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Synthesis and Characterization of DPP-Based Conjugated Polymers via Dehydrogenative Direct Alkenylation Polycondensation

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Abstract

Two π-conjugated polymers were successfully synthesized by polycondensation via dehydrogenative direct alkenylation with Pd(II) catalyst (Pd(OAc)2) without directing groups in an atom- and step-economical and eco-friendly manner. Using the Pd(OAc)2/pyridine catalytic system, C-H activation of the C-5 position on the thiophene moiety of 3,6-di(thiophen-2'-yl)diketopyrrolopyrrole derivative was regioselective and the cross-coupled products were readily formed with trans-configuration. The optical, electrochemical, and thermal properties of the synthesized polymers were studied to investigate their potential applicability to semiconducting materials.

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Authors and Affiliations

  1. Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Busan, 46241, Korea

    Jiwon Lee, Hea Jung Park, Jung Min Joo & Do-Hoon Hwang

Authors
  1. Jiwon Lee
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  2. Hea Jung Park
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  3. Jung Min Joo
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  4. Do-Hoon Hwang
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Corresponding author

Correspondence to Do-Hoon Hwang.

Additional information

Acknowledgments: This work was supported by the National Research Foundation (NRF) grants funded by the Korea Government (MSIT) (NRF- 2017R1A2A2A05001345 and No. 2011–0030013 through GCRC-SOP).

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Lee, J., Park, H.J., Joo, J.M. et al. Synthesis and Characterization of DPP-Based Conjugated Polymers via Dehydrogenative Direct Alkenylation Polycondensation. Macromol. Res. 27, 115–118 (2019). https://doi.org/10.1007/s13233-019-7070-z

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  • DOI: https://doi.org/10.1007/s13233-019-7070-z

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