Physical and Rheological Characteristics of Polymer Modified Bitumen with Nanosilica Particles


This study was conducted to investigate the performance characteristics of polymer modified bitumens (PMB) mixed with nanosilica (NS). PMB, PG 76 and NS were mixed with concentration of binder weight at 0, 2, 4 and 6 %. During the course of the mixing process, the binders were kept at 163 °C and blended using a shear rate of 3000rpm for 1 h. As a result, microstructure examination, effects of NS on storage stability, and physical and rheological properties were investigated. Besides that, requirement tests such as penetration, softening point, ductility, viscosity and rheological analysis, such as isochronal plot, master curves, black diagram and SHRP parameters, are also conducted. SEM result revealed that NS particles disperse well in the bituminous binder matrix and the addition of NS into PMB will enhance the viscosity and ductility. The study result also revealed that nanosilica-modified bitumen binder storage capability is dependent on NS content. Based on the dynamic shear rheometer test, the addition of NS also increased the complex modulus G* at a lower frequencies and/or high temperatures compared to PMB binder, thus increasing the rut factor, causing higher rutting resistance. In contrast, at high frequencies and/or intermediate temperatures, G* decreases leading to improved fatigue behaviour at temperatures lower than 40 °C. Overall, the findings from this study can be concluded that the addition of 6 % of nanosilica is the optimum content to improve the performance characteristics of polymer modified bitumen.

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  1. 1

    Reubush S.D.: Effects of Storage on the Linear Viscoelastic Response of Polymer-Modified Asphalt at Intermediate to High Temperatures. Virginia Polytechnic Institute and State University, Blacksburg (1999)

    Google Scholar 

  2. 2

    Isacsson U., Lu X.: Testing and appraisal of polymer modified road bitumens. Bitum. Bind. Mixes 17, 9 (2004)

    Google Scholar 

  3. 3

    Airey G.D.: Rheological properties of styrene butadiene styrene polymer modified road bitumens. Fuel 82(14), 1709–1719 (2003)

    Article  Google Scholar 

  4. 4

    Read J., Whiteoak D.: The Shell Bitumen Handbook. Thomas Telford, London (2003)

    Google Scholar 

  5. 5

    Yildirim Y.: Polymer modified asphalt binders. Constr. Build. Mater. 21(1), 66–72 (2007)

    Article  Google Scholar 

  6. 6

    Bonemazzi F., Braga V., Corrieri R., Giavarini C., Sartori F.: Characteristics of polymers and polymer-modified binders. Transp. Res. Rec. J. Transp. Res. Board 1535, 36–47 (1996)

    Article  Google Scholar 

  7. 7

    Lewandowski L.: Polymer modification of paving asphalt binders. Rubber Chem. Technol. 67(3), 447–480 (1994)

    Article  Google Scholar 

  8. 8

    Lu X., Isacsson U., Ekblad J.: Phase separation of SBS polymer modified bitumens. J. Mater. Civil Eng. 11(1), 51–57 (1999)

    Article  Google Scholar 

  9. 9

    Widyatmoko I., Elliott R.: Characteristics of elastomeric and plastomeric binders in contact with natural asphalts. Constr. Build. Mater. 22(3), 239–249 (2008)

    Article  Google Scholar 

  10. 10

    Airey G.: Styrene butadiene styrene polymer modification of road bitumens. J. Mater. Sci. 39(3), 951–959 (2004)

    Article  Google Scholar 

  11. 11

    Polacco G., Berlincioni S., Biondi D., Stastna J., Zanzotto L.: Asphalt modification with different polyethylene-based polymers. Eur. Polym. J. 41(12), 2831–2844 (2005)

    Article  Google Scholar 

  12. 12

    Fernandes M.R.S., Forte M.M.C., Leite L.F.M.: Rheological evaluation of polymer-modified asphalt binders. Mater. Res. 11(3), 381–386 (2008)

    Article  Google Scholar 

  13. 13

    Al-Hadidy A., Yi-qiu T.: Effect of styrene-butadiene-styrene on the properties of asphalt and stone-matrix-asphalt mixture. J. Mater. Civil Eng. 23(4), 504–510 (2010)

    Article  Google Scholar 

  14. 14

    Yao H., You Z., Li L., Lee C.H., Wingard D., Yap Y.K., Shi X., Goh S.W.: Rheological properties and chemical bonding of asphalt modified with nanosilica. J. Mater. Civil Eng. 25(11), 1619–1630 (2012)

    Article  Google Scholar 

  15. 15

    Wen G., Zhang Y., Zhang Y., Sun K., Fan Y.: Rheological characterization of storage-stable SBS-modified asphalts. Polym. Test. 21(3), 95–302 (2002)

    Article  Google Scholar 

  16. 16

    Lu X., Isacsson U.: Rheological characterization of styrene-butadiene-styrene copolymer modified bitumens. Constr. Build. Mater. 11(1), 23–32 (1997)

    Article  Google Scholar 

  17. 17

    Gupta R.K., Pasanovic-Zujo V., Bhattacharya S.: Shear and extensional rheology of EVA/layered silicate-nanocomposites. J. Non-Newton. Fluid Mech. 128(2), 116–125 (2005)

    Article  Google Scholar 

  18. 18

    Alexandre M., Dubois P.: Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater. Sci. Eng. 28(1), 1–63 (2000)

    Article  Google Scholar 

  19. 19

    Emerging, S.C.O., Risks, N.I.H.: Modified opinion on the appropriateness of existing methodologies to assess the potential risks associated with engineered and adventitious products of nanotechnology. European Commission European Commission DG for Health and Consumers Brussels, (2006)

  20. 20

    You Z., Mills-Beale J., Foley J.M., Roy S., Odegard G.M., Dai Q., Goh S.W.: Nanoclay-modified asphalt materials: preparation and characterization. Constr. Build. Mater. 25(2), 1072–1078 (2011)

    Article  Google Scholar 

  21. 21

    Khattak M.J., Khattab A., Rizvi H.R., Zhang P.: The impact of carbon nano-fiber modification on asphalt binder rheology. Constr. Build. Mater. 30, 257–264 (2012)

    Article  Google Scholar 

  22. 22

    Yusoff N.I.M., Breem A.A.S., Alattug H.N.M., Hamim A., Ahmad J.: The effects of moisture susceptibility and ageing conditions on nano-silica/polymer-modified asphalt mixtures. Constr. Build. Mater. 72, 139–147 (2014)

    Article  Google Scholar 

  23. 23

    Jahromi S.G., Khodaii A.: Effects of nanoclay on rheological properties of bitumen binder. Constr. Build. Mater. 23(8), 2894–2904 (2009)

    Article  Google Scholar 

  24. 24

    Markanday S.S., Stastna J., Polacco G., Filippi S., Kazatchkov I., Zanzotto L.: Rheology of bitumen modified by EVAOrganoclay nanocomposites. J. Appl. Polym. Sci. 118(1), 557–565 (2010)

    Article  Google Scholar 

  25. 25

    Santagata E., Baglieri O., Tsantilis L., Dalmazzo D.: Rheological characterization of bituminous binders modified with carbon nanotubes. Proced. Soc. Behav. Sci. 53, 546–555 (2012)

    Article  Google Scholar 

  26. 26

    Yu J., Zeng X., Wu S., Wang L., Liu G.: Preparation and properties of montmorillonite modified asphalts. Mater. Sci. Eng. 447(1), 233–238 (2007)

    Article  Google Scholar 

  27. 27

    Polacco G., Pavel K., Filippi S., Stastna J., Biondi D., Zanzotto L.: Rheological properties of asphalt/SBS/clay blends. Eur. Polym. J. 44(11), 3512–3521 (2008)

    Article  Google Scholar 

  28. 28

    Sureshkumar M.S., Filippi S., Polacco G., Kazatchkov I., Stastna J., Zanzotto L.: Internal structure and linear viscoelastic properties of EVA/asphalt nanocomposites. Eur. Polym. J. 46(4), 621–633 (2010)

    Article  Google Scholar 

  29. 29

    Goh S.W., Akin M., You Z., Shi X.: Effect of deicing solutions on the tensile strength of micro-or nano-modified asphalt mixture. Constr. Build. Mater. 25(1), 195–200 (2011)

    Article  Google Scholar 

  30. 30

    Zhang B., Xi M., Zhang D., Zhang H., Zhang B.: The effect of styrenebutadienerubber/montmorillonite modification on the characteristics and properties of asphalt. Constr. Build. Mater. 23(10), 3112–3117 (2009)

    Article  Google Scholar 

  31. 31

    Yang J., Tighe S.: A review of advances of nanotechnology in asphalt mixtures. Proced. Soc. Behav. Sci. 96, 1269–1276 (2013)

    Article  Google Scholar 

  32. 32

    Barik T., Sahu B., Swain V.: Nanosilicafrom medicine to pest control. Parasitol. Res. 103(2), 253–258 (2008)

    Article  Google Scholar 

  33. 33

    Chrissafis K., Paraskevopoulos K.M., Papageorgiou G.Z., Bikiaris D.N.: Thermal and dynamic mechanical behavior of bionanocomposites: fumed silica nanoparticles dispersed in poly (vinyl pyrrolidone), chitosan, and poly (vinyl alcohol). J. Appl. Polym. Sci. 110(3), 1739–1749 (2008)

    Article  Google Scholar 

  34. 34

    Lazzara G., Milioto S.: Dispersions of nanosilica in biocompatible copolymers. Polym. Degrad. Stab. 95(4), 610–617 (2010)

    Article  Google Scholar 

  35. 35

    Vassilev S.V., Vassileva C.G.: Methods for characterization of composition of fly ashes from coalfired power stations: a critical overview. Energy Fuels 19(3), 1084–1098 (2005)

    Article  Google Scholar 

  36. 36

    Postek M.T., Howard K.S., Johnson A.H., McMichael K.L.: Scanning Electron Microscopy: A Student’s Handbook. Ladd research industries. Inc, Burlington (1980)

    Google Scholar 

  37. 37

    Kutchko B.G., Kim A.G.: Fly ash characterization by SEMEDS. Fuel 85(17), 2537–2544 (2006)

    Article  Google Scholar 

  38. 38

    American Society for Testing and Materials. Standard test method for penetration of bituminous materials ASTM D5. Conshohocken (1997)

  39. 39

    American Society for Testing and Materials. Standard test method for softening point of bitumen (ring-and-ball apparatus) ASTM D36. Conshohocken (1995)

  40. 40

    American Society for Testing and Materials. Standard test method for ductility of bituminous materials ASTM D113. Conshohocken (1999)

  41. 41

    Al-Khateeb G.G., Al-Akhras N.M.: Properties of Portland cement-modified asphalt binder using Superpave tests. Constr. Build. Mater. 25(2), 926–932 (2011)

    Article  Google Scholar 

  42. 42

    ASTM. Standard test methods for rheological properties of non-Newtonian materials by rotational (Brookfield type) viscometer. D2196, West Conshohocken (2010b)

  43. 43

    Galooyak S.S., Dabir B., Nazarbeygi A.E., Moeini A.: Rheological properties and storage stability of bitumen/SBS/montmorillonite composites. Constr. Build. Mater. 24(3), 300–307 (2010)

    Article  Google Scholar 

  44. 44

    American Society for Testing and Materials. Standard specification for type IV polymer-modified asphalt cement for use in pavement construction ASTM D5892. Conshohocken (1996)

  45. 45

    Anderson, D.A., Christensen, D.W., Bahia, H.U., Dongre, R., Sharma, M.G., Antle, C.E., Button, J.: Binder characterisation and evaluation: physical characterisation, vol 3. In: NRC (ed.) Strategic highways research program. Technical report, SHRP-A-369. Washington, DC (1994)

  46. 46

    Petersen, J.C., Robertson, R.E., Branthaver, J.F., Harnsberger, P.M., Duvall, J.J., Kim, S.S.: Binder characterisation and evaluation, vol 1. In: NRC (ed.) Strategic highways research program. Technical report, SHRP-A-367. Washington, DC; (1994)

  47. 47

    You Z.P.: Nanomaterials in asphalt pavements. Int. J. Pavement Res. Technol. 6(3), IV–V (2013)

    Google Scholar 

  48. 48

    Whiteoak, D.; Read, J.M.: The Shell Bitumen Handbook, fifth ed. pp. 137 Thomas Telford Services Ltd, London (1999)

  49. 49

    Sengoz B., Isikyakar G.: Evaluation of the properties and microstructure of SBS and EVA polymer modified bitumen. Constr. Build. Mater. 22(9), 1897–1905 (2008)

    Article  Google Scholar 

  50. 50

    Airey G.D.: Use of black diagrams to identify inconsistencies in rheological data. Road Mater. Pavement Des. 3(4), 403–424 (2002)

    Article  Google Scholar 

  51. 51

    Santagata, E., Baglieri, O.: Experimental evaluation of modified bituminous binders for heavy duty applications. In: Proceedings of the 3rd international SIIV congress, Bari (2005)

  52. 52

    Delaporte B., Di Benedetto H., Chaverot P., Gauthier G.: Linear viscoelastic properties of bituminous materials including new products made with ultrafine particles. Road Mater. Pavement Des. 10(1), 7–38 (2009)

    Article  Google Scholar 

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Correspondence to Dhawo Ibrahim Alhamali.

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Alhamali, D.I., Wu, J., Liu, Q. et al. Physical and Rheological Characteristics of Polymer Modified Bitumen with Nanosilica Particles. Arab J Sci Eng 41, 1521–1530 (2016).

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  • Master curve
  • Nanosilica
  • Polymer
  • Bitumen