Abstract
Highly positively polarized anatase TiO2 nanoparticles were prepared through the strong interactions between a TiO2 surface and the phthalate oxygens of poly(ethylene phthalate) (PEP) without stabilizers or surfactants. The prepared anatase TiO2 nanoparticles were monodisperse with a mean diameter of 55 nm, as confirmed by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Surprisingly, X-ray photoelectron spectroscopy (XPS) showed that the prepared anatase TiO2 nanoparticles stabilized by PEP were more positively polarized than other nanoparticles that had been reported previously.
Similar content being viewed by others
References
S. Livraghi, A. Votta, M. C. Pagannini, and E. Giamello, Chem. Commun., 4, 498 (2005).
X. Quan, S. Yang, X. Ruan, and H. Zhao, Environ. Sci. Technol., 39, 3770 (2005).
O. K. Varghese, D. W. Gong, M. Paulose, K. G. Ong, E. C. Dickley, and C. A. Grimes, Adv. Mater., 15, 624 (2003).
Y. Kondo, H. Yoshikawa, K. Awaga, M. Murayama, T. Mori, K. Sunada, S. Bandow, and S. Iijima, Langmuir, 24, 547 (2008).
H. Alarcón, M. Hedlund, E. M. J. Johansson, H. Rensmo, A. Hagfeldt, and G. Boschloo, J. Phys. Chem. C, 111, 13267 (2007).
A. B. Kashyout, M. Soliman, and M. Fathy, Renewable Energy, 35, 2914 (2010).
K. Fan, T. Peng, B. Chai, J. Chen, and K. Dai, Electrochim. Acta, 55, 5239 (2010).
D. C. Hague and M. J. Mayo, J. Am. Ceram. Soc., 77, 1957 (1994).
P. K. Khanna, N. Singh, and S. Charan, Mater. Lett., 61, 4725 (2007).
H. Kumazuawa, H. Otsuki, and E. Sada, J. Mater. Sci. Lett., 15, 839 (1996).
Y. S. Kang, S. W. Kang, H. Kim, J. H. Kim, J. Won, C. K. Kim, and K. Char, Adv. Mater., 19, 475 (2007).
S. W. Kang, K. Char, and Y. S. Kang, Chem. Mater., 20, 1308 (2008).
S. W. Kang, J. H. Kim, K. S. Oh, J. Won, K. Char, H. S. Kim, and Y. S. Kang, J. Memb. Sci., 236, 163 (2004).
R. Patakfalvi, A. Oszkó, and I. Dékány, Colloids Surf. A: Physicochem. Eng. Asp., 220, 45 (2003).
A. A. Galuska, J. C. Uht, P. M. Adams, and J. M. Coggi, J. Vac. Sci. Technol. A, 6, 2403 (1988).
D. Gonbeau, C. Guimon, G. Pfisterguillouzo, A. Levasseur, G. Meunier, and R. Dormoy, Surf. Sci., 254, 81 (1991).
C. M. Chan, S. Trigwell, and T. Duerig, Surf. Interface Anal., 15, 349 (1990).
Author information
Authors and Affiliations
Corresponding author
Additional information
Equally contributed as the first author.
Rights and permissions
About this article
Cite this article
Chae, I.S., Hong, J. & Kang, S.W. Highly polarized anatase TiO2 nanoparticles by poly(ethylene phthalate). Macromol. Res. 19, 948–950 (2011). https://doi.org/10.1007/s13233-011-0916-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13233-011-0916-7