Abstract
This study focuses on utilization of clay brick waste as constituents for metakaolin-based geopolymer concrete (MK-Gpc), and the evaluation of their effect on the modulus of elasticity, shrinkage behavior and microstructure feature. To conduct this experimental study, two groups of MK-Gpc mixtures made with varying contents and forms of brick wastes were prepared, tested and compared with control mix (zero waste content). In first group, clay brick powder was substituted at doses of 10%, 15% and 20% by weight of metakaolin, while the second group consisted of waste clay brick aggregate (BA) as a partial replacement of natural coarse aggregate (NCA) by volume level of 10%, 20% and 30%. It was found that static modulus of elasticity of control mix dropped up to 47% and 56% for specimens with 20%BP and 30%BA, respectively. Test results indicated that the usage of BP increases drying shrinkage of MK-Gpc at early age and tends to decline after 28-day curing. The incorporation of 20%BA showed an adverse effect on shrinkage at all ages while the inclusion of 10% and 30%BA improved the drying shrinkage. The scanning electron microscopy (SEM) images revealed various microstructure features that include porous, microcrack structure and interface bonding zone between geopolymers and recycled waste aggregate, which represent the key factors that are having effects on the MK-Gpc properties.
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Assi, L.; Carter, K.; Deaver, E.E.; Anay, R.; Ziehl, P.: Sustainable concrete: building a greener future. J. Clean. Prod. 198, 1641–1651 (2018). https://doi.org/10.1016/j.jclepro.2018.07.123
Maddalena, R.; Roberts, J.J.; Hamilton, A.: Can Portland cement be replaced by low-carbon alternative materials? A study on the thermal properties and carbon emissions of innovative cements. J. Clean. Prod. 186, 933–942 (2018). https://doi.org/10.1016/j.jclepro.2018.02.138
Wang, B.; Yan, L.; Fu, Q.; Kasal, B.: A comprehensive review on recycled aggregate and recycled aggregate concrete. Resour. Conserv. Recycl. 171, 105565 (2021). https://doi.org/10.1016/j.resconrec.2021.105565
Xie, T.; Visintin, P.; Zhao, X.; Gravina, R.: Mix design and mechanical properties of geopolymer and alkali activated concrete: review of the state-of-the-art and the development of a new unified approach. Constr. Build. Mater. 256, 119380 (2020). https://doi.org/10.1016/j.conbuildmat.2020.119380
Mohammed, A.A.; Ahmed, H.U.; Mosavi, A.: Survey of mechanical properties of geopolymer concrete: a comprehensive review and data analysis. Materials 14(16), 4690 (2021). https://doi.org/10.3390/ma14164690
Lahoti, M.; Narang, P.; Tan, K.H.; Yang, E.H.: Mix design factors and strength prediction of metakaolin-based geopolymer. Ceram. Int. 43(14), 11433–11441 (2017). https://doi.org/10.1016/j.ceramint.2017.06.006
Ma, C.K.; Awang, A.Z.; Omar, W.: Structural and material performance of geopolymer concrete: a review. Constr. Build. Mater. 186, 90–102 (2018). https://doi.org/10.1016/j.conbuildmat.2018.07.111
Korniejenko, K.; Lin, W.T.; Šimonová, H.: Mechanical properties of short polymer fiber-reinforced geopolymer composites. J. Compos. Sci. 4(3), 128 (2020). https://doi.org/10.3390/jcs4030128
Ahmed, M.F.: Utilization of Iraqi metakaolin in special types of concrete: a review based on national researches. J. Eng. 27(8), 80–98 (2021). https://doi.org/10.31026/j.eng.2021.08.06
Marín-López, C.; Araiza, J.R.; Manzano-Ramírez, A.; Avalos, J.R.; Perez-Bueno, J.J.; Muñiz-Villareal, M.S.; Ventura-Ramos, E.; Vorobiev, Y.: Synthesis and characterization of a concrete based on metakaolin geopolymer. Inorg. Mater. 45(12), 1429–1432 (2009). https://doi.org/10.1134/S0020168509120231
Pacheco-Torgal, F.; Moura, D.; Ding, Y.; Jalali, S.: Composition, strength and workability of alkali-activated metakaolin based mortars. Constr. Build. Mater. 25(9), 3732–3745 (2011). https://doi.org/10.1016/j.conbuildmat.2011.04.017
Chen, L.; Wang, Z.; Wang, Y.; Feng, J.: Preparation and properties of alkali activated metakaolin-based geopolymer. Materials 9(9), 767 (2016). https://doi.org/10.3390/ma9090767
Risdanareni, P.; Puspitasari, P.; Santoso, E.; Adi, E.P.: Mechanical and physical properties of metakaolin based geopolymer paste. In: MATEC Web of Conferences, Vol. 101, p. 01021. EDP Sciences (2017). https://doi.org/10.1051/matecconf/201710101021
Jaya, N.A.; Yun-Ming, L.; Abdullah, M.M.; Cheng-Yong, H.; Hussin, K.: Effect of sodium hydroxide molarity on physical, mechanical and thermal conductivity of metakaolin geopolymers. In: IOP Conference Series: Materials Science and Engineering, vol. 343, no. 1, p. 012015. IOP Publishing (2018). https://doi.org/10.1088/1757-899X/343/1/012015
Wong, C.L.; Mo, K.H.; Yap, S.P.; Alengaram, U.J.; Ling, T.C.: Potential use of brick waste as alternate concrete-making materials: a review. J. Clean. Prod. 195, 226–239 (2018). https://doi.org/10.1016/j.jclepro.2018.05.193
Mahmoodi, O.; Siad, H.; Lachemi, M.; Dadsetan, S.; Sahmaran, M.: Optimization of brick waste-based geopolymer binders at ambient temperature and pre-targeted chemical parameters. J. Clean. Prod. 268, 122285 (2020). https://doi.org/10.1016/j.jclepro.2020.122285
D’Angelo, G.; Fumo, M.; Merino, M.D.; Capasso, I.; Campanile, A.; Iucolano, F.; Caputo, D.; Liguori, B.: Crushed bricks: demolition waste as a sustainable raw material for geopolymers. Sustainability 13(14), 7572 (2021). https://doi.org/10.3390/su13147572
Komnitsas, K.; Zaharaki, D.; Vlachou, A.; Bartzas, G.; Galetakis, M.: Effect of synthesis parameters on the quality of construction and demolition wastes (CDW) geopolymers. Adv. Powder Technol. 26(2), 368–376 (2015). https://doi.org/10.1016/j.apt.2014.11.012
Tuyan, M.; Andiç-Çakir, Ö.; Ramyar, K.: Effect of alkali activator concentration and curing condition on strength and microstructure of waste clay brick powder-based geopolymer. Compos. B Eng. 135, 242–252 (2018). https://doi.org/10.1016/j.compositesb.2017.10.013
Fořt, J.; Vejmelková, E.; Koňáková, D.; Alblová, N.; Čáchová, M.; Keppert, M.; Rovnaníková, P.; Černý, R.: Application of waste brick powder in alkali activated aluminosilicates: functional and environmental aspects. J. Clean. Prod. 194, 714–725 (2018). https://doi.org/10.1016/j.jclepro.2018.05.181
Rovnaník, P.; Rovnanikova, P.; Vyšvařil, M.; Grzeszczyk, S.; Janowska-Renkas, E.: Rheological properties and microstructure of binary waste red brick powder/metakaolin geopolymer. Constr. Build. Mater. 188, 924–933 (2018). https://doi.org/10.1016/j.conbuildmat.2018.08.150
Nuaklong, P.; Sata, V.; Chindaprasirt, P.: Properties of metakaolin-high calcium fly ash geopolymer concrete containing recycled aggregate from crushed concrete specimens. Constr. Build. Mater. 161, 365–373 (2018). https://doi.org/10.1016/j.conbuildmat.2017.11.152
Panizza, M.; Natali, M.; Garbin, E.; Tamburini, S.; Secco, M.: Assessment of geopolymers with Construction and Demolition Waste (CDW) aggregates as a building material. Constr. Build. Mater. 181, 119–133 (2018). https://doi.org/10.1016/j.conbuildmat.2018.06.018
dos Santos, A.C.; de Arruda, A.M.; da Silva, T.J.; Vitor, P.D.; Trautwein, L.M.: Influence of coarse aggregate on concrete’s elasticity modulus. Acta Sci. Technol. 39(1), 17–25 (2017). https://doi.org/10.4025/actascitechnol.v39i1.29873
Jacintho, A.E.; Cavaliere, I.S.; Pimentel, L.L.; Forti, N.C.: Modulus and strength of concretes with alternative materials. Materials. 13(19), 4378 (2020). https://doi.org/10.3390/ma13194378
Hashmi, A.F.; Shariq, M.; Baqi, A.: An investigation into age-dependent strength, elastic modulus and deflection of low calcium fly ash concrete for sustainable construction. Constr. Build. Mater. 283, 122772 (2021). https://doi.org/10.1016/j.conbuildmat.2021.122772
Alanazi, H.: Effect of aggregate types on the mechanical properties of traditional concrete and geopolymer concrete. Curr. Comput.-Aided Drug Des. 11(9), 1110 (2021). https://doi.org/10.3390/cryst11091110
Mastali, M.; Kinnunen, P.; Dalvand, A.; Firouz, R.M.; Illikainen, M.: Drying shrinkage in alkali-activated binders—a critical review. Constr. Build. Mater. 190, 533–550 (2018). https://doi.org/10.1016/j.conbuildmat.2018.09.125
Mushtaq, S.M.; Siddique, R.; Goyal, S.; Kaur, K.: Experimental studies and drying shrinkage prediction model for concrete containing waste foundry sand. Clean. Eng. Technol. 2, 100071 (2021). https://doi.org/10.1016/j.clet.2021.100071
Yang, T.; Zhu, H.; Zhang, Z.: Influence of fly ash on the pore structure and shrinkage characteristics of metakaolin-based geopolymer pastes and mortars. Constr. Build. Mater. 153, 284–293 (2017). https://doi.org/10.1016/j.conbuildmat.2017.05.067
Hawa, A.; Tonnayopas, D.; Prachasaree, W.: Performance evaluation and microstructure characterization of metakaolin-based geopolymer containing oil palm ash. Sci. World J. (2013). https://doi.org/10.1155/2013/857586
Si, R.; Dai, Q.; Guo, S.; Wang, J.: Mechanical property, nanopore structure and drying shrinkage of metakaolin-based geopolymer with waste glass powder. J. Clean. Prod. 242, 118502 (2020). https://doi.org/10.1016/j.jclepro.2019.118502
Sun, K.; Peng, X.; Chu, S.H.; Wang, S.; Zeng, L.; Ji, G.: Utilization of BOF steel slag aggregate in metakaolin-based geopolymer. Constr. Build. Mater. 300, 124024 (2021). https://doi.org/10.1016/j.conbuildmat.2021.124024
ASTM C618-17a: Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete. ASTM International, West Conshohocken (2017)
IS:1727-1967: Methods of test for pozzolanic materials (First Revision). Indian Standard; Sixth reprint October 1996
ASTM C311/C311M: Standard Test Methods for Sampling and Testing Fly Ash or Natural Pozzolans for Use in Portland-Cement Concrete. ASTM International, West Conshohocken (2013)
Iraqi Specification, IQ.S 45/1984: Aggregate from Natural Sources for Concrete. Central Organization for Standardization and Quality Control, Baghdad (1984)
Iraqi Specification, IQ.S 30/1981: Determination of Particle Size and Shape of Aggregates. Central Organization for Standardization and Quality Control, Baghdad (1981)
Iraqi Specification, IQ.S 31/1981: Determination of Density, Relative Density (Specific Gravity), Water Absorption and VOIDS for aggregates. Central Organization for Standardization and Quality Control, Baghdad (1981)
ASTM C494/C 494M-99a: Standard Specification for Chemical Admixtures for Concrete. ASTM International, West Conshohocken (2013)
Ahmed, M.F.; Khalil, W.I.; Frayyeh, Q.J.: Blended metakaolin and waste clay brick powder as source material in sustainable geopolymer concrete. In: ISEC 2019—10th International Structural Engineering and Construction Conference, pp. 1–6 (2019). https://doi.org/10.14455/isec.res.2019.31
Khalil, W.I.; Frayyeh, Q.J., Ahmed, M.F.: Evaluation of sustainable metakaolin-geopolymer concrete with crushed waste clay brick. In: IOP Conference Series: Materials Science and Engineering, Vol. 518, No. 2, p. 022053. IOP Publishing (2019). https://doi.org/10.1088/1757-899X/518/2/022053
ASTM C469/C496M-14: Standard Test Method for Static Modulus of Elasticity and Poisson’s Ratio of Concrete in Compression. ASTM International, West Conshohocken (2014)
ASTM C215-14: Standard Test Method for Fundamental Transverse, Longitudinal, and Torsional Resonant Frequencies of Concrete Specimens. ASTM International, West Conshohocken (2014)
Zhang, H.; Wang, Y.; Lehman, D.E.; Geng, Y.; Kuder, K.: Time-dependent drying shrinkage model for concrete with coarse and fine recycled aggregate. Cement Concr. Compos. 105, 103426 (2020). https://doi.org/10.1016/j.cemconcomp.2019.103426
Siddique, R.; Khan, M.I.: Supplementary Cementing Materials. Springer, Berlin (2011)
Hasan, Z.A.: Manufacturing and studying properties of geopolymer concrete produced by using local materials. Ph.D. dissertation. University of Technology, Iraq (2016)
Mehta, P.K.; Monteiro, P.J.: Concrete: Microstructure, Properties, and Materials. McGraw-Hill Education, New York (2014)
Bondar, D.; Lynsdale, C.J.; Milestone, N.B.; Hassani, N.; Ramezanianpour, A.A.: Engineering properties of alkali-activated natural pozzolan concrete. ACI Mater. J. 108(1), 64–72 (2011)
Debieb, F.; Kenai, S.: The use of coarse and fine crushed bricks as aggregate in concrete. Constr. Build. Mater. 22(5), 886–893 (2008). https://doi.org/10.1016/j.conbuildmat.2006.12.013
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Ahmed, M.F., Khalil, W.I. & Frayyeh, Q.J. Effect of Waste Clay Brick on the Modulus of Elasticity, Drying Shrinkage and Microstructure of Metakaolin-Based Geopolymer Concrete. Arab J Sci Eng 47, 12671–12683 (2022). https://doi.org/10.1007/s13369-022-06611-0
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DOI: https://doi.org/10.1007/s13369-022-06611-0