Abstract
PVC-based membranes of sulfamethoxazole diazonium resorcinol (SDR) as electroactive material with dioctylphthalate (DOP), Dioctylsebacate (DOS), o- Nitroph enyloctylether (o-NPOE) as plasticizing solvent mediators have been found to act as Ni2+ selective sensor, the best performance was obtained with the sensor having a membrane of composition plasticizer:PVC:ionophore in the ratio 200:100:5 mg. The sensor exhibits Nernstian response in the activity range 5 × 10−6 to 1.0 × 10−1 M, performs satisfactorily over a wide pH range (5–9), with a fast response time (10 s). The sensor was found to work satisfactorily in partially different internal solution concentrations and could be used over a period of 2 months. Potentiometric selectivity coefficients determined by matched potential method (MPM) indicate excellent selectivity for Ni2+ ions. The sensors could be used successfully in the estimation of nickel as an indicator electrode in potentiometric titration.
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Templeton D.: Biological Monitoring of Chemical Exposure in the Workplace. World Health Organization, Geneva (1990)
Kristiansen J., Christensen J.M., Henriksen T., Nielsen N.H., Menne T.: Determination of nickel in fingernails and forearm skin (Stratum Corneum). Anal. Chim. Acta 403, 265 (2000)
Gupta V.K., Jain A.K., Singh L.P., Khurana U.: Porphyrins as carrier in PVC based membrane potentiometric sensors for nickel (II). Anal. Chim. Acta 355, 33 (1997)
Singh L.P., Bhatnager J.M.: PVC Based Selective Sensors for Ni2+ Ions Using Carboxylated and Methylated Porphine. Sensors 3, 393 (2003)
Mousavi M.F., Alizadeh N., Shamsipur M., Zohari N.: A new PVC-based 1, 10-dibenzyl-1, 10-diaza-18-crown-6 selective electrode for detecting nickel (II) ion. Sens. Actuator B 66, 98 (2000)
Shamsipur, M.; Kazemi, S.Y.: A PVC-based dibenzodiaza-15-crown-4 membrane potentiometric sensor for Ni (II). Electroanalysis 12, 1472 (2000)
Hampton M.D., Peters C.A., Wellington L.A.: Response of poly (vinyl chloride) electrodes based on the neutral carrier 1, 4, 7, 10-tetraoxacyclododecane). Anal. Chim. Acta 194, 171 (1987)
Gupta V.K., Goyal R.N., Agarwal S., Kumar P., Bachheti N.: Nickel (II)-selective sensor based on dibenzo-18-crown-6 in PVC matrix. Talanta 71, 795 (2007)
Jain A.K., Gupta V.K., Singh R.D., Khurana U., Singh L.P.: Nickel (II)-selective sensors based on heterogeneous membranes of macrocyclic compounds. Sens. Actuators B 40, 15 (1997)
Gupta V.K., Prasad R., Kumar P., Mangla R.: New nickel(II) selective potentiometric sensor based on 5,7,12,14-tetramethyldibenzotetraazaannulene in a poly(vinyl chloride) matrix. Anal. Chim. Acta 420, 19 (2000)
Gupta V.K., Prasad R., Kumar A.: Cu (II) selective sensor based on 5, 7, 12, 14-tetramethyldibenzo [b,i]-1,4,8,11-tetraazacyclotetradecane in PVC matrix. Sensors 2, 384 (2002)
Rao, G.N.; Srivastava, S.; Srivastava, S.K.; Singh, M.: Chelating ion-exchange resin membrane sensor for nickel (II) ions. Talanta 43, 1821 (1996)
Gyrdasova, I.O.; Volkov, V.L.: J. Anal. Chem. 52, 764 (1997)
Mazloum, M.; Niassary, M.; Amini, M.K.: Pentacyclooctaaza as a neutral carrier in coated-wire ion-selective electrode for nickel (II). Sens. Actuators B 82, 259 (2002)
Shamsipur M., Poursaberi T., Karami A.R., Hosseini M., Momeni A., Alizadeh A., Yousefi M., Ganjali M.R.: Development of a new fluorimetric bulk optode membrane based on 2,5-thiophenylbis (5-tert-butyl-1, 3-benzexazole) for nickel(II) ions. Anal. Chim. Acta 501, 55 (2004)
Yari A., Azizi S., Kakanejadifard A.: An electrochemical Ni (II)-selective sensor-based on a newly synthesized dioxime derivative as a neutral ionophore. Sens. Actuators B 119, 167 (2006)
Mashhadiazadeh H., Sheikhshoaie I., Saeid-Nia S.: Nickel (II)-selective membrane potentiometric sensor using a recently synthesized Schiff base as neutral carrier. Sens. Actuators B 94, 241 (2003)
Jain, A.K.; Gupta, V.K.; Ganeshpure, P.A.; Raisoni, J,: Ni (II)-selective ion sensors of salen type Schiff base chelates. Anal. Chim. Acta 553, 177 (2005)
Kumar K.G., Poduval R., John S., Augustine P.: A PVC plasticized membrane sensor for nickel ions. Microchim. Acta 156, 283 (2007)
Buchanan B.: New coated-wire cobalt (II)-selective electrode based on the benzalkonium tetrathiocyanatocobaltate (II) ion pair. Anal. Chem 40, 517 (1968)
Lal U.S., Chattopadhyaya M.C., Dey A.K.: A Manganese (II) sensitive electrode using cation exchange resin. J. Ind. Chem. Soc. 59, 493 (1982)
Luca, C.; Pleniceanu, M.; Muresan, N.: Liquid membrane electrode for determination of nickel. Rev. Rom. Chim. 27, 1088 (1976)
Pleniceanu M., Isvoranu M., Spinu C.: Potentiometric determination of copper and nickel. J. Ind. Chem. Soc. 79, 884 (2002)
Pleniceanu M., Isvoranu M., Spinu C.: Spectrophotometric study of the binary system Ni(II)-N-[2-Thyenilmethyliden]-2-Aminothyazole and theDetermination of Ni(II). Seria Chim. 30, 9 (2001)
Reglinski, J.; Morris, S.; Stevenson, D.E.: Supporting conformational change at metal centres. Part 2: four and five coordinate geometry. Polyhedron 21, 2175 (2002)
Yamada S.: Schiff base nickel (II) complexes with coordination number exceeding four. Coord. Chem. Rev. 190, 537 (1999)
Memon S., Yilmaz M., Macromol J.: Estimation of chromium(VI) adsorption efficiency of . . . behavior of calix[6]arene ester derivative. Sci. Pure Appl. Chem. 39, 63 (2002)
Cimerman Z., Galic N., Bosner B.: The Schiff bases of salicylaldehyde and aminopyridines as highly sensitive analytical reagents. Anal. Chim. Acta 343, 145 (1997)
Gurnule W.B., Rahangadale P.K., Paliwal L.J., Kharat R.B.: Ion-exchange properties of 4-hydroxyacetophenone-biuret-formaldehyde tercopolymer. Ult. Sci. Phys. Sci. 15, 89 (2003)
Sima J., Fodran P., Hledik J., Kotocova A., Valigura D.: Inorgan. Chim. Acta 81, 143 (1984)
Belokon, Y.N.; Bespalova, N.B.; Churkina, D.T.; Cisarova, I.; Ezernitskaya, M.G.; Harutyunyan, R.S.; Hrdina, R.; Kagan, H.B.; Kocovsky, P.; Kochetkov, K.A.; Larionov, O.V.; Lyssenko, K.A.; North, M.; Polasek, M.; Peregudov, A.S.; Prisyazhnyuk, V.V.; Vyskocil, S.: Nickel(II) complexes of glycine-derived Schiff bases. J. Am. Chem. Soc. 125, 12860 (2003)
Cozzi P.G.: Metal-Salen Schiff base complexes in catalysis: practical aspects. Chem. Soc. Rev. 33, 410 (2004)
Gupta V.K., Jain A.K., Ishtaiwi Z., Langb H., Maheshwari G.: Ni2+ selective sensors based on meso-tetrakis-4-[tris-(4-allyl dimethylsilyl-phenyl)-silyl]-phenyl porphyrin and (sal) 2trien in poly (vinyl chloride) matrix. Talanta 73, 803 (2007)
Gupta V.K., Singh A.K., Pal M.K.: Ni (II) selective sensors based on Schiff bases membranes in poly(vinyl chloride). Analyt. Chim. Acta 624, 223 (2008)
Li L., Lafdi K.: Nickel modification of carbon nanotubes grown on graphite for electrochemical sensors. Sens. Actuators B Chem. 132(1), 202 (2008)
Afkhami A., Tarighat MA., Khanmohammadi H.: Simultaneous determination of Co2+, Ni2+, Cu2+ and Zn2+ ions in foodstuffs and vegetables with a new Schiff base using artificial neural networks. Talanta 77(3), 995 (2009)
Yari A., Gholivand M.B., Rahhedayat F.: Development and characterization of a new nickel (II) ion selective optode based on 2-amino-1-cyclopentene-dithiocarboxylic acid. Measurement 44(9), 1691 (2011)
Aouarram A., Riaño M.D.G., Vargas M.G., Stitou M., El Yousfi F.: A permeation liquid membrane system for determination of nickel in seawater. Talanta 71(1), 165 (2007)
Mashhadizadeh M.H., Momeni A.: Nickel (II) selective membrane potentiometric sensor using a recently synthesized mercapto compound as neutral carrier. Talanta 59(1), 47 (2003)
Takeuchi, R.M.; Santos, A.L.; Padilha, P.M.; Stradiotto, N.R.: A solid paraffin-based carbon paste electrode modified with 2-aminothiazole organofunctionalized silica for differential pulse adsorptive stripping analysis of nickel in ethanol fuel. Analyt. Chim. Acta 584(2), 295 (2007)
Mazloum M, Niassary MS, Amini M.K.: Pentacyclooctaaza as a neutral carrier in coated-wire ion-selective electrode for nickel (II). Sensors and Actuators B: Chemical 82(2–3), 259 (2002)
Mousavi M.F., Alizadeh N., Shamsipur M., Zohari N.: A new PVC-based 1, 10-dibenzyl-1, 10-diaza-18-crown-6 selective electrode for detecting nickel (II)ion. Sens. Actuat. B Chem. 66(1–3), 98 (2000)
Candir S., Narin I., Soylak M.: Ligandless cloud point extraction of Cr (III), Pb (II), Cu (II), Ni (II), Bi (III), and Cd (II) ions in environmental samples with Tween 80 and flame atomic absorption spectrometric determination. Talanta 77(1), 289 (2008)
Ghaedi M., Shokrollahi A., Ahmadi F., Rajabi H.R., Soylak M.: Cloud point e × traction for the determination of copper, nickel and cobalt ions in environmental samples by flame atomic absorption spectrometry. J. Hazard. Mater. 150(3), 533 (2008)
Chen S., Xiao M., Lu D., Wang Z.: The use of carbon nanofibers microcolumn preconcentration for inductively coupled plasma mass spectrometry determination of Mn, Co and Ni. Spectrochim. Acta Part B Atomic Spectrosc. 62(11), 1216 (2007)
Zarei K., Atabati M., Malekshabani Z.: Simultaneous spectrophotometric determination of iron, nickel and cobalt in micellar media by using direct orthogonal signal correction-partial least squares method. Analyt. Chim. Acta 556(1), 247 (2006)
Zhao S.L., Xia X.Q., Ma H.R., Xi H.J.: Spectrophotometric determination of nickel with p-acetylarsenazo. Talanta 41(8), 1353 (1994)
Mohanapriya S., Lakshminarayanan V.: Simultaneous purification and spectrophotometric determination of nickel present in as-prepared single-walled carbon nanotubes (SWCNT). Talanta 71(1), 493 (2007)
Vendramini D., Grassi V., Zagatto E.A.G.: Spectrophotometric flow-injection determination of copper and nickel in plant digests exploiting differential kinetic analysis and multi-site detection. Analyt. Chim. Acta 570(1), 124 (2006)
Magni D.M., Olivieri AC., Bonivardi A.L.: Artificial neural networks study of the catalytic reduction of resazurin: stopped-flow injection kinetic-spectrophotometric determination of Cu (II) and Ni (II). Analyt. Chim. Acta 528(2), 275 (2005)
Chamjangali M.A., Bagherian G., Azizi G.: Simultaneous determination of cobalt, nickel and palladium in micellar media using partial least square regression and direct orthogonal signal correction. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 62(1–3), 189 (2005)
Yoshikuni N., Baba T., Tsunoda N., Oguma K.: Aqueous two-phase extraction of nickel dimethylglyoximato complex and its application to spectrophotometric determination of nickel in stainless steel. Talanta 66(1), 40 (2005)
Ghaedi M.: Selective and sensitized spectrophotometric determination of trace amounts of Ni (II) ion using α-benzyl dioxime in surfactant media. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 66(2), 295 (2007)
Fakhari A.R., Khorrami A.R., Naeimi H.: Synthesis and analytical application of a novel tetradentate N2O2 Schiff base as a chromogenic reagent for determination of nickel in some natural food samples. Talanta 66(4), 813 (2005)
Shokoufi N., Shemirani F., Memarzadeh F.: Fiber optic-linear array detection spectrophotometry in combination with cloud point extraction for simultaneous preconcentration and determination of cobalt and nickel. Analyt. Chim. Acta 601(2), 204 (2007)
Patil, S.A.; Unki, S.N.; Kulkarni, A.D.; Naik, V.H.; Badami, P.S.: Co (II), Ni (II) and Cu (II) complexes with coumarin-8-yl Schiff-bases: Spectroscopic, in vitro antimicrobial, DNA cleavage and fluorescence studies. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 79(5), 1128 (2011)
Reddy K.H., Prasad N.B.L., Reddy T.S.: Analytical properties of 1-phenyl-1, 2-propanedione-2-oxime thiosemicarbazone: simultaneous spectrophotometric determination of copper (II) and nickel (II) in edible oils and seeds. Talanta 59(3), 425 (2003)
Ghasemi J., Shahabadi N., Seraji H.R.: Spectrophotometric simultaneous determination of cobalt, copper and nickel using nitroso-R-salt in alloys by partial least squares. Analyt. Chim. Acta 510(1), 121 (2004)
Öztürk, B.D.; Filik, H.; Tütem, E.; Apak, R.: Simultaneous derivative spectrophotometric determination of cobalt (II) and nickel (II) by dithizone without extraction. Talanta 53(1), 263 (2000)
Amini M.K., Isfahani T.M., Khorasani J.H., Pourhossein M.: Development of an optical chemical sensor based on 2-(5-bromo-2-pyridylazo)-5-(diethylamino) phenol in Nafion for determination of nickel ion. Talanta 63(3), 713 (2004)
Vicente S., Maniasso N., Queiroz Z.F., Zagatto E.A.G.: Spectrophotometric flow-injection determination of nickel in biological materials. Talanta 57(3), 475 (2002)
Chimpalee N., Chimpalee D., Keawpasert P., Burns D.T.: Flow injection extraction spectrophotometric determination of nickel using bis(acetylacetone)ethylenediimine. Analyt. Chim. Acta 408(1–2), 123 (2000)
Sözgen K., Tütem E.: Second derivative spectrophotometric method for simultaneous determination of cobalt, nickel and iron using 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol. Talanta 62(5), 971 (2004)
Sheng N., Cai W., Shao X.: An approach by using near-infrared diffuse reflectance spectroscopy and resin adsorption for the determination of copper, cobalt and nickel ions in dilute solution. Talanta 79(2), 339 (2009)
Liu Y., Chang X., Wang S., Guo Y., Din B., Meng S.: Solid-phase spectrophotometric determination of nickel in water and vegetable samples at sub-μg l−1 level with o-carboxylphenyldiazoaminoazobenzene loaded XAD-4. Talanta 64(1), 160 (2004)
Ebdelli R., Rouis A., Mlika R., Bonnamour I., Renault N.J., Ben Ouada H., Davenas J.: Electrochemical impedance detection of Hg2+, Ni2+ and Eu3+ ions by a new azo-calix[4]arene membrane. J. Electroanalyt. Chem. 661(1), 31 (2011)
Garrido G., Rà àfols C., Bosch E.: Isothermal titration calorimetry of Ni (II) binding to histidine and to N-2-aminoethylglycine. Talanta 84(2), 347 (2011)
Srivustuvu S.K., Gupta V.K., Juin S.: A PVC-based Benzo-15-Crown-5 membrane. Sensor for cadmium. Electroanalysis 8, 938 (1996)
Gupta V.K., Kumar P.: Cadmium (II)-selective sensors based on dibenzo-24-crown-8 in PVC matrix. Analyt. Chim. Acta 389, 205 (1999)
Gupta, V.K.; Chandra, S.; Mangla, R.: Dicyclohexano-18-crown-6 as active material in PVC matrix membrane for the fabrication of cadmium selective potentiometric sensor. Electrochim. Acta 47, 1579 (2002)
Gupta V.K., Al Khayat M., Singh A.K., Pal M.K.: Nano level detection of Cd (II) using poly (vinyl chloride) based membranes of Schiff bases. Anal. Chim. Acta 634(1), 36 (2009)
Gupta V.K., Kumar P., Mangla R.: A new Zn2+-selective sensor based on 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine in PVC matrix. Electroanalysis 12(9), 752 (2000)
Gupta, V.K.; Mangla, R.; Agarwal, S.: Pb (II) selective potentiometric sensor based on. 4-tert-butylcalix [4]arene in PVC matrix. Electroanalysis 14, 1127 (2002)
Srivastava S.K., Gupta V.K., Jain S.: Tin (II) selective PVC membrane electrode based on of Salicylaldehyde thiosemicarbazone (STSC) as an ionophore. Analyst 120, 495 (1995)
Jain A.K., Gupta V.K., Singh L.P.: A comparative study of Pb2+selective sensors based on derivatized tetrapyrazole and calix[4]arene receptors. Electrochimica Acta 51(12), 2547 (2006)
Gupta V.K.: Iron (III) Selective electrode based on S-Methyl N-(Methylcarbamoyloxy) thioacetimidate as a sensing material. J. Electrochem. Sci. 6(30), 650 (2011)
Gupta, V.K.; Goyal, R.N.; Jain, A.K.; Sharma, R.A.: Aluminium (III)-selective PVC membrane sensor based on a Schiff base complex of N, N′-bis (salicylidene)-1, 2-cyclohexanediamine. Electrochim. Acta 54, 3218 (2009)
Singh A.K., Gupta V.K., Gupta B.: Chromium(III) selective membrane sensors based on Schiff bases as chelating ionophores. Anal. Chim. Acta 585(1), 171 (2007)
Gupta V.K., Singh A.K., Al Khayat M.: Neutral carriers based polymeric membrane electrodes for selective determination of mercury (II). Analyt. Chim. Acta 590(1), 81 (2007)
Rofouei K.M., Arab P., Gupta V.K.: Multi-walled carbon nanotubes-ionic liquid-carbon paste electrode as a super selectivity sensor: Application to potentiometric monitoring of mercury ion (II). J. Hazard. Mater. 183, 402 (2010)
Srivastava, S.K.; Gupta, V.K.; Jain, S.: PVC-based 2, 2, 2-Cryptand. Anal. Chem. 68, 1272 (1996)
Gupta V.K., Goyal R.N.: An electrochemical cell configuration incorporating an ion conducting membrane separator between reference and working electrode. Int. J. Electrochem. Sci. 4(1), 156 (2009)
Pleniceanu, M.; Preda, M.; Muresan, M.; Simoiu, L.: A selective spectrofluorimetric method for the determination of aminocephalos-porins in formulations and biological fluids. Anal. Lett. 29, 1485 (1996)
Diaz, M.T.; Bakker, E.: Comparative studies of praseodymium(III) selective sensors based on newlysynthesized Schiff’s bases. Anal. Chem. 73, 5582 (2001)
Heier, P.C.; Ammann, D.; Morf, W.E.; Simon, W.; Koryta, J. (Ed.): Medical and Biological Application of Electrochemical Devices. Wiley, New York (1980)
de Los A.M., Perez A., Martin L.P., Quintana J.C., Pedram M.Y.: Influence of different plasticizers on the response of chemical sensors based on polymeric membranes for nitrate ion determination. Sens. Actuators B 89, 262 (2003)
Vogel’s, A.I.: Textbook of Practical Organic Chemistry, 5th edn., chap. 2 Longman Group, UK (1989)
Gehring P.M., Morf W.E., Welti M., Pretsch E., Simon W.: Catalysis of ion transfer by tetraphenylborates in neutral carrier-based ion-selective electrodes. Helv. Chim. Acta 73, 203 (1990)
Christian, G.D.: Analytical Chemistry, 6th edn., Chap. 6. Wiley, NJ (2003)
Kumar, K.G.; Poduval, R.; Augustine, P.; John, S.; Saraswathyamma, B.: A PVC plasticized sensor for Ni (II) ion based on a simple ethylenediamine derivative. Anal. Sci. 22, 1333 (2006)
Yari A., Azizi S., Kakanejadifard A.: An electrochemical Ni (II)-selective sensor-based on a newly synthesized dioxime derivative as a neutral ionophore. Sens. Actuators B 119, 167 (2006)
Singh AK., Singh R.: Synthesis and spectral characterization of trinuclear, oxo-centered, carboxylate-bridged, mixed-valence iron complexes with Schiff bases. J. Incl. Phenom. Macrocycl. Chem. 53, 249 (2005)
Belhamel K., Ludwig R., Benamor M.: Nickel ion-selective membrane electrodebased on new t-octylcalix[6]arene derivative. Microchim. Acta 149, 145 (2005)
Gupta V.K., Singh A.K., Pal M.K.: Ni(II) selective sensors based on Schiff bases membranes in poly(vinyl chloride). Analyt. Chim. Acta 624(2), 223 (2008)
Dietrich, B.; Viout, P.; Lehn, J.M.: Macrocyclic Chemistry, pp. 384–386. V.C.H. Weinheim, Germany (1993)
Kimura E.: Developments in functionalization of macrocyclic polyamines. Pure Appl. Chem. 61, 823 (1989)
Dietrich, B.; Viout, P.; Lehn, J.M.: Macrocyclic Chemistry, pp. 387–389. V.C.H. Weinheim, Germany (1993)
Gadzekpo V.P., Christian G.D.: Determination of selectivity coefficients of ion-selective electrodes by a matched-potential method. Analyt. Chim. Acta 164, 279 (1984)
Bakker, E.; Pretsch, E.; Bhulmann, P.: Carrier-based ion-selective electrodes and bulk optodes. General characteristics. Chem. Rev. 97, 3083 (1997)
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Elsaid, F.A.G., Hamza, S., Rizk, N. et al. Ni2+ Selective Membrane Sensors Based on Sulfamethoxazole Diazonium Resorcinol in Poly (Vinyl Chloride) (PVC) Matrix. Arab J Sci Eng 38, 1681–1689 (2013). https://doi.org/10.1007/s13369-012-0383-2
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DOI: https://doi.org/10.1007/s13369-012-0383-2