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Removal of Yellow F3R, Di Maria Brilliant Blue R and Reactive Brilliant Red M-3BE from Aqueous Solutions by a Rapid and Efficient Ultrasound-Assisted Process with a Novel Biosorbent of Cottonseed Cake: Statistical Modeling, Kinetic and Thermodynamic Studies

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Abstract

Cottonseed cake as a domestic feed and a by-product of textile industry was utilized as a novel adsorbent for the decolorization of Yellow F3R (YF3R), Di Maria Brilliant Blue R (DBBR) and Reactive Brilliant Red M-3BE (Red F3B) aqueous solutions based on a rapid and efficient process of ultrasound-assisted adsorption. This study aimed to model the effects of the five factors on decolorization efficiency by response surface methodology: temperature, initial pH, reaction time, concentrations of initial dyestuff and adsorbent. A Box–Behnken design with five factors at three levels was used to set the experimental schedule. The maximum decolorization efficiency was obtained consistently at the lowest initial pH (2), the highest reaction time (30 min) and adsorbent concentration (1.5 g/L). Analysis of variance and the best-fit multiple nonlinear regression models were cross-validated (R 2 pred) accounting for 90.03–93.94 % of variation in decolorization efficiency. The decolorization of YF3R, DBBR and Red F3B on cottonseed cake fitted well pseudo-second-order kinetic mechanism and Langmuir isotherm and it was found to be of endothermic and spontaneous nature.

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References

  1. Sayan E., Edecan M.E.: An optimization study using response surface methods on the decolorization of reactive blue 19 from aqueous solution by ultrasound. Ultrason. Sonochem 15, 530–538 (2008)

    Article  Google Scholar 

  2. Tanyildizi M.S.: Modeling of adsorption isotherms and kinetics of reactive dye from aqueous solution by peanut hull. Chem. Eng. J. 168, 1234–1240 (2011)

    Article  Google Scholar 

  3. Sayan E.: Optimization and modelling of decolorization and COD reduction of reactive dye solutions by ultrasound-assisted adsorption. Chem. Eng. J. 119, 175–181 (2006)

    Article  Google Scholar 

  4. Dincer A.R., Gunes Y., Karakaya N., Gunes E.: Coal-based bottom ash (CBBA) waste material as adsorbent for removal of textile dyestuffs from aqueous solution. J. Hazard. Mater. 141, 529–535 (2007)

    Article  Google Scholar 

  5. Yang S.S., Guo W.Q., Zhou X.J., Meng Z.H., Liu B., Ren N.Q.: Optimization of operating parameters for sludge process reduction under alternating aerobic/oxygen-limited conditions by response surface methodology. Bioresour. Technol. 102, 9843–9851 (2011)

    Article  Google Scholar 

  6. Song S., Fan J., He Z., Zhan L., Liu Z., Chen J., Xu X.: Electrochemical degradation of azo dye C.I. Reactive Red 195 by anionic oxidation on Ti/SnO2−Sb/PbO2 electrodes. Electrochim. Acta 55, 3606–3613 (2010)

    Article  Google Scholar 

  7. Sahinkaya S.: COD and color removal from synthetic textile wastewater by ultrasound assisted electro-Fenton oxidation process. J. Ind. Eng. Chem. 19, 601–605 (2013)

    Article  Google Scholar 

  8. Onat A.T., Gumusdere T.H., Guvenc A., Donmez G., Mehmetoglu U.: Decolorization of textile azo dyes by ultrasonication and microbial removal. Desalination 255, 154–158 (2010)

    Article  Google Scholar 

  9. Hamdaoui O., Chiha M., Naffrechoux E.: Ultrasound-assisted removal of malachite green from aqueous solution by dead pine needles. Ultrason. Sonochem. 15, 799–807 (2008)

    Article  Google Scholar 

  10. Gulnaz O., Kaya A., Dincer S.: The reuse of dried activated sludge for adsorption of reactive dye. J. Hazard. Mater B134, 190–196 (2006)

    Article  Google Scholar 

  11. Ozer A., Akkaya E.: Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J. Hazard. Mater. 144, 171–179 (2007)

    Article  Google Scholar 

  12. Zhou X.J., Guo W.Q., Yang S.S., Ren N.Q.: A rapid and low energy consumption method to decolorize the high concentration triphenylmethane dye wastewater: operational parameters optimization for the ultrasonic-assisted ozone oxidation process. Bioresour. Technol. 105, 40–47 (2012)

    Article  Google Scholar 

  13. Zhou X.J., Guo W.Q., Yang S.S., Zheng H.S., Ren N.Q.: Ultrasonic-assisted ozone oxidation process of triphenylmethane dye degradation: evidence for the promotion effects of ultrasonic on malachite green decolorization and degradation mechanism. Bioresour. Technol. 128, 827–830 (2013)

    Article  Google Scholar 

  14. Robinson T., McMullan G., Marchant R., Nigam P.: Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresour. Technol. 77, 247–255 (2001)

    Article  Google Scholar 

  15. Voncina B.D., Majcen-Le-Marechal A.: Reactive dye decolorization using combined ultrasound/H 2 O 2. Dyes Pigm. 59, 173–179 (2004)

    Article  Google Scholar 

  16. Demirbas E., Kobya M., Sulak M.T.: Adsorption kinetics of a basic dye from aqueous solutions onto apricot stone activated carbon. Bioresour. Technol. 99, 5368–5673 (2008)

    Article  Google Scholar 

  17. Li Y., Hsieh W.P., Mahmudov R., Wei X., Huang C.P.: Combined ultrasound and Fenton (US-Fenton) process for the treatment of ammunition wastewater. J. Hazard. Mater. 244–245, 403–411 (2013)

    Article  Google Scholar 

  18. Behnajady M.A., Modirshahla N., Shokri M., Vahid B.: Effect of operational parameters on degradation of malachite green by ultrasonic irradiation. Ultrason. Sonochem. 15, 1009–1014 (2008)

    Article  Google Scholar 

  19. Korkut O., Sayan E., Lacin O., Bayrak B.: Investigation of adsorption and ultrasound assisted desorption of lead (II) and copper (II) on local bentonite: a modelling study. Desalination 259, 243–248 (2010)

    Article  Google Scholar 

  20. Guo W.Q., Ding J., Cao G.L., Ren N.Q., Cui F.Y.: Treatability study of using low frequency ultrasonic pretreatment to augment continuous biohydrogen production. Int. J. Hydrogen Energy 36, 14180–14185 (2011)

    Article  Google Scholar 

  21. Lacin O., Bayrak B., Korkut O., Sayan E.: Modeling of adsorption and ultrasonic desorption of cadmium (II) and zinc (II) on local bentonite. J. Colloid. Interf. Sci. 292, 330–335 (2005)

    Article  Google Scholar 

  22. Hosmer D.W., Lemeshow S.: Appilied Logistic Regression, 2nd edn. Wiley, Hoboken (2000)

    Book  Google Scholar 

  23. Frank I.E., Friedman J.H.: A statistical view of some chemometrics regression tools. Technometrics 35, 109–135 (1993)

    Article  Google Scholar 

  24. McCullagh P., Nelder J.A.: Generalized Linear Model. Chapman and Hall, London (1992)

    Google Scholar 

  25. Dursun A.Y., Tepe O.: Removal of Chemazol Reactive Red 195 from aqueous solution by dehydrated beet pulp carbon. J. Hazard. Mater. 194, 303–311 (2011)

    Article  Google Scholar 

  26. Zhang H., Duan L., Zhang X.: Decolorization of methyl orange by ozonation in combination with ultrasonic irradiation. J. Hazard. Mater. B138, 53–59 (2006)

    Article  Google Scholar 

  27. Chiou M.S., Li H.Y.: Equilibrium and kinetic modeling of adsorption of reactive dye on cross-linked chitosan beads. J. Hazard. Mater. 93, 233–248 (2002)

    Article  Google Scholar 

  28. Dutta S.: Optimization of Reactive Black 5 removal by adsorption process using Box-Behnken design. Desalination Water Treat. 51, 40–42 (2013)

    Google Scholar 

  29. Jumasiah A., Chuah T.G., Gimbon J., Choong T.S.Y., Azni I.: Adsorption of basic dye onto palm kernel shell activated carbon: sorption equilibrium and kinetics studies. Desalination 186, 57–64 (2005)

    Article  Google Scholar 

  30. Al-Ghouti M., Khraisheh M.A.M., Ahmad M.N.M., Allen S.: Thermodynamic behaviour and the effect of temperature on the removal of dyes from aqueous solution using modified diatomite: a kinetic study. J. Colloid. Interf. Sci. 287, 6–13 (2005)

    Article  Google Scholar 

  31. Ozacar M., Sengil I.A.: Adsorption of reactive dyes on calcined alunite from aqueous solutions. J. Hazard. Mater. B98, 211–224 (2003)

    Article  Google Scholar 

  32. Gong R.M., Ding Y., Lie M., Yang C., Liu H.J., Sun Y.Z.: Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution. Dyes Pigm. 64, 187–192 (2005)

    Article  Google Scholar 

  33. Arami M., Limaee N.Y., Mahmoodi N.M., Tabrizi N.S.: Equilibrium and kinetics studies for the adsorption of direct and acid dyes from aqueous solution by sol meal hull. J. Hazard. Mater. 135, 171–179 (2006)

    Article  Google Scholar 

  34. Hashemian S., Misrhamsi M.: Kinetic and thermodynamic of adsorption of 2-picoline by sawdust from aqueous solution. J. Ind. Eng. Chem 18, 2010–2015 (2012)

    Article  Google Scholar 

  35. Hanafiah M.A.K.M., Ngah W.S.W., Zolkafly S.H., Teong J.C., Majid Z.A.A.: Acid Blue 25 adsorption on base treated Shorea dasyphylla sawdust: Kinetic, isotherm, thermodynamic and spectroscopic analysis. J. Environ. Sci. 24(2), 261–268 (2012)

    Article  Google Scholar 

  36. Mittal A.: Adsorption kinetics of removal of a toxic dye, Malachite Green, from wastewater by using hen feathers. J. Hazard. Mater. 133, 196–202 (2006)

    Article  Google Scholar 

  37. Wu C.H., Yu C.H.: Effects of TiO2 dosage, pH and temperature on decolorization of C.I. Reactive Red 2 in a UV/US/TiO2 system. J. Hazard. Mater. 169, 1179–1183 (2009)

    Article  Google Scholar 

  38. Cicek F., Ozer D., Ozer A., Ozer A.: Low cost removal of reactive dyes using wheat bran. J. Hazard. Mater. 146, 408–416 (2007)

    Article  Google Scholar 

  39. Ozer A., Dursun G.: Removal of methylene blue from aqueous solution by dehydrated wheat bran carbon. J. Hazard. Mater. 146, 262–269 (2007)

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Environmental Engineering, Abant Izzet Baysal University, Bolu, Turkey

    Musa Buyukada

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  1. Musa Buyukada
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Correspondence to Musa Buyukada.

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Buyukada, M. Removal of Yellow F3R, Di Maria Brilliant Blue R and Reactive Brilliant Red M-3BE from Aqueous Solutions by a Rapid and Efficient Ultrasound-Assisted Process with a Novel Biosorbent of Cottonseed Cake: Statistical Modeling, Kinetic and Thermodynamic Studies. Arab J Sci Eng 40, 2153–2168 (2015). https://doi.org/10.1007/s13369-015-1751-5

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  • DOI: https://doi.org/10.1007/s13369-015-1751-5

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