Abstract
Micro- and nanoparticles of aluminum oxide (alumina) have been used to confer increased flammability to polymers. In the present study, different weight fractions of alumina nanoparticles were impregnated into a traditional softwood and the flammability of these treated woods was studied. Sodium polyacrylate (SPAC) was used as a surfactant and also as a positive control. The influence of the treatment in physical (apparent density), mechanical (static bending and hardness), and thermal (flame retardancy and thermal stability tests) characteristics were evaluated. The presence of alumina nanoparticles in the wood ultrastructure was confirmed by means of SEM/EDS analyses. Compared to the untreated pine wood and that wood impregnated with neat SPAC, the impregnation of alumina contents within 0.3–0.5 wt% reduced the flame spreading of the studied pine woods. Also compared to the untreated wood, similar thermal and mechanical properties were achieved. The studied pine wood became less flammable with alumina impregnation, and there was no detrimental effects to its mechanical properties.






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Acosta AP, Gallio E, Schulz HR et al (2020a) Wood-polymer composites produced by in situ polymerization of styrene into juvenile and mature pine woods. Int Wood Prod J. https://doi.org/10.1080/20426445.2020.1776486
Acosta AP, Schulz HR, Barbosa KT et al (2020b) Dimensional stability and colour responses of Pinus elliottii wood subjected to furfurylation treatments. Maderas Cienc y Tecnol. https://doi.org/10.4067/s0718-221x2020005000305
Alfredsen G, Bader TK, Dibdiakova J et al (2012) Thermogravimetric analysis for wood decay characterisation. Eur J Wood Wood Prod 70:527–530. https://doi.org/10.1007/s00107-011-0566-7
Aydemir D, Civi B, Alsan M et al (2016) Mechanical, morphological and thermal properties of nano-boron nitride treated wood materials. Maderas Cienc y Tecnol 18:19–32. https://doi.org/10.4067/S0718-221X2016005000003
Chandrasekaran A, Ramachandran S, Subbiah S (2017) Determination of kinetic parameters in the pyrolysis operation and thermal behavior of Prosopis juliflora using thermogravimetric analysis. Bioresour Technol 233:413–422. https://doi.org/10.1016/j.biortech.2017.02.119
Chu D, Mu J, Zhang L, Li Y (2017) Promotion effect of NP fire retardant pre-treatment on heat-treated poplar wood. Part 1: Color generation, dimensional stability, and fire retardancy. Holzforschung 71:207–215. https://doi.org/10.1515/hf-2016-0082
Ding WD, Koubaa A, Chaala A (2013) Mechanical properties of MMA-hardened hybrid poplar wood. Ind Crops Prod 46:304–310. https://doi.org/10.1016/j.indcrop.2013.02.004
Dong Y, Yan Y, Ma H et al (2017) In-Situ Chemosynthesis of ZnO Nanoparticles to Endow Wood with Antibacterial and UV-Resistance Properties. J Mater Sci Technol 33:266–270. https://doi.org/10.1016/j.jmst.2016.03.018
Feng Y, Hu J, Xue Y et al (2017) Simultaneous improvement in the flame resistance and thermal conductivity of epoxy/Al2O3 composites by incorporating polymeric flame retardant-functionalized graphene. J Mater Chem A 5:13544–13556. https://doi.org/10.1039/c7ta02934a
Gašparoviè L, Labovský J, Markoš J, Jelemenský L (2012) Calculation of kinetic parameters of the thermal decomposition of wood by distributed activation energy model (DAEM). Chem Biochem Eng Q 26:45–53
Jiao C, Chen X, Zhang J (2010) Synergistic flame-retardant effects of aluminum oxide with layered double hydroxides in EVA/LDH composites. J Thermoplast Compos Mater 23:501–512. https://doi.org/10.1177/0892705709356494
de Junkes CFO, Duz JVV, Kerber MR et al (2019) Resinosis of young slash pine (Pinus elliottii Engelm.)as a tool for resin stimulant paste development and high yield individual selection. Ind Crops Prod 135:179–187. https://doi.org/10.1016/j.indcrop.2019.04.048
Laachachi A, Cochez M, Leroy E et al (2006) Effect of Al2O3 and TiO2 nanoparticles and APP on thermal stability and flame retardance of PMMA. Polym Adv Technol 17:327–334. https://doi.org/10.1002/pat.690
Lande S, Westin M, Schneider M (2004) Properties of furfurylated wood. Scand J for Res 19:22–30. https://doi.org/10.1080/0282758041001915
Li T, Cheng DL, Avramidis S et al (2017) Response of hygroscopicity to heat treatment and its relation to durability of thermally modified wood. Constr Build Mater 144:671–676. https://doi.org/10.1016/j.conbuildmat.2017.03.218
Li Y, Dong X, Liu Y et al (2011) Improvement of decay resistance of wood via combination treatment on wood cell wall: Swell-bonding with maleic anhydride and graft copolymerization with glycidyl methacrylate and methyl methacrylate. Int Biodeterior Biodegrad 65:1087–1094. https://doi.org/10.1016/j.ibiod.2011.08.009
Liodakis S, Tsapara V, Agiovlasitis IP, Vorisis D (2013) Thermal analysis of Pinus sylvestris L. wood samples treated with a new gel-mineral mixture of short- and long-term fire retardants. Thermochim Acta 568:156–160. https://doi.org/10.1016/j.tca.2013.06.011
Liu R, Morrell JJ, Yan L (2018) Thermogravimetric analysis studies of thermally-treated glycerol impregnated poplar wood. BioResources 13:1563–1575. https://doi.org/10.15376/biores.13.1.1563-1575
Lowden L, Hull T (2013) Flammability behaviour of wood and a review of the methods for its reduction. Fire Sci Rev 2:4. https://doi.org/10.1186/2193-0414-2-4
Mantanis GI (2017) Chemical modification of wood by acetylation or furfurylation: a review of the present scaled-up technologies. BioResources 12:4478–4489. https://doi.org/10.15376/biores.12.2.4478-4489
Mattos BD, de Cademartori PHG, Missio AL et al (2015) Wood-polymer composites prepared by free radical in situ polymerization of methacrylate monomers into fast-growing pinewood. Wood Sci Technol 49:1281–1294. https://doi.org/10.1007/s00226-015-0761-5
Missio AL, De Cademartori PHG, Mattos BD et al (2015) Propriedades mecânicas da madeira resinada de Pinus elliottii. Cienc Rural 45:1432–1438. https://doi.org/10.1590/0103-8478cr20130475
Neis FA, de Costa F, de Almeida MR et al (2019) Resin exudation profile, chemical composition, and secretory canal characterization in contrasting yield phenotypes of Pinus elliottii Engelm. Ind Crops Prod 132:76–83. https://doi.org/10.1016/j.indcrop.2019.02.013
Norouzbeigi R, Edrissi M (2011) Preparation of nano alumina powder via combustion synthesis: Porous structure optimization via taguchi L16 design. J Am Ceram Soc 94:4052–4058. https://doi.org/10.1111/j.1551-2916.2011.04675.x
Okon KE, Lin F, Chen Y, Huang B (2017) Effect of silicone oil heat treatment on the chemical composition, cellulose crystalline structure and contact angle of Chinese parasol wood. Carbohydr Polym 164:179–185. https://doi.org/10.1016/j.carbpol.2017.01.076
Olaniran SO, Michen B, Mora Mendez DF et al (2019) Mechanical behaviour of chemically modified Norway spruce (Picea abies L. Karst.): Experimental mechanical studies on spruce wood after methacrylation and in situ polymerization of styrene. Wood Sci Technol 53:425–445. https://doi.org/10.1007/s00226-019-01080-5
Silveira EA, Lin BJ, Colin B et al (2018) Heat treatment kinetics using three-stage approach for sustainable wood material production. Ind Crops Prod 124:563–571. https://doi.org/10.1016/j.indcrop.2018.07.045
Sun QF, Lu Y, Xia YZ et al (2012) Flame retardancy of wood treated by TiO2/ZnO coating. Surf Eng 28:555–559. https://doi.org/10.1179/1743294412Y.0000000027
Taghiyari HR, Rassam G, Ahmadi-DavazdahEmam K (2017) Effects of densification on untreated and nano-aluminum-oxide impregnated poplar wood. J for Res 28:403–410. https://doi.org/10.1007/s11676-016-0321-3
Yang H, Yan R, Chen H et al (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788. https://doi.org/10.1016/j.fuel.2006.12.013
Zanatta P, Lazarotto M, Gonzalez de Cademartori PH et al (2017) The effect of titanium dioxide nanoparticles obtained by microwave-assisted hydrothermal method on the color and decay resistance of pinewood. Maderas Cienc y Tecnol. https://doi.org/10.4067/s0718-221x2017005000901
Zanatta P, Peres ML, Gallio E et al (2018) Redução da inflamabilidade da madeira de Pinus elliottii modificada com partículas de TiO2. Matéria (rio Janeiro). https://doi.org/10.1590/s1517-707620180001.0481
Zhuravlev VD, Bamburov VG, Beketov AR et al (2013) Solution combustion synthesis of α-Al2O3 using urea. Ceram Int 39:1379–1384. https://doi.org/10.1016/j.ceramint.2012.07.078
Acknowledgements
This work was supported by Coordination for the Improvement of Higher Education—CAPES (Financing Code 001) and National Council for Scientific and Technological Development—CNPq (Financing Code 301758/2019-0). The authors would like to thank Centro de Microscopia Eletrônica do Sul (CEME-SUL), located at University of Rio Grande (FURG/Brazil) due to the SEM images.
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Gallio, E., Acosta, A.P., Delucis, R.d. et al. Flammability of a softwood impregnated with alumina nanoparticles. J Indian Acad Wood Sci 18, 75–82 (2021). https://doi.org/10.1007/s13196-021-00282-4
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DOI: https://doi.org/10.1007/s13196-021-00282-4

