Abstract
The synthesis of water dispersible phosphor materials is important due to the possibility of their applications in sensors, bioimaging, magnetic resonance imaging (MRI), etc. Surfactants are in use for the controlled size synthesis of nanomaterials as well as for tuning the dispersibility of colloidal particles in different solvents. In this study, we exploited cetrimonium bromide (CTAB) with pre-added lanthanide ions or with “so called modified counterions” for the synthesis of water dispersible phosphor materials. Colloidal GdF3:Ce3+(5%), Eu3+(x%) (where x is 1, 3, 5 and 7% Eu+3) and GdF3:Ce3+(5%), Eu3+(5%)/SiO2 phosphor nanocomposites were synthesized. Initially, cationic CTAB system was altered by pre-adding selected lanthanides required for synthesizing phosphors as well as silica–phosphor nanocomposite. Later, the same modified CTABs were used for single step synthesis of nanoparticles as well as nanocomposites. The elemental and structural characterizations were performed using x-ray photoelectron spectroscopy (XPS), and powder x-ray diffraction (XRD) techniques. The size and morphology of the samples were checked using a transmission electron microscope (TEM). The photoluminescence (PL) properties were explored using a spectrofluorometer, and the results established the formation of phosphor nanocomposite. The method expanded the possibilities of size and shape control in for phosphor materials. Furthermore, the study offered a way to decrease the use of lanthanide while keeping the phosphor’s overall properties intact. The results shown that this study can pave an alternate way for the synthesis of nano-sized structures of GdF3: Ce3+(5%) Eu3+(x%) and also for size and shape control in GdF3: Ce3+(5%) Eu3+(x%)/SiO2 type nanocomposites.
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References
Bedekar V, Dutta DP, Mohapatra M, Godbole S, Ghildiyal R, Tyagi A (2009) Rare-earth doped gadolinia based phosphors for potential multicolor and white light emitting deep UV LEDs. Nanotech 20(12):125707. https://doi.org/10.1088/0957-4484/20/12/125707/meta
Blasse G, Grabmaier B (1994) A general introduction to luminescent materials. In: Luminescent materials. Springer, Berlin, pp 1–9
Boulon G (2012) Fifty years of advances in solid-state laser materials. Opt Mater 34(3):499–512. https://doi.org/10.1016/j.optmat.2011.04.018
Brown P, Bushmelev A, Butts CP, Cheng J, Eastoe J, Grillo I, Heenan RK, Schmidt AM (2012) Magnetic control over liquid surface properties with responsive surfactants. Angew Chem 124(10):2464–2466
Evanics F, Diamente P, Van Veggel F, Stanisz G, Prosser R (2006) Water-soluble GdF3 and GdF3/LaF3 nanoparticles physical characterization and NMR relaxation properties. Chem Mater 18(10):2499–2505. https://doi.org/10.1021/cm052299w
Guan H, Sheng Y, Xu C, Dai Y, Xie X, Zou H (2016) Energy transfer and tunable multicolor emission and paramagnetic properties of GdF 3: Dy 3+, Tb 3+, Eu 3+ phosphors. Phys Chem Chem Phys 18(29):19807–19819. https://doi.org/10.1039/C6CP03989H
Gui W, Liu S (2018) The GdF3 phosphors with enhanced multicolor luminescence via multi-channel excitation and energy migration procedure. Mater Res Bull 100:161–170. https://doi.org/10.1016/j.materresbull.2017.12.024
Han Y, Li H, Wang Y, Pan Y, Huang L, Song F, Huang W (2017) Upconversion modulation through pulsed laser excitation for anti-counterfeiting. Sci Rep 7(1):1320. https://doi.org/10.1038/s41598-017-01611-9
Hondow N, Harowfield J, Koutsantonis G, Nealon G, Saunders M (2012) Metallosurfactants in the preparation of mesoporous silicas. Microporous Mesoporous Mater 151:264–270. https://doi.org/10.1016/j.micromeso.2011.10.027
Huang X (2016) Realizing efficient upconversion and down-shifting dual-mode luminescence in lanthanide-doped NaGdF4 core–shell–shell nanoparticles through gadolinium sublattice-mediated energy migration. Dyes Pigm 130:99–105. https://doi.org/10.1016/j.dyepig.2016.03.015
Jiang K, Wang Y, Gao X, Cai C, Lin H (2018) Facile, Quick, and gram-scale synthesis of ultralong-lifetime room-temperature-phosphorescent carbon dots by microwave irradiation. Angew Chem 57(21):6216–6220. https://doi.org/10.1002/anie.201802441
Johnson NJ, Oakden W, Stanisz GJ, Scott Prosser R, van Veggel FC (2011) Size-tunable, ultrasmall NaGdF4 nanoparticles: insights into their T1 MRI contrast enhancement. Chem Mater 23(16):3714–3722. https://doi.org/10.1021/cm201297x
Karbowiak M, Mech A, Bednarkiewicz A, Stręk W, Kępiński L (2005) Comparison of different NaGdF4: Eu3+ synthesis routes and their influence on its structural and luminescent properties. J Phys Chem Solids 66(6):1008–1019. https://doi.org/10.1016/j.jpcs.2005.01.002
Khan LU, da Silva GH, de Medeiros AMZ, Khan ZU, Gidlund M, Brito HF, Moscoso-Londoño O, Muraca D, Knobel M, Pérez CA, Martinez DST (2019) Fe3O4@SiO2 nanoparticles concurrently coated with chitosan and GdOF:Ce3+, Tb3+ Luminophore for bioimaging: toxicity evaluation in the zebrafish model. ACS Appl Nano Mater. https://doi.org/10.1021/acsanm.9b00339
Kulpinski P, Namyslak M, Grzyb T, Lis S (2012) Luminescent cellulose fibers activated by Eu 3+-doped nanoparticles. Cellulose 19(4):1271–1278. https://doi.org/10.1007/s10570-012-9709-1
Kumar P, Singh S, Gupta BK (2016) Future prospects of luminescent nanomaterial based security inks: from synthesis to anti-counterfeiting applications. Nanoscale 8(30):14297–14340. https://doi.org/10.1039/C5NR06965C
Lecoq P, Schussler M, Schneegans M (1992) Progress and prospects in the development of new scintillators for future high energy physics experiments. Nucl Instrum Methods Phys Res B 315(1–3):337–343. https://doi.org/10.1016/0168-9002(92)90725-J
Li M, Zeng L, Chen Y, Zhuang L, Wang X, Shen H (2013) Realization of colored multicrystalline silicon solar cells with SiO2/SiNX: H double layer antireflection coatings. Int J Photoenergy 2013:352473. https://doi.org/10.1155/2013/352473
Liu C, Gao Z, Zeng J, Hou Y, Fang F, Li Y, Qiao R, Shen L, Lei H, Yang W, Gao M (2013) Magnetic/upconversion fluorescent NaGdF4:Yb, Er nanoparticle-based dual-modal molecular probes for imaging tiny tumors in vivo. ACS Nano 7(8):7227–7240. https://doi.org/10.1021/nn4030898
Nikolić M, Al-Juboori A, Đorđević V, Dramićanin M (2013) Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors. Phys Scr 2013(T157):014056
Raiser D, Deville JP (1991) Study of XPS photoemission of some gadolinium compounds. J Electron Spectrosc Relat Phenom 57(1):91–97. https://doi.org/10.1016/0368-2048(91)85016-M
Rehman AU, Khan SA, Ali S, Nazar MF, Shah A, Rahman Khan A, Khan AM (2019) Counterion engineered surfactants for the novel synthesis of colloidal metal and bimetal oxide/SiO2 materials with catalytic applications. Colloids Surf A 571:80–85. https://doi.org/10.1016/j.colsurfa.2019.03.053
Ronda C (1995) Phosphors for lamps and displays: an applicational view. J Alloys Compd 225(1–2):534–538. https://doi.org/10.1016/0925-8388(94)07065-2
Rubab R, Ali S, Rehman AU, Khan SA, Khan AM (2021) Templated synthesis of NiO/SiO2 nanocomposite for dye removal applications: adsorption kinetics and thermodynamic properties. Colloids Surf Physicochem Eng Aspects 615:126253. https://doi.org/10.1016/j.colsurfa.2021.126253
Sarkar D, Ganguli S, Samanta T, Mahalingam V (2018) Design of lanthanide-doped colloidal nanocrystals: applications as phosphors, sensors, and photocatalysts. Langmuir. https://doi.org/10.1021/acs.langmuir.8b01593
Shuaibu AD, Rubab R, Khan S, Ali S, Shaikh AJ, Khan SA, Khan AM (2022) Comparative effects of zinc oxide nanoparticles over the interfacial properties of low concentrations of ionic surfactants at interfaces. Colloids Surf A 637:128241. https://doi.org/10.1016/j.colsurfa.2021.128241
Song Y, Shao B, Feng Y, Lü W, Liu G, You H (2016) A novel strategy to enhance the luminescence performance of NaGdF 4: Ln 3+ nanocrystals. Dalton Trans 45(23):9468–9476. https://doi.org/10.1039/C6DT01206J
Takagi K, Fukazawa T (1983) Cerium-activated Gd2SiO5 single crystal scintillator. Appl Phys Lett 42(1):43–45. https://doi.org/10.1063/1.93760
Tian Y, Yang H-Y, Li K, Jin X (2012) Monodispersed ultrathin GdF3 nanowires: oriented attachment, luminescence, and relaxivity for MRI contrast agents. J Mater Chem 22(42):22510–22516. https://doi.org/10.1039/C2JM34987F
Vashista M, Paul S (2012) Correlation between full width at half maximum (FWHM) of XRD peak with residual stress on ground surfaces. Philos Mag 92(33):4194–4204. https://doi.org/10.1080/14786435.2012.704429
Wang Q, Shantz DF (2008) Ordered mesoporous silica-based inorganic nanocomposites. J Solid State Chem 181(7):1659–1669. https://doi.org/10.1016/j.jssc.2008.06.015
Wang L, Li P, Li Y (2007) Down-and Up-Conversion Luminescent Nanorods. Adv Mater (Weinheim, Ger.) 19(20):3304–3307. https://doi.org/10.1002/adma.200700144
Wegh R, Donker H, Oskam K, Meijerink A (1999) Visible quantum cutting in Eu3+-doped gadolinium fluorides via downconversion. J Lumin 82(2):93–104. https://doi.org/10.1016/S0022-2313(99)00042-3
Wong H-T, Chan HL, Hao J (2009) Magnetic and luminescent properties of multifunctional GdF 3: Eu 3+ nanoparticles. Appl Phys Lett 95(2):022512. https://doi.org/10.1063/1.3177194
You M, Zhong J, Hong Y, Duan Z, Lin M, Xu F (2015) Inkjet printing of upconversion nanoparticles for anti-counterfeit applications. Nanoscale 7(10):4423–4431. https://doi.org/10.1039/C4NR06944G
Younis A, Loucif A (2021) Defects mediated enhanced catalytic and humidity sensing performance in ceria nanorods. Ceram Int 47(11):15500–15507. https://doi.org/10.1016/j.ceramint.2021.02.117
Younis A, Shirsath SE, Shabbir B, Li S (2018) Controllable dynamics of oxygen vacancies through extrinsic doping for superior catalytic activities. Nanoscale 10(39):18576–18585. https://doi.org/10.1039/C8NR03801E
Zhang Z, Zhang Y, Wang C, Feng Z, Zhang W, Xia H (2017) White light emission characteristics of Tb3+/Sm3+ co-doped glass ceramics containing YPO4 nanocrystals. J Mater Sci Technol 33(5):432–437. https://doi.org/10.1016/j.jmst.2016.10.002
Acknowledgements
Attiq Ur Rehman and Asad M. Khan would like to acknowledge the Higher Education Commission (HEC) of Pakistan for supporting this project via grants No. 20-5410 /HEC/R&D/2017 and 20-4271/R&D/HEC/14. L.U Khan would like to thank Brazilian Centre for Research in Energy material (CNPEM) for providing lab facilities and material characterizations.
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Rehman, A.U., Khan, L.U., de Brito, H.F. et al. Surfactant-based synthesis of optically active colloidal GdF3:Ce3+(5%), Eu3+(x%) and GdF3:Ce3+(5%), Eu3+(5%)/SiO2 phosphor nanocomposites. Appl Nanosci 12, 2183–2193 (2022). https://doi.org/10.1007/s13204-022-02473-y
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DOI: https://doi.org/10.1007/s13204-022-02473-y