Abstract
ZnWO4 (sanmartinite) powders were produced by mechanochemical synthesis using ZnO and WO3 at 700 rpm for 25, 50 and 100 min, respectively. SEM indicated the ratio of sub-micron-sized ZnWO4 particles was raised, and particle size distribution was homogenized by increasing process time. XRD results revealed the formation of sanmartinite after 100 min milling with 700 rpm. Raman Spectroscopy confirmed the XRD results except detection of WO3 and ZnO traces. The surface area of the samples was ranged between 3.65 and 4.05 m2/g. Optical band-gap energies of the samples increased from 2.68 to 2.86 eV with further process time. Under the visible light, the highest photocatalytic efficiency for degradation of malachite green dyes was observed in sample ball milled at 700 rpm for 25 min. Samples ball milled at 700 rpm for 100 min have lower photocatalytic activity compared to samples ball milled at 700 rpm 25 and 50 min. The efficiency of photocatalytic activities changed from 45 to 83% after 120-min photocatalysis process. It is possible to claim that ZnWO4 powders are promising photocatalyst.
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Rajrana, K.; Gupta, A.; Mir, R.A.; Pandey, O.P.: Facile sono-chemical synthesis of nanocrystalline MnO2 for catalytic and capacitive applications. Physica B 564, 179–185 (2019). https://doi.org/10.1016/j.physb.2019.04.002
Sharma, J.; Gupta, A.; Pandey, O.P.: Effect of Zr doping and aging on optical and photocatalytic properties of ZnS nano powder. Ceram. Int. 45, 13671–13678 (2019). https://doi.org/10.1016/j.ceramint.2019.04.061
Dutta, D.P.; Raval, P.: Effect of transition metal ion (Cr3+, Mn2+ and Cu2+) doping on the photocatalytic properties of ZnWO4 nanoparticles. J. Photochem. Photobiol. A 357, 193–200 (2018). https://doi.org/10.1016/j.jphotochem.2018.02.026
Dodd, A.; McKinley, A.; Tsuzuki, T.; Saunders, M.: Mechanochemical synthesis of nanoparticulate ZnO–ZnWO4 powders and their photocatalytic activity. J. Eur. Ceram. Soc. 29, 139–144 (2009). https://doi.org/10.1016/j.jeurceramsoc.2008.05.027
Marschall, R.; Wang, L.: Non-metal doping of transition metal oxides for visible-light photocatalysis. Catal. Today 225, 111–135 (2014). https://doi.org/10.1016/j.cattod.2013.10.088
Li, K.; Xue, J.; Zhang, Y.; Wei, H.; Liu, Y.; Dong, C.: ZnWO4 nanorods decorated with Ag/AgBr nanoparticles as highly efficient visible-light-responsive photocatalyst for dye AR18photodegradation. Appl. Surf. Sci. 320, 1–9 (2014). https://doi.org/10.1016/j.apsusc.2014.09.060
Jin, Z.; Duan, W.; Liu, B.; Chen, X.; Yang, F.; Guo, J.: Fabrication of efficient visible light activated Cu–P25–graphene ternary composite for photocatalytic degradation of methyl blue. Appl. Surf. Sci. 356, 707–718 (2015). https://doi.org/10.1016/j.apsusc.2015.08.122
Lu, J.; Liu, M.; Zhou, S.; Zhou, X.; Yang, Y.: Electrospinning fabrication of ZnWO4 nanofibers and photocatalytic performance for organic dyes. Dyes Pigm. 136, 1–7 (2017). https://doi.org/10.1016/j.dyepig.2016.08.008
Mancheva, M.; Iordanova, R.; Dimitriev, Y.: Mechanochemical synthesis of nanocrystalline ZnWO4 at room temperature. J. Alloy. Compd. 509, 15–20 (2011). https://doi.org/10.1016/j.jallcom.2010.08.033
Lin, S.; Chen, J.; Weng, X.; Yang, L.; Chen, X.: Fabrication and photocatalysis of mesoporous ZnWO4 with PAMAM as a template. Mater. Res. Bull. 44, 1102–1105 (2009). https://doi.org/10.1016/j.materresbull.2008.10.011
Keereeta, Y.; Thongtem, S.; Thongtem, T.: Enhanced photocatalytic degradation of methylene blue by WO3/ZnWO4 composites synthesized by a combination of microwave-solvothermal method and incipient wetness procedure. Powder Technol. 284, 85–94 (2015). https://doi.org/10.1016/j.powtec.2015.06.046
Garadkar, K.M.; Ghule, L.A.; Sapnar, K.B.; Dhole, S.D.: A facile synthesis of ZnWO4 nanoparticles by microwave assisted technique and its application in photocatalysis. Mater. Res. Bull. 48, 1105–1109 (2013). https://doi.org/10.1016/j.materresbull.2012.12.002
Wang, Y.; Liping, L.; Li, G.: Solvothermal synthesis, characterization and photocatalytic performance of Zn-rich ZnWO4 nanocrystals. Appl. Surf. Sci. 393, 159–167 (2017). https://doi.org/10.1016/j.apsusc.2016.10.001
Tan, D.; Garcia, F.: Main group mechanochemistry: from curiosity to established protocols. Chem. Soc. Rev. 48(8), 2273–2292 (2019). https://doi.org/10.1039/c7cs00813a
Chen, S.J.; Zhou, J.H.; Chen, X.T.; Li, J.; Li, L.H.; Hong, J.M.; et al.: Fabrication of nanocrystalline ZnWO4 with different morphologies and sizes via hydrothermal route. Chem. Phys. Lett. 375, 185–190 (2003). https://doi.org/10.1016/S0009-2614(03)00878-9
Huang, J.; Gao, L.: One-step fabrication of ZnWO4 hollow spheres by nanoparticle aggregation and ripening in alcohol solution. J. Am. Ceram. Soc. 89–12, 3877–3880 (2006). https://doi.org/10.1111/j.1551-2916.2006.01318.x
Amouzegar, Z.; Naghizadeh, R.; Rezaie, H.R.; Ghari, M.; Aminzari, M.: Cubic ZnWO4 nano-photocatalysts synthesized by the microwave-assisted precipitation technique. Ceram. Int. 41, 1743–1747 (2015). https://doi.org/10.1016/j.ceramint.2014.09.119
Wieczorek-Ciurowa, K.; Gamrat, K.: Some aspects of mechanochemical reactions. Mater. Sci. Pol. 25(1), 219–232 (2007). http://www.materialsscience.pwr.wroc.pl/bi/vol25no1/articles/ms_2006_037.pdf
Shao, D.; Yu, M.; Lian, J.; Sawyer, S.: An ultraviolet photodetector fabricated from WO3 nanodiscs/reduced graphene oxide composite material. Nanotechnology 24, 1–5 (2013). https://doi.org/10.1088/0957-4484/24/29/295701
Huang, B.R.; Lin, T.C.; Chu, K.T.; Yang, Y.K.; Lin, J.C.: Field emission properties of zinc oxide/zinc tungstate (ZnO/ZnWO4) composite nanorods. Surf. Coat. Technol. 231, 289–292 (2013). https://doi.org/10.1016/j.surfcoat.2012.05.006
Shim, H.W.; Lim, A.H.; Lee, G.H.; Jung, H.C.; Kim, D.W.: Fabrication of core/shell ZnWO4/carbon nanorods and their Li electroactivity. Nanoscale Res. Lett. 7–9, 1–7 (2012). https://doi.org/10.1186/1556-276X-7-9
Arin, J.; Dumrongrojthanath, P.; Yayapao, O.; Phuruangrat, A.; Thongtem, S.; Thongtem, T.: Synthesis, characterization and optical activity of La-doped ZnWO4 nanorods by hydrothermal method. Superlattices Microstruct. 67, 197–206 (2014). https://doi.org/10.1016/j.spmi.2013.12.024
Manakkadu, S.: Synthesis and tribological study of selected double metal oxide nanomaterials. Annamalai University, M.S Thesis (2000). https://search.proquest.com/docview/578523960/7685CBFB2FBC4C0CPQ/1?accountid=13654
Elamin, N.; Elsanousi, A.: Synthesis of ZnO nanostructures and their photocatalytic activity. J. Appl. Ind. Sci. 1(1), 32–35 (2013). https://pdfs.semanticscholar.org/73b3/048e29cf7aeb3cc889b085b22c200ef61a83.pdf
Kumar, S.S.; Venkateswarlu, P.; Rao, V.R.; Rao, G.N.: Synthesis, characterization and optical properties of zinc oxide nanoparticles. Int. Nano Lett. 30–3, 1–6 (2013). https://doi.org/10.1186/2228-5326-3-30
Hua-Jun, Y.; Ya-Qi, C.; Fang, Y.; Yue-Hua, P.; Xiong-Wu, H.; Ding, Z.; Dong-Sheng, T.: Hydrothermal synthesis and chromic properties of hexagonal WO3 nanowires. Chin. Phys. B 20–3, 1–6 (2011). https://doi.org/10.1088/1674-1056/20/3/036103
Jiang, X.; Zhao, X.; Duan, L.; Shen, H.; Liu, H.; Hou, T.; Wang, F.: Enhanced photoluminescence and photocatalytic activity of ZnO-ZnWO4 nanocomposites synthesized by a precipitation method. Ceram. Int. 42, 15160–15165 (2016). https://doi.org/10.1016/j.ceramint.2016.05.098
Qi, K.; Cheng, B.; Yu, J.; Ho, W.: Review on the improvement of the photocatalytic and antibacterial activities of ZnO. J. Alloy. Compd. 727, 792–820 (2017). https://doi.org/10.1016/j.jallcom.2017.08.142
Atacan, K.; Guy, N.; Cakar, S.; Ozacar, M.: Efficiency of glucose oxidase immobilized on tannin modified NiFe2O4 nanoparticles on decolorization of dye in the Fenton and photo-biocatalytic processes. J. Photochem. Photobiol. A 382, 1–9 (2019). https://doi.org/10.1016/j.jphotochem.2019.111935
Teymouri, M.; Khorsandi, H.; Aghapour, A.A.; Jafari, S.J.; Maleki, R.: Electro-Fenton method for the removal of Malachite Green: effect of operational parameters. Appl. Water Sci. 10–39, 1–14 (2020). https://doi.org/10.1007/s13201-019-1123-5
Osotsi, M.I.; Macharia, D.K.; Zhu, B.; Wang, Z.; Shen, X.; Liu, Z.; Zhang, L.; Chen, Z.: Synthesis of ZnWO4−x nanorods with oxygen vacancy for efficient photocatalytic degradation of tetracycline. Progr. Nat. Sci. Mater. Int. 28, 408–415 (2017). https://doi.org/10.1016/j.pnsc.2018.01.007
Gao, B.; Fan, H.; Zhang, X.; Song, L.: Template-free hydrothermal synthesis and high photocatalytic activity of ZnWO4 nanorods. Mater. Sci. Eng., B 177, 1126–1132 (2012). https://doi.org/10.1016/j.mseb.2012.05.022
Andrade Neto, N.F.; Nunes, T.B.O.; Li, M.; Longo, E.; Movio, M.R.D.; Motta, F.V.: Influence of microwave-assisted hydrothermal treatment time on the crystallinity, morphology and optical properties of ZnWO4 nanoparticles. Photocatal. Act. Ceram. Int. 46, 1766–1774 (2020). https://doi.org/10.1016/j.ceramint.2019.09.151
Wu, Y.; Zhou, S.; He, T.; Jin, X.; Lun, L.: Photocatalytic activities of ZnWO4 and Bi@ZnWO4 nanorods. Appl. Surf. Sci. 484, 409–413 (2019). https://doi.org/10.1016/j.apsusc.2019.04.116
Zhu, J.; Liu, M.; Tang, Y.; Sun, T.; Ding, J.; Han, L.; Wang, M.: Facile photochemical synthesis of ZnWO4/Ag yolk-shell microspheres with enhanced visible-light photocatalytic activity. Mater. Lett. 190, 60–63 (2017). https://doi.org/10.1016/j.matlet.2016.12.056
Song, X.C.; Li, W.T.; Huang, W.Z.; Zhou, H.; Zheng, Y.F.; Yin, H.Y.: A novel pen heterojunction BiOBr/ZnWO4: preparation and its improved visible light photocatalytic activity. Mater. Chem. Phys. 160, 251–256 (2015). https://doi.org/10.1016/j.matchemphys.2015.04.033
Wei, L.; Zhang, H.; Chao, J.: Electrospinning of Ag/ZnWO4/WO3 composite nanofibers with high visible light photocatalytic activity. Mater. Lett. 236, 171–174 (2019). https://doi.org/10.1016/j.matlet.2018.10.088
Aslam, M.; Ismail, I.M.I.; Chandresekaran, S.; Hameed, A.: Morphology controlled bulk synthesis of disc-shaped WO3 powder and evaluation of its photocatalytic activity for the degradation of phenols. J. Hazard. Mater. 276, 120–128 (2014). https://doi.org/10.1016/j.jhazmat.2014.05.022
Hameed, A.; Aslam, M.; Ismail, I.M.I.; Chandresekaran, S.; Kadi, M.W.; Gondal, M.A.: Sunlight assisted photocatalytic mineralization of nitrophenol isomers over W6+ impregnated ZnO. Appl. Catal. B 160–161, 227–239 (2014). https://doi.org/10.1016/j.apcatb.2014.05.023
Aslam, M.; Soomro, M.T.; Ismail, I.M.I.; Salah, M.; Gondal, M.A.; Hameed, A.: Sunlight mediated removal of chlorophenols over tungsten supported ZnO: electrochemical and photocatalytic studies. J. Environ. Chem. Eng. 3(3), 1901–1911 (2015). https://doi.org/10.1016/j.jece.2015.07.004
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Altinsoy, I., Guy, N., Ozacar, M. et al. Preparation of ZnWO4 (Sanmartinite) Powder Through Mechanochemical Method for Visible Light-Induced Photocatalysis. Arab J Sci Eng 46, 463–475 (2021). https://doi.org/10.1007/s13369-020-04859-y
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DOI: https://doi.org/10.1007/s13369-020-04859-y