Abstract
This study investigated the effects of aging on the micromechanics, chemical functional groups, and rheological properties of SBS-modified asphalt, with the help of atomic force microscopy, Fourier transform infrared spectroscopy, and dynamic shear rheometry, respectively. Aging has a significant effect on the micromechanics of asphalt and its distribution, especially in the pressure aging–vessel aging process. The micromechanics are affected by the chemical functional groups directly, and the resulting changes are the outcome of the synergistic effect of the aging of base asphalt and the degradation of the SBS modifier. The micromechanics were quantitatively consistent with the rheological properties, thus indicating that the micromechanics of the asphalt surface contribute to the macro-mechanical behavior. Such a systematic approach for the characterization of the aging process of SBS-modified asphalt could provide a scientific method for improving the properties and recycling of SBS-modified asphalt.
Similar content being viewed by others
References
Wang, Y.; Sun, L.; Zhou, J.: Pavement performance evaluation of recycled styrene–butadiene–styrene-modified asphalt mixture. Int. J. Pavement Eng. 18(5), 404–413 (2017)
Huang, W.: Aging performance of SBS modified asphalt. Pet. Sci. Technol. 26(17), 2108–2114 (2008)
Zhao, Z.; Wu, S.; Liu, Q.: Investigation of the effect of layer double hydroxides on comprehensive properties of SBS-modified asphalt mixture. Mater. Res. Innov. 19(sup5), S5–764 (2015)
Zhao, X.; Wang, S.; Wang, Q.; Yao, H.: Rheological and structural evolution of SBS modified asphalts under natural weathering. Fuel 184, 242–247 (2016)
Blab, B.H.R.: Enhancing triaxial cyclic compression testing of hot mix asphalt by introducing cyclic confining pressure. Road Mater. Pavement Des. 15(1), 16–34 (2014)
Lu, X.; Isacsson, U.: Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens. Fuel 77(9–10), 961–972 (1998)
Chen, H.X.; Zhou, Y.; WANG, B.G.: Dynamic mechanics performance of aged SBS modified-asphalt. J. Chang’an Univ. (Nat. Sci. Edit.) 1, 002 (2009)
Lamontagne, J.; Dumas, P.; Mouillet, V.; Kister, J.: Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens. Fuel 80(4), 483–488 (2001)
Kim, K.W.; Burati Jr., J.L.: Use of GPC chromatograms to characterize aged asphalt cements. J. Mater. Civ. Eng. 5(1), 41–52 (1993)
Cong, P.; Luo, W.; Xu, P.; Zhao, H.: Investigation on recycling of SBS modified asphalt binders containing fresh asphalt and rejuvenating agents. Constr. Build. Mater. 91, 225–231 (2015)
Eilers, H.: The colloidal structure of asphalt. J. Phys. Chem. 53(8), 1195–1211 (1949)
Lesueur, D.: The colloidal structure of bitumen: consequences on the rheology and on the mechanisms of bitumen modification. Adv. Colloid Interface Sci. 145(1), 42–82 (2009)
Hofko, B.; Eberhardsteiner, L.; Füssl, J.; Grothe, H.; Handle, F.; Hospodka, M.; et al.: Impact of maltene and asphaltene fraction on mechanical behavior and microstructure of bitumen. Mater. Struct. 49(3), 829–841 (2016)
Handle, F.; Füssl, J.; Neudl, S.; Grossegger, D.; Eberhardsteiner, L.; Hofko, B.; et al.: The bitumen microstructure: a fluorescent approach. Mater. Struct. 49(1–2), 167–180 (2016)
Chen, J.S.; Liao, M.C.; Shiah, M.S.: Asphalt modified by styrene–butadiene–styrene triblock copolymer: morphology and model. J. Mater. Civ. Eng. 14(3), 224–229 (2002)
Kang, Y.; Song, M.; Pu, L.; Liu, T.: Rheological behaviours of epoxy asphalt binder in comparison of base asphalt binder and SBS modified asphalt binder. Constr. Build. Mater. 76, 343–350 (2015)
Sengoz, B.; Isikyakar, G.: Analysis of styrene–butadiene–styrene polymer modified bitumen using fluorescent microscopy and conventional test methods. J. Hazard. Mater. 150(2), 424–432 (2008)
Eberhardsteiner, L.; Füssl, J.; Hofko, B.; Handle, F.; Hospodka, M.; Blab, R.; et al.: Influence of asphaltene content on mechanical bitumen behavior: experimental investigation and micromechanical modeling. Mater. Struct. 48(10), 3099–3112 (2015)
Eberhardsteiner, L.; Füssl, J.; Hofko, B.; Handle, F.; Hospodka, M.; Blab, R.; et al.: Towards a microstructural model of bitumen aging behavior. Int. J. Pavement Eng. 16(10), 939–949 (2014)
Loeber, L.; Muller, G.; Morel, J.; Sutton, O.: Bitumen in colloid science: a chemical, structural and rheological approach. Fuel 77(13), 1443–1450 (1998)
Pauli, A.T.; Branthaver, J.F.; Robertson, R.E.; Grimes, W.; Eggleston, C.M.: Atomic force microscopy investigation of SHRP asphalts: heavy oil and resid compatibility and stability. Am. Chem. Soc. Div. Pet. Chem. 46(2), 104–110 (2001)
Pauli, A.T.; Grimes, R.W.; Beemer, A.G.; Turner, T.F.; Branthaver, J.F.: Morphology of asphalts, asphalt fractions and model wax-doped asphalts studied by atomic force microscopy. Int. J. Pavement Eng. 12(4), 291–309 (2011)
Das, P.K.; Kringos, N.; Wallqvist, V.; Birgisson, B.: Micromechanical investigation of phase separation in bitumen by combining atomic force microscopy with differential scanning calorimetry results. Road Mater. Pavement Des. 14(sup1), 25–37 (2013)
Soenen, H.; Besamusca, J.; Fischer, H.R.; Poulikakos, L.D.; Planche, J.P.; Das, P.K.; et al.: Laboratory investigation of bitumen based on round robin DSC and AFM tests. Mater. Struct. 47(7), 1205–1220 (2014)
Lyne, Å.L.; Wallqvist, V.; Rutland, M.W.; Claesson, P.; Birgisson, B.: Surface wrinkling: the phenomenon causing bees in bitumen. J. Mater. Sci. 48(20), 6970–6976 (2013)
Allen, R.G.; Little, D.N.; Bhasin, A.; Glover, C.J.: The effects of chemical composition on asphalt microstructure and their association to pavement performance. Int. J. Pavement Eng. 15(1), 9–22 (2014)
Li, Y.; Yang, J.; Tan, T.: Study on adhesion between asphalt binders and aggregate minerals under ambient conditions using particle-modified atomic force microscope probes. Constr. Build. Mater. 101, 159–165 (2015)
Lyne, Å.L.; Wallqvist, V.; Birgisson, B.: Adhesive surface characteristics of bitumen binders investigated by atomic force microscopy. Fuel 113, 248–256 (2013)
Yu, X.; Zaumanis, M.; Dos Santos, S.; Poulikakos, L.D.: Rheological, microscopic, and chemical characterization of the rejuvenating effect on asphalt binders. Fuel 135, 162–171 (2014)
Allen, R.G.; Little, D.N.; Bhasin, A.: Structural characterization of micromechanical properties in asphalt using atomic force microscopy. J. Mater. Civ. Eng. 24(10), 1317–1327 (2012)
Wang, P.E.Y.; Zhao, K.; Glover, C.; Chen, L.; Wen, Y.; Chong, D.; et al.: Effects of aging on the properties of asphalt at the nanoscale. Constr. Build. Mater. 80, 244–254 (2015)
Hofko, B.; Hospodka, M.; Blab, R.; Eberhardsteiner, L.; Füssl, J.; Grothe, H.; et al.: Impact of field ageing on low-temperature performance of binder and hot mix asphalt. In: ISAP Conference on Asphalt Pavements (2014)
Steiner, D.; Hofko, B.; Hospodka, M.; Handle, F.; Grothe, H.; Füssl, J.; et al.: Towards an optimised lab procedure for long-term oxidative ageing of asphalt mix specimen. Int. J. Pavement Eng. 17(6), 471–477 (2016)
Fischer, H.; et al.: Challenges While Performing AFM on Bitumen. Multi-scale Modeling and Characterization of Infrastructure Materials, pp. 89–98. Springer, Amsterdam (2013)
Nahar, S.N.; Schmets, A.J.M.; Schitter, G.; Scarpas, A.: Quantitative nanomechanical property mapping of bitumen micro-phases by peak-force atomic force microscopy. In: 12th ISAP Conference on, vol. 30. Asphalt Pavements (2014)
Das, P.K.: Ageing of asphalt mixtures: micro-scale and mixture morphology investigation. Doctoral Dissertation, KTH Royal Institute of Technology (2014)
Navarro, F.J.; Partal, P.; García-Morales, M.; Martinez-Boza, F.J.; Gallegos, C.: Bitumen modification with a low-molecular-weight reactive isocyanate-terminated polymer. Fuel 86(15), 2291–2299 (2007)
Nazzal, M.D.; Qtaish, L.A.: The use of atomic force micros-copy to evaluate warm mix asphalt. Final Report, FHWA/OH-2012/19, Microscopy (2013)
Zhang, H.; Jia, X.; Yu, J.; Xue, L.: Effect of expanded vermiculite on microstructures and aging properties of styrene–butadiene–styrene copolymer modified bitumen. Constr. Build. Mater. 40(3), 224–230 (2013)
Zhang, H.; Yu, J.; Wang, H.; Xue, L.: Investigation of microstructures and ultraviolet aging properties of organo-montmorillonite/SBS modified bitumen. Mater. Chem. Phys. 129(3), 769–776 (2011)
Hofko, B.; Alavi, M.Z.; Grothe, H.; Jones, D.; Harvey, J.: Repeatability and sensitivity of FTIR ATR spectral analysis methods for bituminous binders. Mater. Struct. 50(3), 187 (2017)
Wu, S.P.; Pang, L.; Mo, L.T.; Chen, Y.C.; Zhu, G.J.: Influence of aging on the evolution of structure, morphology and rheology of base and SBS modified bitumen. Constr. Build. Mater. 23(2), 1005–1010 (2009)
Gao, Y.; Gu, F.; Zhao, Y.: Thermal oxidative aging characterization of SBS modified asphalt. J. Wuhan Univ. Technol. 28(1), 88 (2013). Materials Science Edition
Acknowledgements
This study was mainly supported by the Natural Science Foundation of China (Grant number 51678251), the Special Fund for Science and Technology Development (Grant number 2017A010103036), the Fundamental Research Funds for the Central Universities (Grant number SCUT.2015ZZ074), the Guangzhou Municipal Science and Technology Program in China (Grant number 1563000255), the Guangdong Province science and technology plan projects (Grant number 2014B010105005). The writers also appreciate the staff and facility support from the Road Research Institution (RRI) at the South China University of Technology.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yang, Z., Zhang, X., Yu, J. et al. Effects of Aging on the Multiscale Properties of SBS-Modified Asphalt. Arab J Sci Eng 44, 4349–4358 (2019). https://doi.org/10.1007/s13369-018-3399-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13369-018-3399-4