Abstract
Modified graphene oxide (GO) has widened the spectrum of its applications in the preparation of highly effective composite materials. This paper reports the effect and mechanism of modified butylated GO (C4H9-GO) on the mechanical properties of reinforced cement-based composites. Experimental findings showed that compared with the pristine GO/cement composite, the fluidity of 0.03 wt% C4H9-GO/cement was slightly improved while its bending strength and compressive strength were increased by 10.50% and 17.00%, respectively, after curing for 28 days. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, mercury intrusion porosimetry, and surface area analysis revealed that C4H9-GO can effectively increase the degree of hydration, promote the formation of C–S–H bonds, Aft and Afm crystals (two kinds of calcium sulfoaluminate hydration), and inhibit the generation and development of cracks and pores thus increasing the bending and compressive strengths of the C4H9-GO/cement composite. Based on the experimental and characterization findings, a suitable mechanism for the enhancement in mechanical properties of C4H9-GO/cement was proposed. This study provides useful findings for the simplified and cost-effective preparation of C4H9-GO/cement for applications in highway and bridge construction industries.
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References
He, L.; Collins, F.; Zhu, J.: Mechanical properties and microstructure of a graphene oxide-cement composite. Cem. Concr. Compos. 50, 140–147 (2015)
Du, H.; Gao, H.J.; Pang, S.D.: Improvement in concrete resistance against water and chloride ingress by adding graphene nanoplatelet. Cem. Concr. Res. 83, 114–123 (2016)
Sohail, M.G.; Alnahhal, W.; Taha, A.; Abdelaal, K.: Sustainable alternative aggregates: characterization and influence on mechanical behavior of basalt fiber reinforced concrete. Constr. Build. Mater. 255(20), 119365 (2020)
Kwon, S.; Nishiwaki, T.; Kikuta, T.; Mihashi, H.: Development of ultra-high-performance hybrid fiber- reinforced cement-based composites. ACI Mater. J. 111(3), 309–318 (2014)
Xu, S.; Liu, J.; Li, Q.: Mechanical properties and microstructure of multi-walled carbon nanotube-reinforced cement paste. Constr. Build. Mater. 76(1), 16–23 (2015)
Thomas, J.J.; Jennings, H.M.; Chen, J.J.: Influence of Nucleation seeding on the hydration mechanisms of tricalcium silicate and cement. J. Phys. Chem. C 113(11), 4327–4334 (2009)
Du, H.; Du, S.; Liu, X.: Durability performances of concrete with nano-silica. Constr. Build. Mater. 73(30), 705–712 (2014)
Nazari, A.; Riahi, S.: TiO2 nanoparticles’ effects on properties of concrete using ground granulated blast furnace slag as binder. Sci. China 54(11), 3109–3118 (2011)
Ren, J.; Lai, Y.; Gao, J.: Exploring the influence of SiO2 and TiO2 nanoparticles on the mechanical properties of concrete. Constr. Build. Mater. 175(30), 277–285 (2018)
Mohamed, M.; Saleh, A.; Mohammad, A.: Hybrid effect of carbon nanotube and nano-clay on physico-mechanical properties of cement mortar. Constr. Build. Mater. 25(1), 145–149 (2011)
Lee, C.; Wei, X.; Kysar, J.W.; Hone, J.: Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887), 385–388 (2008)
Li, X.; Wang, L.; Liu, Y.; Li, W.; Wen, H.D.: Dispersion of graphene oxide agglomerates in cement paste and its effects on electrical resistivity and flexural strength. Cem. Concr. Compos. 92, 145–154 (2018)
Shamsaei, E.; De Souza, F.B.; Yao, X.; Benhelal, E.; Akbari, A.; Duan, W.: Graphene-based nanosheets for stronger and more durable concrete: a review. Constr. Build. Mater. 183(20), 642–660 (2018)
Chuah, S.; Pan, Z.; Sanjayan, J.G.; Wang, C.M.; Duan, W.H.: Nano reinforced cement and concrete composites and new perspective from graphene oxide. Constr. Build. Mater. 73(30), 113–124 (2014)
Kang, S.S.; Lee, H.; Chung, W.: Experimental study on mechanical strength of GO-cement composites. Constr. Build. Mater. 131(30), 303–308 (2017)
Pan, Z.; He, L.; Qiu, L.; Korayem, A.H.; Li, G.; Zhu, J.W.; Collins, F.; Li, D.; Duan, W.H.; Wang, M.C.: Mechanical properties and microstructure of a graphene oxide–cement composite. Cem. Concr. Compos. 58, 140–147 (2015)
Peng, H.; Ge, Y.; Cai, C.S.; Zhang, Y.; Liu, Z.: Mechanical properties and microstructure of graphene oxide cement-based composites. Constr. Build. Mater. 194(10), 102–109 (2019)
Musso, S.; Tulliani, J.-M.; Ferro, G.; Tagliaferro, A.: Influence of carbon nanotubes structure on the mechanical behavior of cement composites. Compos. Sci. Technol. 69(11–12), 1985–1990 (2009). https://doi.org/10.1016/j.compscitech.2009.05.002
Cao, K.; Siepermann, C.P.; Ming, Y.; Waas, A.M.; Kotov, N.A.; Thouless, M.; Arruda, E.M.: Reactive aramid nanostructures as high-performance polymeric building blocks for advanced composites. Adv. Funct. Mater. 23(16), 2072–2080 (2013)
Li, H.; Xu, C.; Dong, B.; Chen, Q.; Yang, X.: Differences between their influences of TEA and TEA·HCl on the properties of cement paste. Constr. Build. Mater. 239(10), 117797 (2020)
Geng, Y.L.; Pei, M.W.; Zhao, X.: Mechanical behavior and microstructure of cement composites incorporating surface-treated multi-walled carbon nanotubes. Carbon 43(6), 1239–1245 (2005)
Subhan, S.; Muhammad, Y.; Ahmad, B.; Tong, Z.; Subhan, F.; Sahibazda, M.: Fabrication of MnO2 NPs incorporated UiO-66 for the green and efficient oxidative desulfurization and denitrogenation of fuel oils. J. Environ. Chem. Eng. 9(3), 105179 (2021)
El-Aleem, S.A.; Gawwad, H.A.; Ouda, A.S.: Preparation and characterization of one-part non-Portland cement. Ceram. Int. 42(1), 220–228 (2016)
Duan, S.; Muhammad, Y.; Li, J.; Maria, S.; Yang, H.: Enhancing effect of microalgae biodiesel incorporation on the performance of crumb Rubber/SBS modified asphalt. J. Clean. Prod. 237, 117725 (2019)
Hui, R.; Guan, C.; Hou, D.: Study on IR characteristics of carboxylic acid and their salts. J. Anshan Teach. Coll. 01, 95–98 (2001)
Shen, J.; Na, L.; Min, S.; Hu, Y.; Ye, M.: Covalent synthesis of organophilic chemically functionalized graphene sheets. J. Colloid Interface Sci. 348(2), 377–383 (2010)
Thompson, B.C.; Murray, E.; Wallace, G.G.: Graphite oxide to grapheme. Biomaterials to Bionics. Adv. Mater. 27(46), 7563–7582 (2016)
Herrera-Alonso, M.; Abdala, A.A.; McAllister, M.J.; Aksay, I.A.; Prud’homme, R.K.: Intercalation and stitching of graphite oxide with diaminoalkanes. Langmuir 23(21), 10644–10649 (2007)
Han, Y.; Yun, L.: Preparation and characterization of graphite oxide/polypyrrole composites. Carbon 45(12), 2394–2399 (2007)
Lv, S.; Ma, Y.; Qiu, C.; Sun, T.; Liu, J.; Zhou, Q.: Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites. Constr. Build. Mater. 49, 121–127 (2013)
Shang, Y.; Zhang, D.; Yang, C.; Liu, Y.; Liu, Y.: Effect of graphene oxide on the rheological properties of cement pastes. Constr. Build. Mater. 96, 20–28 (2015). https://doi.org/10.1016/j.conbuildmat.2015.07.181
Yu, P.; Kirkpatrick, R.J.; Poe, B.; Mcmillan, P.F.; Cong, X.: Structure of calcium silicate hydrate (C-S-H): near-, mid-, and far-infrared spectroscopy. J. Am. Ceram. Soc. 82(3), 742–748 (1999)
Lien, C.; Yen, M.; Lin, Y.; Chen, M.; Lin, J.: FTIR study of adsorption and surface reactions of N(CH3)(3) on TiO2. J. Phys. Chem. B 109(21), 10962–10968 (2005)
Jung, D.H.; Ko, Y.K.; Jung, H.T.: Aggregation behavior of chemically attached poly(ethylene glycol) to single-walled carbon nanotubes (SWNTs) ropes. Mater. Sci. Eng. C 24(1), 117–121 (2004)
Hu, P.; Zhao, Z.; Sun, X.; Muhammad, Y.; Li, J.; Chen, S.; Pang, C.; Liao, T.; Zhao, Z.: Construction of crystal defect sites in N-coordinated UiO-66 via mechanochemical in-situ N-doping strategy for highly selective adsorption of cationic dyes. Chem. Eng. J. 356, 329–340 (2019)
Pan, Z.; He, L.; Collins, F.; Zhu, J.; Qiu, L.: Mechanical properties and microstructure of a graphene oxide-cement composite. Cem. Concr. Compos. 50, 140–147 (2015)
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This work was supported by Guangxi Key Research and Development Project of 409 China (Guike AB17292061), Guangxi Science and Technology Department (2017GXNSFBA198185), and the National Natural Science Foundation of China (51768007).
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Zhu, Z., Zhao, Z., Muhammad, Y. et al. Preparation and Performance Evaluation of Butylated Graphene Oxide (C4H9-GO) Incorporated Modified Cement. Arab J Sci Eng 47, 3991–4002 (2022). https://doi.org/10.1007/s13369-021-05847-6
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DOI: https://doi.org/10.1007/s13369-021-05847-6