review. J. Molec. Liq. 256, 395–407 (2018). https://doi.org/10.1016/j.molliq.2018.02.034
Choong, C.E.; Ibrahim, S.; Basirun, W.J.: Mesoporous silica from batik sludge impregnated with aluminum hydroxide for the removal of bisphenol A and ibuprofen. J. Colloid Interf. Sci. 541, 12–17 (2019). https://doi.org/10.1016/j.jcis.2019.01.071
Attallah, M.F.; Ahmed, I.M.; Hamed, M.M.: Treatment of industrial wastewater containing Congo Red and Naphthol Green B using low-cost adsorbent. Environ. Sci. Pollut. Res. 20, 1106–1116 (2013). https://doi.org/10.1007/s11356-012-0947-4
Santos, S.C.R.; Vilar, V.J.P.; Boaventura, R.A.R.: Waste metal hydroxide sludge as adsorbent for a reactive dye. J. Hazard. Mater. 153, 999–1008 (2008). https://doi.org/10.1016/j.jhazmat.2007.09.050
Golder, A.K.; Samanta, A.N.; Ray, S.: Anionic reactive dye removal from aqueous solution using a new adsorbent—sludge generated in removal of heavy metal by electrocoagulation. Chem. Eng. J. 122, 107–115 (2006). https://doi.org/10.1016/j.cej.2006.06.003
Yilmaz, A.E.; Boncukcuoglu, R.; Kocakerim, M.; Karakas, İH.: Waste utilization: The removal of textile dye (Bomaplex Red CR-L) from aqueous solution on sludge waste from electrocoagulation as adsorbent. Desalination 277, 156–163 (2011). https://doi.org/10.1016/j.desal.2011.04.018
García-Gómez, C.; Rivera-Huerta, M.L.; Almazán-García, F.; Martin, A.: Electrocoagulated metal hydroxide sludge for fluoride and arsenic removal in aqueous solution: characterization, kinetic, and equilibrium studies. Water Air Soil Poll. 227(96), 1–16 (2016). https://doi.org/10.1007/s11270-016-2783-5
Golder, A.K.; Samanta, A.N.; Ray, S.: Removal of phosphate from aqueous solutions using calcined metal hydroxides sludge waste generated from electrocoagulation. Separ. Purif. Technol. 52, 102–109 (2006). https://doi.org/10.1016/j.seppur.2006.03.027
Gibson, L.T.: Mesosilica materials and organic pollutant adsorption: Part B removal from aqueous solution. Chem. Soc. Rev. 43(15), 5163–5172 (2014). https://doi.org/10.1039/c3cs60095e
Castañeda, L.F.; Coreño, O.; Nava, J.L.: Arsenic and hydrated silica removal from groundwater by electrocoagulation using an up-flow reactor in a serpentine array. J. Environ. Chem. Eng. 7(5), 103353 (2019). https://doi.org/10.1016/j.jece.2019.103353
Amri, N.; Ismail, S.; Azha, S.F.; Abdullah, A.Z.: Behaviors and mechanism of color, COD, and silica removals in the electrocoagulation of batik wastewater using waste aluminum electrodes. Int. J. Environ. Res. 15, 509–525 (2021). https://doi.org/10.1007/s41742-021-00329-x
Azha, S.F.; Shamsudin, M.S.; Shahadat, M.; Ismail, S.: Low cost zwitterionic adsorbent coating for treatment of anionic and cationic dyes. J. Ind. Eng. Chem. 67, 187–198 (2018). https://doi.org/10.1016/j.jiec.2018.06.029
Hach: Method 8185 Powder Pillows - Silicomolybdate Method. 1, 1–6, DOC316.53.01133 (2014). https://www.hach.com/silica-reagent-set-high-range-10-ml/product?id=7640191740. Accessed 12 Jan 2021
Devi, P.; Saroha, A.K.: Utilization of sludge based adsorbents for the removal of various pollutants: a review. Sci. Total Environ. 578, 16–33 (2017). https://doi.org/10.1016/j.scitotenv.2016.10.220
Langmuir, I.: The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40(9), 1361–1403 (1918). https://doi.org/10.1021/ja02242a004
Yusoff, M.M.; Yahaya, N.; Saleh, N.M.; Raoov, M.: A study on the removal of propyl, butyl, and benzyl parabens via newly synthesised ionic liquid loaded magnetically confined polymeric mesoporous adsorbent. RSC Adv. 8, 25617–25635 (2018). https://doi.org/10.1039/C8RA03408G
Freundlich, H.M.F.: Over the adsorption in solution. J. Phys. Chem. 57, 385–471 (1906)
Ayawei, N.; Ebelegi, A.N.; Wankasi, D.: Modelling and interpretation of adsorption isotherms. J. Chem. 2017, 3039817 (2017). https://doi.org/10.1155/2017/3039817
Temkin, M.J.; Pyzhev, V.: Recent modifications to Langmuir isotherms. Acta Physiochim. 12, 217–225 (1940)
Ho, Y.S.; McKay, G.: Pseudo-second order model for sorption processes. Proc. Biochem. 34, 451–465 (1999). https://doi.org/10.1016/S0032-9592(98)00112-5
Murthy, T.P.K.; Gowrishankar, B.S.; Prabha, M.N.C.; Kruthi, M.; Krishna, R.H.: Studies on batch adsorptive removal of malachite green from synthetic wastewater using acid treated coffee husk: equilibrium, kinetics and thermodynamic studies. Microchem. J. 146, 192–201 (2019). https://doi.org/10.1016/j.microc.2018.12.067
Sing, K.S.W.; Everett, D.H.: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 57(4), 603–619 (1985). https://doi.org/10.1351/pac198254112201
Souza, A.D.V.; Arruda, C.C.; Fernandes, L.: Characterization of aluminum hydroxide (Al(OH)3) for use as a porogenic agent in castable ceramics. J. Eur. Ceram. Soc. 35(2), 803–812 (2015). https://doi.org/10.1016/j.jeurceramsoc.2014.09.010
Sakthisharmila, P.; Palanisamy, P.N.; Manikandan, P.: Removal of benzidine based textile dye using different metal hydroxides generated in situ electrochemical treatment—a comparative study. J. Cleaner Prod. 172, 2206–2215 (2018). https://doi.org/10.1016/j.jclepro.2017.11.192
Darmawan, A.; Smart, S.; Julbe, A.; da Costa, J.C.D.: Iron oxide silica derived from sol-gel synthesis. Materials 4(2), 448–456 (2011). https://doi.org/10.3390/ma4020448
Takahashi, R.; Sato, S.; Sodesawa, T.; Kawakita, M.; Ogura, K.: High surface-area silica with controlled pore size prepared from nanocomposite of silica and citric acid. J. Phys. Chem. B 104(51), 12184–12191 (2000). https://doi.org/10.1021/jp002662g
Wang, L.; Yan, W.; He, C.; Wen, H.; Cai, Z.; Wang, Z.; Chen, Z.; Lui, W.: Microwave-assisted preparation of nitrogen-doped biochars by ammonium acetate activation for adsorption of acid red 18. Appl. Surf. Sci. 433, 222–231 (2018). https://doi.org/10.1016/j.apsusc.2017.10.031
Oulebsir, A.; Chaabane, T.; Zaidi, S.; Omine, K.; Alonzo, V.; Darchen, A.; Msagati, T.A.M.; Sivasankar, V.: Preparation of mesoporous alumina electro-generated by electrocoagulation in NaCl electrolyte and application in fluoride removal with consistent regenerations. Arab. J. Chem. 13(1), 271–289 (2020). https://doi.org/10.1016/j.arabjc.2017.04.007
Hashim, K.S.; Hussein, A.H.; Zubaidi, S.L.; Kot, P.; Kraidi, L.; Alkhaddar, R.; Shaw, A.; Alwash, R.: Effect of initial pH value on the removal of reactive black dye from water by electrocoagulation (EC) method. J. Phys. Conf. Series 1294, 072017 (2019). https://doi.org/10.1088/1742-6596/1294/7/072017
Mirzaei, N.; Reza, H.; Shara, K.; Velayati, A.: Modified natural zeolite using ammonium quaternary based material for Acid red 18 removal from aqueous solution. J. Environ. Chem. Eng. 5, 3151–3160 (2017). https://doi.org/10.1016/j.jece.2017.06.008
Shirmardi, M.; Mesdaghinia, A.; Mahvi, A.H.; Nasseri, S.; Nabizadeh, R.: Kinetics and equilibrium studies on adsorption of Acid Red 18 (Azo-dye) using multiwall carbon nanotubes (MWCNTs) from aqueous solution. E-J. Chem. 9(4), 2371–2383 (2012). https://doi.org/10.1155/2012/541909
Shokoohi, R.; Vatanpoor, V.; Zarrabi, M.; Vatani, A.: Adsorption of Acid Red 18 (AR18) by activated carbon from poplar wood—a kinetic and equilibrium study. E-J. Chem. 7(1), 65–72 (2010). https://doi.org/10.1155/2010/958073
Zhou, Y.; Ge, L.; Fan, N.; Xia, M.: Adsorption of Congo red from aqueous solution onto shrimp shell powder. Adsorp. Sci. Technol. 36(5–6), 1310–1330 (2018). https://doi.org/10.1177/0263617418768945
Lafi, R.; Montasser, I.; Hafiane, A.: Adsorption of congo red dye from aqueous solutions by prepared activated carbon with oxygen-containing functional groups and its regeneration. Adsorp. Sci. Technol. 37(1–2), 160–181 (2019). https://doi.org/10.1177/0263617418819227
Funding
The authors gratefully acknowledge the financial support from the Ministry of Higher Education of Malaysia for the LRGS Grant (LRGS/1/2018/USM/01/1/3) as well as Universiti Teknologi MARA (UiTM) for the postgraduate scholarship and study leave of the first author.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
Not applicable.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Amri, N., Ismail, S. & Abdullah, A.Z. Electrocoagulated Batik Sludge Adsorbent for the Adsorption of Acid Red 18 Dye in an Aqueous Solution and its Regeneration Capability. Arab J Sci Eng 48, 8705–8721 (2023). https://doi.org/10.1007/s13369-022-07316-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13369-022-07316-0