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PAN electrospun nanofibers reinforced with Ag2CO3 nanoparticles: Highly efficient visible light photocatalyst for photodegradation of organic contaminants in waste water

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Abstract

This paper presents fabrication of polyacrylonitrile (PAN) electrospun nanofibers (NFs) reinforced with Ag2CO3 nanoparticles (NPs) as highly efficient visible light photocatalyst. Preparation of the introduced NFs was accomplished by using simple, effective, high yield, and low cost process; electrospinning of Ag2CO3/PAN colloidal solution at different applied electric voltages. Photocatalytic efficiency of the introduced nanofiber mats was investigated by photodegradation of three dyes (Methyl orange, Methylene blue, and RhodamineB) under visible light irradiation. Experimental results indicated that the nanofiber mat obtained at applied electric voltage of 18 kV could show higher performance towards the photodegradation of organic contaminants. Moreover, field emission scanning electron microscopy (FE-SEM) and transmission electron microscope (TEM) analysis confirmed the confinement of Ag2CO3 NPs inside polymeric NFs, which can overcome the serious problems of photocorrosion of photocatalyst and secondary pollution. Overall, the introduced NFs can be used as efficient, low cost, and healthily safe visible light driven photocatalyst in the field of water treatment and can promote its industrial application, especially in the open water surfaces.

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References

  1. S. Kang, S. Choi, M. Kang, J. Kim, H. Kim, T. Hyeon, and Y. Sung, Adv. Mater., 20, 54 (2008).

    Article  CAS  Google Scholar 

  2. X. Zong, H. Yan, G. Wu, G. Ma, F. Wen, L. Wang, and C. Li, J. Am. Chem. Soc., 130, 7176 (2008).

    Article  CAS  Google Scholar 

  3. H. J. Donga, G. Chen, J. X. Sun, C. M. Li, Y. G. Yu, and D. H. Chen, Appl. Catal. B, 134–135, 46 (2013).

    Article  Google Scholar 

  4. Q. J. Xiang, J. G. Yu, and M. Jaroniec, Chem. Soc. Rev., 41, 782 (2012).

    Article  CAS  Google Scholar 

  5. S. Ito, K. R. Thampi, P. Comte, P. Liska, and M. Gratzel, Chem. Commun., 268 (2005).

    Google Scholar 

  6. S. J. Doh, C. Kim, S. G. Lee, S. J. Lee, and H. Kim, J. Hazard. Mater., 154, 118 (2008).

    Article  CAS  Google Scholar 

  7. G. Dai, J. Yu, and G. Liu, J. Phys. Chem. C, 116, 15519 (2012).

    Article  CAS  Google Scholar 

  8. C. Xu, Y. Liu, B. Huang, H. Li, X. Qin, X. Zhang, and Y. Dai, Appl. Surf. Sci., 257, 8732 (2011).

    Article  CAS  Google Scholar 

  9. G. P. Dai, J. G. Yu, and G. Liu, J. Phys. Chem. C, 116, 15519 (2012).

    Article  CAS  Google Scholar 

  10. C. Dong, K. L. Wu, X. W. Wei, X. Z. Li, L. Liu, T. H. Ding, J. Wang, and Y. Ye, CrystEngComm., 16, 730 (2014).

    Article  CAS  Google Scholar 

  11. Y. Song, J. Zhu, H. Xu, C. Wang, Y. Xu, H. Ji, K. Wang, Q. Zhang, and H. Li, J. Alloys Compd., 592, 258 (2014).

    Article  CAS  Google Scholar 

  12. C. Yu, G. Li, S. Kumar, K. Yang, and R. Jin, R. Adv. Mater., 26, 892 (2014).

    Article  CAS  Google Scholar 

  13. C. Feng, G. Li, P. Ren, Y. Wang, X. Huang, and D. Li, Appl. Catal. B, 158–159, 224 (2014).

    Article  Google Scholar 

  14. H. Dong, G. Chen, J. Sun, Y. Feng, C. Li, G. Xiong, and C. Lv, Dalton Trans., 43, 7282 (2014).

    Article  CAS  Google Scholar 

  15. S. Park, J. M. Lee, Y. K. Jo, I. Y. Kim, and S. J. Hwang, Dalton Trans., 43, 10566 (2014).

    Article  CAS  Google Scholar 

  16. G. Panthi, N. A. M. Barakat, K. A. Khalil, A. Yousef, K. S. Jeon, and H. Y. Kim, Ceram. Int., 39, 1469 (2013).

    Article  CAS  Google Scholar 

  17. B. Muktha, G. Madras, T. N. Guru Row, U. Scherf, and S. Patil, J. Phys. Chem. B, 111, 7994 (2007).

    Article  CAS  Google Scholar 

  18. D. Meissner, R. Memming, and B. Kastening, Chem. Phys. Lett., 96, 34 (1983).

    Article  CAS  Google Scholar 

  19. G. Panthi, N. A. M. Barakat, S. S. Al-Deyab, M. El-Newehy, D. R. Pandeya, and H. Y. Kim, J. Appl. Polym. Sci., 127, 2025 (2012).

    Article  Google Scholar 

  20. T. Uyar, A. Balan, L. Toppare, and F. Besenbacher, Polymer, 50, 475 (2009).

    Article  CAS  Google Scholar 

  21. Z. Sun, E. Zussman, A. L. Yarin, J. H. Wendorff, and A. Greiner, Adv. Mater., 15, 1929 (2003).

    Article  CAS  Google Scholar 

  22. X. Wang, B. Ding, G. Sun, M. Wang, and J. Yu, Prog. Mater. Sci., 58, 1173 (2013).

    Article  CAS  Google Scholar 

  23. H. Yu, Q. Dong, Z. Jiao, T. Wang, J. Ma, G. Lu, and Y. Bi, J. Mater. Chem. A, 2, 1668 (2014).

    Article  CAS  Google Scholar 

  24. L. Ji, A. J. Medford, and X. Zhang, Polymer, 50, 605 (2009).

    Article  CAS  Google Scholar 

  25. D. Li and Y. Xia, Adv. Mater., 16, 1151 (2004).

    Article  CAS  Google Scholar 

  26. V. Beachley and X. Wen, Mater. Sci. Eng. C, 29, 663 (2009).

    Article  CAS  Google Scholar 

  27. W. Zhang, J. Liu, and G. Wu. Carbon, 41, 2805 (2003).

    Article  CAS  Google Scholar 

  28. H. H. Yi, Q. F. Yu, X. L. Tang, P. Ning, L. P. Yang, Z. Q. Ye, and J. H. Song, Ind. Eng. Chem. Res., 50, 3960 (2011).

    Article  CAS  Google Scholar 

  29. J. F. Weaver and G. B. Hoflund, Chem. Mater., 6, 1693 (1994).

    Article  CAS  Google Scholar 

  30. C. W. Xu, Y. Y. Liu, B. B. Huang, H. Li, X. Y. Qin, X. Y. Zhang, and Y. Dai, Appl. Surf. Sci., 257, 8732 (2011).

    Article  CAS  Google Scholar 

  31. J. D. Zhuang, W. X. Dai, Q. F. Tian, Z. H. Li, L. Y. Xie, J. X. Wang, and P. Liu, Langmuir, 26, 9686 (2010).

    Article  CAS  Google Scholar 

  32. T. X. Wu, G. M. Liu, and J. C. Zhao, J. Phys. Chem. B, 102, 5845 (1998).

    Article  CAS  Google Scholar 

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Correspondence to Soo-Jin Park or Hak-Yong Kim.

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Panthi, G., Park, M., Park, SJ. et al. PAN electrospun nanofibers reinforced with Ag2CO3 nanoparticles: Highly efficient visible light photocatalyst for photodegradation of organic contaminants in waste water. Macromol. Res. 23, 149–155 (2015). https://doi.org/10.1007/s13233-015-3032-2

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  • DOI: https://doi.org/10.1007/s13233-015-3032-2

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